Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts

Autores
Rochetti Yharour, Maria Florencia; Fellenz, Nicolás Antonio; Alvarez, Ana Maria; Bengoa, Jose Fernando; Gallegos, Norma Graciela; Cagnoli, Maria Virginia; Marchetti, Sergio Gustavo
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Bulk γ-Fe2O3 (maghemite) and Fe3O4 (magnetite) were synthesized with Fe(III) hydroxyacetate as an intermediate during the preparation step. The fresh and used catalysts were characterized by X-ray diffraction, N2 adsorption at 77 K, Mössbauer spectroscopy at 298 K, diffuse-reflectance spectroscopy, and thermogravimetric analysis. The solids were used as catalysts in the ethanol hydrotreatment within the range of 673-758 K. The catalysts showed a satisfactory selectivity for H2 and an especially low CO production. These activities and selectivities were analyzed in conjunction with the structural properties of the oxides. Magnetite seemed to be a more appropriate catalyst than maghemite since the latter was converted into magnetite at reaction temperatures higher than 713 K because of the reducing atmosphere.
Fil: Rochetti Yharour, Maria Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Fellenz, Nicolás Antonio. Universidad Nacional de Rio Negro. Sede Atlantica. Escuela de Produccion, Tecnologia y Medio Ambiente; Argentina
Fil: Alvarez, Ana Maria. Universidad Nacional de Rio Negro; Argentina
Fil: Bengoa, Jose Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Gallegos, Norma Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Cagnoli, Maria Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Marchetti, Sergio Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Materia
Hydrogen Production with Low Co Content
Ethanol Hydrotreatment
Magnetite Catalyst
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5752
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/5752
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network_name_str CONICET Digital (CONICET)
spelling Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalystsRochetti Yharour, Maria FlorenciaFellenz, Nicolás AntonioAlvarez, Ana MariaBengoa, Jose FernandoGallegos, Norma GracielaCagnoli, Maria VirginiaMarchetti, Sergio GustavoHydrogen Production with Low Co ContentEthanol HydrotreatmentMagnetite Catalysthttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Bulk γ-Fe2O3 (maghemite) and Fe3O4 (magnetite) were synthesized with Fe(III) hydroxyacetate as an intermediate during the preparation step. The fresh and used catalysts were characterized by X-ray diffraction, N2 adsorption at 77 K, Mössbauer spectroscopy at 298 K, diffuse-reflectance spectroscopy, and thermogravimetric analysis. The solids were used as catalysts in the ethanol hydrotreatment within the range of 673-758 K. The catalysts showed a satisfactory selectivity for H2 and an especially low CO production. These activities and selectivities were analyzed in conjunction with the structural properties of the oxides. Magnetite seemed to be a more appropriate catalyst than maghemite since the latter was converted into magnetite at reaction temperatures higher than 713 K because of the reducing atmosphere.Fil: Rochetti Yharour, Maria Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Fellenz, Nicolás Antonio. Universidad Nacional de Rio Negro. Sede Atlantica. Escuela de Produccion, Tecnologia y Medio Ambiente; ArgentinaFil: Alvarez, Ana Maria. Universidad Nacional de Rio Negro; ArgentinaFil: Bengoa, Jose Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Gallegos, Norma Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Cagnoli, Maria Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Marchetti, Sergio Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaElsevier2014-07-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5752Rochetti Yharour, Maria Florencia; Fellenz, Nicolás Antonio; Alvarez, Ana Maria; Bengoa, Jose Fernando; Gallegos, Norma Graciela; et al.; Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts; Elsevier; International Journal Of Hydrogen Energy; 39; 24; 12-7-2014; 12563-125710360-3199enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0360319914017170info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2014.06.076info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:27:10Zoai:ri.conicet.gov.ar:11336/5752instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:27:11.103CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts
title Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts
spellingShingle Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts
Rochetti Yharour, Maria Florencia
Hydrogen Production with Low Co Content
Ethanol Hydrotreatment
Magnetite Catalyst
title_short Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts
title_full Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts
title_fullStr Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts
title_full_unstemmed Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts
title_sort Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts
dc.creator.none.fl_str_mv Rochetti Yharour, Maria Florencia
Fellenz, Nicolás Antonio
Alvarez, Ana Maria
Bengoa, Jose Fernando
Gallegos, Norma Graciela
Cagnoli, Maria Virginia
Marchetti, Sergio Gustavo
author Rochetti Yharour, Maria Florencia
author_facet Rochetti Yharour, Maria Florencia
Fellenz, Nicolás Antonio
Alvarez, Ana Maria
Bengoa, Jose Fernando
Gallegos, Norma Graciela
Cagnoli, Maria Virginia
Marchetti, Sergio Gustavo
author_role author
author2 Fellenz, Nicolás Antonio
Alvarez, Ana Maria
Bengoa, Jose Fernando
Gallegos, Norma Graciela
Cagnoli, Maria Virginia
Marchetti, Sergio Gustavo
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Hydrogen Production with Low Co Content
Ethanol Hydrotreatment
Magnetite Catalyst
topic Hydrogen Production with Low Co Content
Ethanol Hydrotreatment
Magnetite Catalyst
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Bulk γ-Fe2O3 (maghemite) and Fe3O4 (magnetite) were synthesized with Fe(III) hydroxyacetate as an intermediate during the preparation step. The fresh and used catalysts were characterized by X-ray diffraction, N2 adsorption at 77 K, Mössbauer spectroscopy at 298 K, diffuse-reflectance spectroscopy, and thermogravimetric analysis. The solids were used as catalysts in the ethanol hydrotreatment within the range of 673-758 K. The catalysts showed a satisfactory selectivity for H2 and an especially low CO production. These activities and selectivities were analyzed in conjunction with the structural properties of the oxides. Magnetite seemed to be a more appropriate catalyst than maghemite since the latter was converted into magnetite at reaction temperatures higher than 713 K because of the reducing atmosphere.
Fil: Rochetti Yharour, Maria Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Fellenz, Nicolás Antonio. Universidad Nacional de Rio Negro. Sede Atlantica. Escuela de Produccion, Tecnologia y Medio Ambiente; Argentina
Fil: Alvarez, Ana Maria. Universidad Nacional de Rio Negro; Argentina
Fil: Bengoa, Jose Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Gallegos, Norma Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Cagnoli, Maria Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Marchetti, Sergio Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
description Bulk γ-Fe2O3 (maghemite) and Fe3O4 (magnetite) were synthesized with Fe(III) hydroxyacetate as an intermediate during the preparation step. The fresh and used catalysts were characterized by X-ray diffraction, N2 adsorption at 77 K, Mössbauer spectroscopy at 298 K, diffuse-reflectance spectroscopy, and thermogravimetric analysis. The solids were used as catalysts in the ethanol hydrotreatment within the range of 673-758 K. The catalysts showed a satisfactory selectivity for H2 and an especially low CO production. These activities and selectivities were analyzed in conjunction with the structural properties of the oxides. Magnetite seemed to be a more appropriate catalyst than maghemite since the latter was converted into magnetite at reaction temperatures higher than 713 K because of the reducing atmosphere.
publishDate 2014
dc.date.none.fl_str_mv 2014-07-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5752
Rochetti Yharour, Maria Florencia; Fellenz, Nicolás Antonio; Alvarez, Ana Maria; Bengoa, Jose Fernando; Gallegos, Norma Graciela; et al.; Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts; Elsevier; International Journal Of Hydrogen Energy; 39; 24; 12-7-2014; 12563-12571
0360-3199
url http://hdl.handle.net/11336/5752
identifier_str_mv Rochetti Yharour, Maria Florencia; Fellenz, Nicolás Antonio; Alvarez, Ana Maria; Bengoa, Jose Fernando; Gallegos, Norma Graciela; et al.; Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts; Elsevier; International Journal Of Hydrogen Energy; 39; 24; 12-7-2014; 12563-12571
0360-3199
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0360319914017170
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2014.06.076
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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