Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts
- Autores
- Rochetti Yharour, Maria Florencia; Fellenz, Nicolás Antonio; Alvarez, Ana Maria; Bengoa, Jose Fernando; Gallegos, Norma Graciela; Cagnoli, Maria Virginia; Marchetti, Sergio Gustavo
- Año de publicación
- 2014
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Bulk γ-Fe2O3 (maghemite) and Fe3O4 (magnetite) were synthesized with Fe(III) hydroxyacetate as an intermediate during the preparation step. The fresh and used catalysts were characterized by X-ray diffraction, N2 adsorption at 77 K, Mössbauer spectroscopy at 298 K, diffuse-reflectance spectroscopy, and thermogravimetric analysis. The solids were used as catalysts in the ethanol hydrotreatment within the range of 673-758 K. The catalysts showed a satisfactory selectivity for H2 and an especially low CO production. These activities and selectivities were analyzed in conjunction with the structural properties of the oxides. Magnetite seemed to be a more appropriate catalyst than maghemite since the latter was converted into magnetite at reaction temperatures higher than 713 K because of the reducing atmosphere.
Fil: Rochetti Yharour, Maria Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Fellenz, Nicolás Antonio. Universidad Nacional de Rio Negro. Sede Atlantica. Escuela de Produccion, Tecnologia y Medio Ambiente; Argentina
Fil: Alvarez, Ana Maria. Universidad Nacional de Rio Negro; Argentina
Fil: Bengoa, Jose Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Gallegos, Norma Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Cagnoli, Maria Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina
Fil: Marchetti, Sergio Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina - Materia
-
Hydrogen Production with Low Co Content
Ethanol Hydrotreatment
Magnetite Catalyst - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/5752
Ver los metadatos del registro completo
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Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalystsRochetti Yharour, Maria FlorenciaFellenz, Nicolás AntonioAlvarez, Ana MariaBengoa, Jose FernandoGallegos, Norma GracielaCagnoli, Maria VirginiaMarchetti, Sergio GustavoHydrogen Production with Low Co ContentEthanol HydrotreatmentMagnetite Catalysthttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Bulk γ-Fe2O3 (maghemite) and Fe3O4 (magnetite) were synthesized with Fe(III) hydroxyacetate as an intermediate during the preparation step. The fresh and used catalysts were characterized by X-ray diffraction, N2 adsorption at 77 K, Mössbauer spectroscopy at 298 K, diffuse-reflectance spectroscopy, and thermogravimetric analysis. The solids were used as catalysts in the ethanol hydrotreatment within the range of 673-758 K. The catalysts showed a satisfactory selectivity for H2 and an especially low CO production. These activities and selectivities were analyzed in conjunction with the structural properties of the oxides. Magnetite seemed to be a more appropriate catalyst than maghemite since the latter was converted into magnetite at reaction temperatures higher than 713 K because of the reducing atmosphere.Fil: Rochetti Yharour, Maria Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Fellenz, Nicolás Antonio. Universidad Nacional de Rio Negro. Sede Atlantica. Escuela de Produccion, Tecnologia y Medio Ambiente; ArgentinaFil: Alvarez, Ana Maria. Universidad Nacional de Rio Negro; ArgentinaFil: Bengoa, Jose Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Gallegos, Norma Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Cagnoli, Maria Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaFil: Marchetti, Sergio Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; ArgentinaElsevier2014-07-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5752Rochetti Yharour, Maria Florencia; Fellenz, Nicolás Antonio; Alvarez, Ana Maria; Bengoa, Jose Fernando; Gallegos, Norma Graciela; et al.; Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts; Elsevier; International Journal Of Hydrogen Energy; 39; 24; 12-7-2014; 12563-125710360-3199enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0360319914017170info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2014.06.076info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:38:05Zoai:ri.conicet.gov.ar:11336/5752instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:38:05.613CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts |
title |
Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts |
spellingShingle |
Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts Rochetti Yharour, Maria Florencia Hydrogen Production with Low Co Content Ethanol Hydrotreatment Magnetite Catalyst |
title_short |
Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts |
title_full |
Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts |
title_fullStr |
Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts |
title_full_unstemmed |
Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts |
title_sort |
Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts |
dc.creator.none.fl_str_mv |
Rochetti Yharour, Maria Florencia Fellenz, Nicolás Antonio Alvarez, Ana Maria Bengoa, Jose Fernando Gallegos, Norma Graciela Cagnoli, Maria Virginia Marchetti, Sergio Gustavo |
author |
Rochetti Yharour, Maria Florencia |
author_facet |
Rochetti Yharour, Maria Florencia Fellenz, Nicolás Antonio Alvarez, Ana Maria Bengoa, Jose Fernando Gallegos, Norma Graciela Cagnoli, Maria Virginia Marchetti, Sergio Gustavo |
author_role |
author |
author2 |
Fellenz, Nicolás Antonio Alvarez, Ana Maria Bengoa, Jose Fernando Gallegos, Norma Graciela Cagnoli, Maria Virginia Marchetti, Sergio Gustavo |
author2_role |
author author author author author author |
dc.subject.none.fl_str_mv |
Hydrogen Production with Low Co Content Ethanol Hydrotreatment Magnetite Catalyst |
topic |
Hydrogen Production with Low Co Content Ethanol Hydrotreatment Magnetite Catalyst |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Bulk γ-Fe2O3 (maghemite) and Fe3O4 (magnetite) were synthesized with Fe(III) hydroxyacetate as an intermediate during the preparation step. The fresh and used catalysts were characterized by X-ray diffraction, N2 adsorption at 77 K, Mössbauer spectroscopy at 298 K, diffuse-reflectance spectroscopy, and thermogravimetric analysis. The solids were used as catalysts in the ethanol hydrotreatment within the range of 673-758 K. The catalysts showed a satisfactory selectivity for H2 and an especially low CO production. These activities and selectivities were analyzed in conjunction with the structural properties of the oxides. Magnetite seemed to be a more appropriate catalyst than maghemite since the latter was converted into magnetite at reaction temperatures higher than 713 K because of the reducing atmosphere. Fil: Rochetti Yharour, Maria Florencia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina Fil: Fellenz, Nicolás Antonio. Universidad Nacional de Rio Negro. Sede Atlantica. Escuela de Produccion, Tecnologia y Medio Ambiente; Argentina Fil: Alvarez, Ana Maria. Universidad Nacional de Rio Negro; Argentina Fil: Bengoa, Jose Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina Fil: Gallegos, Norma Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina Fil: Cagnoli, Maria Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina Fil: Marchetti, Sergio Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina |
description |
Bulk γ-Fe2O3 (maghemite) and Fe3O4 (magnetite) were synthesized with Fe(III) hydroxyacetate as an intermediate during the preparation step. The fresh and used catalysts were characterized by X-ray diffraction, N2 adsorption at 77 K, Mössbauer spectroscopy at 298 K, diffuse-reflectance spectroscopy, and thermogravimetric analysis. The solids were used as catalysts in the ethanol hydrotreatment within the range of 673-758 K. The catalysts showed a satisfactory selectivity for H2 and an especially low CO production. These activities and selectivities were analyzed in conjunction with the structural properties of the oxides. Magnetite seemed to be a more appropriate catalyst than maghemite since the latter was converted into magnetite at reaction temperatures higher than 713 K because of the reducing atmosphere. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-07-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/5752 Rochetti Yharour, Maria Florencia; Fellenz, Nicolás Antonio; Alvarez, Ana Maria; Bengoa, Jose Fernando; Gallegos, Norma Graciela; et al.; Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts; Elsevier; International Journal Of Hydrogen Energy; 39; 24; 12-7-2014; 12563-12571 0360-3199 |
url |
http://hdl.handle.net/11336/5752 |
identifier_str_mv |
Rochetti Yharour, Maria Florencia; Fellenz, Nicolás Antonio; Alvarez, Ana Maria; Bengoa, Jose Fernando; Gallegos, Norma Graciela; et al.; Hydrogen production from ethanol with low carbon monoxide generation in one-pot reaction with iron oxides as catalysts; Elsevier; International Journal Of Hydrogen Energy; 39; 24; 12-7-2014; 12563-12571 0360-3199 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0360319914017170 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2014.06.076 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613202886787072 |
score |
13.070432 |