NaA zeolite as an effective diffusion barrier in composite Pd/PSS membranes
- Autores
- Bosko, María Laura; Ojeda, F.; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria
- Año de publicación
- 2009
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Palladium composite membranes on porous stainless steel were prepared by electroless plating. In order to obtain a thin palladium film, an intermediate layer was necessary to modify the pore size of the substrate and form a diffusion barrier between the palladium film and the support. The NaA zeolite, used as intermediate, was synthesized by vacuum-assisted secondary growth. Pure gas permeability tests were conducted using hydrogen and nitrogen between 400 and 450 °C. The surface morphology and the components of the different layers of the membrane were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray analysis (EDS), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD). When vacuum was applied during the zeolite synthesis at 80 °C, the Pd membrane showed high H2/N2 ideal selectivity in the working temperature range. This result suggests that NaA zeolite is an effective intermediate substrate modifier when an appropriate synthesis method is employed.
Fil: Bosko, María Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Ojeda, F.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina - Materia
-
Hydeogen Purification
Zeolite Synthesis
Pd Membrane - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/57142
Ver los metadatos del registro completo
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NaA zeolite as an effective diffusion barrier in composite Pd/PSS membranesBosko, María LauraOjeda, F.Lombardo, Eduardo AgustinCornaglia, Laura MariaHydeogen PurificationZeolite SynthesisPd Membranehttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Palladium composite membranes on porous stainless steel were prepared by electroless plating. In order to obtain a thin palladium film, an intermediate layer was necessary to modify the pore size of the substrate and form a diffusion barrier between the palladium film and the support. The NaA zeolite, used as intermediate, was synthesized by vacuum-assisted secondary growth. Pure gas permeability tests were conducted using hydrogen and nitrogen between 400 and 450 °C. The surface morphology and the components of the different layers of the membrane were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray analysis (EDS), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD). When vacuum was applied during the zeolite synthesis at 80 °C, the Pd membrane showed high H2/N2 ideal selectivity in the working temperature range. This result suggests that NaA zeolite is an effective intermediate substrate modifier when an appropriate synthesis method is employed.Fil: Bosko, María Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Ojeda, F.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2009-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/57142Bosko, María Laura; Ojeda, F.; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria; NaA zeolite as an effective diffusion barrier in composite Pd/PSS membranes; Elsevier Science; Journal of Membrane Science; 331; 1-2; 4-2009; 57-650376-7388CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.memsci.2009.01.005info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:36:58Zoai:ri.conicet.gov.ar:11336/57142instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:36:58.779CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
NaA zeolite as an effective diffusion barrier in composite Pd/PSS membranes |
title |
NaA zeolite as an effective diffusion barrier in composite Pd/PSS membranes |
spellingShingle |
NaA zeolite as an effective diffusion barrier in composite Pd/PSS membranes Bosko, María Laura Hydeogen Purification Zeolite Synthesis Pd Membrane |
title_short |
NaA zeolite as an effective diffusion barrier in composite Pd/PSS membranes |
title_full |
NaA zeolite as an effective diffusion barrier in composite Pd/PSS membranes |
title_fullStr |
NaA zeolite as an effective diffusion barrier in composite Pd/PSS membranes |
title_full_unstemmed |
NaA zeolite as an effective diffusion barrier in composite Pd/PSS membranes |
title_sort |
NaA zeolite as an effective diffusion barrier in composite Pd/PSS membranes |
dc.creator.none.fl_str_mv |
Bosko, María Laura Ojeda, F. Lombardo, Eduardo Agustin Cornaglia, Laura Maria |
author |
Bosko, María Laura |
author_facet |
Bosko, María Laura Ojeda, F. Lombardo, Eduardo Agustin Cornaglia, Laura Maria |
author_role |
author |
author2 |
Ojeda, F. Lombardo, Eduardo Agustin Cornaglia, Laura Maria |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Hydeogen Purification Zeolite Synthesis Pd Membrane |
topic |
Hydeogen Purification Zeolite Synthesis Pd Membrane |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Palladium composite membranes on porous stainless steel were prepared by electroless plating. In order to obtain a thin palladium film, an intermediate layer was necessary to modify the pore size of the substrate and form a diffusion barrier between the palladium film and the support. The NaA zeolite, used as intermediate, was synthesized by vacuum-assisted secondary growth. Pure gas permeability tests were conducted using hydrogen and nitrogen between 400 and 450 °C. The surface morphology and the components of the different layers of the membrane were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray analysis (EDS), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD). When vacuum was applied during the zeolite synthesis at 80 °C, the Pd membrane showed high H2/N2 ideal selectivity in the working temperature range. This result suggests that NaA zeolite is an effective intermediate substrate modifier when an appropriate synthesis method is employed. Fil: Bosko, María Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Ojeda, F.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina |
description |
Palladium composite membranes on porous stainless steel were prepared by electroless plating. In order to obtain a thin palladium film, an intermediate layer was necessary to modify the pore size of the substrate and form a diffusion barrier between the palladium film and the support. The NaA zeolite, used as intermediate, was synthesized by vacuum-assisted secondary growth. Pure gas permeability tests were conducted using hydrogen and nitrogen between 400 and 450 °C. The surface morphology and the components of the different layers of the membrane were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray analysis (EDS), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD). When vacuum was applied during the zeolite synthesis at 80 °C, the Pd membrane showed high H2/N2 ideal selectivity in the working temperature range. This result suggests that NaA zeolite is an effective intermediate substrate modifier when an appropriate synthesis method is employed. |
publishDate |
2009 |
dc.date.none.fl_str_mv |
2009-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/57142 Bosko, María Laura; Ojeda, F.; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria; NaA zeolite as an effective diffusion barrier in composite Pd/PSS membranes; Elsevier Science; Journal of Membrane Science; 331; 1-2; 4-2009; 57-65 0376-7388 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/57142 |
identifier_str_mv |
Bosko, María Laura; Ojeda, F.; Lombardo, Eduardo Agustin; Cornaglia, Laura Maria; NaA zeolite as an effective diffusion barrier in composite Pd/PSS membranes; Elsevier Science; Journal of Membrane Science; 331; 1-2; 4-2009; 57-65 0376-7388 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.memsci.2009.01.005 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613163542118400 |
score |
13.070432 |