Investigation of iron oxide reduction by ethanol as a potential route to produce hydrogen
- Autores
- Rosmaninho, Marcelo G.; Moura, Flávia C.; Souza, Lívia Ribeiro de; Nogueira, R.K.; Gomes, G.M.; Pádua, Sebastião José Nascimento de; Pereira, Mayra Camargo; Fabris, José Domingos; Ardisson, José Domingos; Nazzarro, Marcelo Sandro; Sapag, Manuel Karim; Araújo, Maria Helena; Lago, Rochel Montero
- Año de publicación
- 2012
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- In this work, a novel way to indirectly store and produce H2 from ethanol was investigated using a two-step process based on the reduction of iron oxide followed by oxidation with H2O. The reduction of different iron oxides, i.e., Fe2O3, Fe3O4 and FeOOH, with ethanol to produce Feo was investigated. TPRe (Temperature Programmed Reactions) and Mössbauer and XRD analyses showed that ethanol reduces Fe2O3 sequentially to Fe3O4 at 350–500 °C, to Fe3O4/FeO at 500–600 °C and finally to Feo at 700 °C. The formed Feo can then be oxidized by H2O to produce H2 and Fe3O4, as shown by Mössbauer and XRD analyses. Cyclic experiments showed that iron could be consecutively reduced/oxidized at least 5 times without any significant decrease in H2 production after the second cycle. However, reactions of Fe2O3 with ethanol at higher temperatures, i.e., 800 and 900 °C, led to the formation of iron carbide and significant carbon deposition. XPS, SEM, TEM, Raman and TG showed 24–28 wt% carbon content, particularly on the surface as nanofibers and as amorphous and graphitic carbon.
Fil: Rosmaninho, Marcelo G.. Universidade Federal de Minas Gerais; Brasil
Fil: Moura, Flávia C.. Universidade Federal de Minas Gerais; Brasil
Fil: Souza, Lívia Ribeiro de. Universidade Federal de Minas Gerais; Brasil
Fil: Nogueira, R.K.. Universidade Federal de Minas Gerais; Brasil
Fil: Gomes, G.M.. Universidade Federal de Minas Gerais; Brasil
Fil: Pádua, Sebastião José Nascimento de. Universidade Federal de Minas Gerais; Brasil
Fil: Pereira, Mayra Camargo. Universidade Federal de Minas Gerais; Brasil
Fil: Fabris, José Domingos. Universidade Federal de Minas Gerais; Brasil
Fil: Ardisson, José Domingos. Comissão Nacional de Energia Nuclear. Centro de Desenvolvimento da Tecnologia Nuclear; Brasil. Universidade Federal de Minas Gerais; Brasil
Fil: Nazzarro, Marcelo Sandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Sapag, Manuel Karim. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Araújo, Maria Helena. Universidade Federal de Minas Gerais; Brasil
Fil: Lago, Rochel Montero. Universidade Federal de Minas Gerais; Brasil - Materia
-
HYDROGEN PRODUCTION
ETHANOL
HYDROGEN STORAGE
IRON OXIDE - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/104434
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Investigation of iron oxide reduction by ethanol as a potential route to produce hydrogenRosmaninho, Marcelo G.Moura, Flávia C.Souza, Lívia Ribeiro deNogueira, R.K.Gomes, G.M.Pádua, Sebastião José Nascimento dePereira, Mayra CamargoFabris, José DomingosArdisson, José DomingosNazzarro, Marcelo SandroSapag, Manuel KarimAraújo, Maria HelenaLago, Rochel MonteroHYDROGEN PRODUCTIONETHANOLHYDROGEN STORAGEIRON OXIDEhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2In this work, a novel way to indirectly store and produce H2 from ethanol was investigated using a two-step process based on the reduction of iron oxide followed by oxidation with H2O. The reduction of different iron oxides, i.e., Fe2O3, Fe3O4 and FeOOH, with ethanol to produce Feo was investigated. TPRe (Temperature Programmed Reactions) and Mössbauer and XRD analyses showed that ethanol reduces Fe2O3 sequentially to Fe3O4 at 350–500 °C, to Fe3O4/FeO at 500–600 °C and finally to Feo at 700 °C. The formed Feo can then be oxidized by H2O to produce H2 and Fe3O4, as shown by Mössbauer and XRD analyses. Cyclic experiments showed that iron could be consecutively reduced/oxidized at least 5 times without any significant decrease in H2 production after the second cycle. However, reactions of Fe2O3 with ethanol at higher temperatures, i.e., 800 and 900 °C, led to the formation of iron carbide and significant carbon deposition. XPS, SEM, TEM, Raman and TG showed 24–28 wt% carbon content, particularly on the surface as nanofibers and as amorphous and graphitic carbon.Fil: Rosmaninho, Marcelo G.. Universidade Federal de Minas Gerais; BrasilFil: Moura, Flávia C.. Universidade Federal de Minas Gerais; BrasilFil: Souza, Lívia Ribeiro de. Universidade Federal de Minas Gerais; BrasilFil: Nogueira, R.K.. Universidade Federal de Minas Gerais; BrasilFil: Gomes, G.M.. Universidade Federal de Minas Gerais; BrasilFil: Pádua, Sebastião José Nascimento de. Universidade Federal de Minas Gerais; BrasilFil: Pereira, Mayra Camargo. Universidade Federal de Minas Gerais; BrasilFil: Fabris, José Domingos. Universidade Federal de Minas Gerais; BrasilFil: Ardisson, José Domingos. Comissão Nacional de Energia Nuclear. Centro de Desenvolvimento da Tecnologia Nuclear; Brasil. Universidade Federal de Minas Gerais; BrasilFil: Nazzarro, Marcelo Sandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaFil: Sapag, Manuel Karim. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaFil: Araújo, Maria Helena. Universidade Federal de Minas Gerais; BrasilFil: Lago, Rochel Montero. Universidade Federal de Minas Gerais; BrasilElsevier Science2012-04-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/104434Rosmaninho, Marcelo G.; Moura, Flávia C.; Souza, Lívia Ribeiro de ; Nogueira, R.K.; Gomes, G.M.; et al.; Investigation of iron oxide reduction by ethanol as a potential route to produce hydrogen; Elsevier Science; Applied Catalysis B: Environmental; 115-116; 5-4-2012; 45-520926-3373CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0926337311005479info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2011.11.038info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:23:07Zoai:ri.conicet.gov.ar:11336/104434instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:23:07.582CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Investigation of iron oxide reduction by ethanol as a potential route to produce hydrogen |
title |
Investigation of iron oxide reduction by ethanol as a potential route to produce hydrogen |
spellingShingle |
Investigation of iron oxide reduction by ethanol as a potential route to produce hydrogen Rosmaninho, Marcelo G. HYDROGEN PRODUCTION ETHANOL HYDROGEN STORAGE IRON OXIDE |
title_short |
Investigation of iron oxide reduction by ethanol as a potential route to produce hydrogen |
title_full |
Investigation of iron oxide reduction by ethanol as a potential route to produce hydrogen |
title_fullStr |
Investigation of iron oxide reduction by ethanol as a potential route to produce hydrogen |
title_full_unstemmed |
Investigation of iron oxide reduction by ethanol as a potential route to produce hydrogen |
title_sort |
Investigation of iron oxide reduction by ethanol as a potential route to produce hydrogen |
dc.creator.none.fl_str_mv |
Rosmaninho, Marcelo G. Moura, Flávia C. Souza, Lívia Ribeiro de Nogueira, R.K. Gomes, G.M. Pádua, Sebastião José Nascimento de Pereira, Mayra Camargo Fabris, José Domingos Ardisson, José Domingos Nazzarro, Marcelo Sandro Sapag, Manuel Karim Araújo, Maria Helena Lago, Rochel Montero |
author |
Rosmaninho, Marcelo G. |
author_facet |
Rosmaninho, Marcelo G. Moura, Flávia C. Souza, Lívia Ribeiro de Nogueira, R.K. Gomes, G.M. Pádua, Sebastião José Nascimento de Pereira, Mayra Camargo Fabris, José Domingos Ardisson, José Domingos Nazzarro, Marcelo Sandro Sapag, Manuel Karim Araújo, Maria Helena Lago, Rochel Montero |
author_role |
author |
author2 |
Moura, Flávia C. Souza, Lívia Ribeiro de Nogueira, R.K. Gomes, G.M. Pádua, Sebastião José Nascimento de Pereira, Mayra Camargo Fabris, José Domingos Ardisson, José Domingos Nazzarro, Marcelo Sandro Sapag, Manuel Karim Araújo, Maria Helena Lago, Rochel Montero |
author2_role |
author author author author author author author author author author author author |
dc.subject.none.fl_str_mv |
HYDROGEN PRODUCTION ETHANOL HYDROGEN STORAGE IRON OXIDE |
topic |
HYDROGEN PRODUCTION ETHANOL HYDROGEN STORAGE IRON OXIDE |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.3 https://purl.org/becyt/ford/1 https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
In this work, a novel way to indirectly store and produce H2 from ethanol was investigated using a two-step process based on the reduction of iron oxide followed by oxidation with H2O. The reduction of different iron oxides, i.e., Fe2O3, Fe3O4 and FeOOH, with ethanol to produce Feo was investigated. TPRe (Temperature Programmed Reactions) and Mössbauer and XRD analyses showed that ethanol reduces Fe2O3 sequentially to Fe3O4 at 350–500 °C, to Fe3O4/FeO at 500–600 °C and finally to Feo at 700 °C. The formed Feo can then be oxidized by H2O to produce H2 and Fe3O4, as shown by Mössbauer and XRD analyses. Cyclic experiments showed that iron could be consecutively reduced/oxidized at least 5 times without any significant decrease in H2 production after the second cycle. However, reactions of Fe2O3 with ethanol at higher temperatures, i.e., 800 and 900 °C, led to the formation of iron carbide and significant carbon deposition. XPS, SEM, TEM, Raman and TG showed 24–28 wt% carbon content, particularly on the surface as nanofibers and as amorphous and graphitic carbon. Fil: Rosmaninho, Marcelo G.. Universidade Federal de Minas Gerais; Brasil Fil: Moura, Flávia C.. Universidade Federal de Minas Gerais; Brasil Fil: Souza, Lívia Ribeiro de. Universidade Federal de Minas Gerais; Brasil Fil: Nogueira, R.K.. Universidade Federal de Minas Gerais; Brasil Fil: Gomes, G.M.. Universidade Federal de Minas Gerais; Brasil Fil: Pádua, Sebastião José Nascimento de. Universidade Federal de Minas Gerais; Brasil Fil: Pereira, Mayra Camargo. Universidade Federal de Minas Gerais; Brasil Fil: Fabris, José Domingos. Universidade Federal de Minas Gerais; Brasil Fil: Ardisson, José Domingos. Comissão Nacional de Energia Nuclear. Centro de Desenvolvimento da Tecnologia Nuclear; Brasil. Universidade Federal de Minas Gerais; Brasil Fil: Nazzarro, Marcelo Sandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina Fil: Sapag, Manuel Karim. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina Fil: Araújo, Maria Helena. Universidade Federal de Minas Gerais; Brasil Fil: Lago, Rochel Montero. Universidade Federal de Minas Gerais; Brasil |
description |
In this work, a novel way to indirectly store and produce H2 from ethanol was investigated using a two-step process based on the reduction of iron oxide followed by oxidation with H2O. The reduction of different iron oxides, i.e., Fe2O3, Fe3O4 and FeOOH, with ethanol to produce Feo was investigated. TPRe (Temperature Programmed Reactions) and Mössbauer and XRD analyses showed that ethanol reduces Fe2O3 sequentially to Fe3O4 at 350–500 °C, to Fe3O4/FeO at 500–600 °C and finally to Feo at 700 °C. The formed Feo can then be oxidized by H2O to produce H2 and Fe3O4, as shown by Mössbauer and XRD analyses. Cyclic experiments showed that iron could be consecutively reduced/oxidized at least 5 times without any significant decrease in H2 production after the second cycle. However, reactions of Fe2O3 with ethanol at higher temperatures, i.e., 800 and 900 °C, led to the formation of iron carbide and significant carbon deposition. XPS, SEM, TEM, Raman and TG showed 24–28 wt% carbon content, particularly on the surface as nanofibers and as amorphous and graphitic carbon. |
publishDate |
2012 |
dc.date.none.fl_str_mv |
2012-04-05 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/104434 Rosmaninho, Marcelo G.; Moura, Flávia C.; Souza, Lívia Ribeiro de ; Nogueira, R.K.; Gomes, G.M.; et al.; Investigation of iron oxide reduction by ethanol as a potential route to produce hydrogen; Elsevier Science; Applied Catalysis B: Environmental; 115-116; 5-4-2012; 45-52 0926-3373 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/104434 |
identifier_str_mv |
Rosmaninho, Marcelo G.; Moura, Flávia C.; Souza, Lívia Ribeiro de ; Nogueira, R.K.; Gomes, G.M.; et al.; Investigation of iron oxide reduction by ethanol as a potential route to produce hydrogen; Elsevier Science; Applied Catalysis B: Environmental; 115-116; 5-4-2012; 45-52 0926-3373 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0926337311005479 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2011.11.038 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614224764993536 |
score |
13.070432 |