Self-limiting robust surface-grafted organic nanofilms

Autores
Todd Banner, L.; Tekobo, Samuel; Garay, Fernando Sebastian; Clayton, Benjamin T.; Thomas, Zachary P.; Lindner, Ernö; Richter, Andrew G.; Pinkhassik, Eugene
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Robust surface-bound insulating polymer films with controlled thickness in <5 nm range are important for technological advances in diverse disciplines such as electrochemical sensors, molecular electronics, separations, and anticorrosive coatings. Creating these films by simple methods from readily available materials has been a significant challenge. Here we report a newly synthesized molecule combining styrene and thiol moieties, joined via a short linker, that binds to the gold surface, polymerizes, and cross-links polymer chains to form robust films with uniform and controlled thickness and complete surface coverage. Additional layers can be deposited. These films that bridge two- and three-dimensional materials show excellent stability and insulating properties.
Fil: Todd Banner, L.. University of Memphis; Estados Unidos
Fil: Tekobo, Samuel. University of Memphis; Estados Unidos
Fil: Garay, Fernando Sebastian. University of Memphis; Estados Unidos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Clayton, Benjamin T.. University of Memphis; Estados Unidos
Fil: Thomas, Zachary P.. University of Memphis; Estados Unidos
Fil: Lindner, Ernö. University of Memphis; Estados Unidos
Fil: Richter, Andrew G.. University of Memphis; Estados Unidos
Fil: Pinkhassik, Eugene. University of Memphis; Estados Unidos
Materia
Nanofilm
Nanothin Coating
3-(4-Vinylphenyl)Propane-1-Thiol
Anticorrosive Polymer
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/71485
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/71485
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Self-limiting robust surface-grafted organic nanofilmsTodd Banner, L.Tekobo, SamuelGaray, Fernando SebastianClayton, Benjamin T.Thomas, Zachary P.Lindner, ErnöRichter, Andrew G.Pinkhassik, EugeneNanofilmNanothin Coating3-(4-Vinylphenyl)Propane-1-ThiolAnticorrosive Polymerhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Robust surface-bound insulating polymer films with controlled thickness in <5 nm range are important for technological advances in diverse disciplines such as electrochemical sensors, molecular electronics, separations, and anticorrosive coatings. Creating these films by simple methods from readily available materials has been a significant challenge. Here we report a newly synthesized molecule combining styrene and thiol moieties, joined via a short linker, that binds to the gold surface, polymerizes, and cross-links polymer chains to form robust films with uniform and controlled thickness and complete surface coverage. Additional layers can be deposited. These films that bridge two- and three-dimensional materials show excellent stability and insulating properties.Fil: Todd Banner, L.. University of Memphis; Estados UnidosFil: Tekobo, Samuel. University of Memphis; Estados UnidosFil: Garay, Fernando Sebastian. University of Memphis; Estados Unidos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Clayton, Benjamin T.. University of Memphis; Estados UnidosFil: Thomas, Zachary P.. University of Memphis; Estados UnidosFil: Lindner, Ernö. University of Memphis; Estados UnidosFil: Richter, Andrew G.. University of Memphis; Estados UnidosFil: Pinkhassik, Eugene. University of Memphis; Estados UnidosAmerican Chemical Society2010-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/71485Todd Banner, L.; Tekobo, Samuel; Garay, Fernando Sebastian; Clayton, Benjamin T.; Thomas, Zachary P.; et al.; Self-limiting robust surface-grafted organic nanofilms; American Chemical Society; Chemistry Of Materials; 22; 7; 4-2010; 2248-22540897-47561520-5002CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/cm903024hinfo:eu-repo/semantics/altIdentifier/doi/10.1021/cm903024hinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:00:10Zoai:ri.conicet.gov.ar:11336/71485instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:00:10.288CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Self-limiting robust surface-grafted organic nanofilms
title Self-limiting robust surface-grafted organic nanofilms
spellingShingle Self-limiting robust surface-grafted organic nanofilms
Todd Banner, L.
Nanofilm
Nanothin Coating
3-(4-Vinylphenyl)Propane-1-Thiol
Anticorrosive Polymer
title_short Self-limiting robust surface-grafted organic nanofilms
title_full Self-limiting robust surface-grafted organic nanofilms
title_fullStr Self-limiting robust surface-grafted organic nanofilms
title_full_unstemmed Self-limiting robust surface-grafted organic nanofilms
title_sort Self-limiting robust surface-grafted organic nanofilms
dc.creator.none.fl_str_mv Todd Banner, L.
Tekobo, Samuel
Garay, Fernando Sebastian
Clayton, Benjamin T.
Thomas, Zachary P.
Lindner, Ernö
Richter, Andrew G.
Pinkhassik, Eugene
author Todd Banner, L.
author_facet Todd Banner, L.
Tekobo, Samuel
Garay, Fernando Sebastian
Clayton, Benjamin T.
Thomas, Zachary P.
Lindner, Ernö
Richter, Andrew G.
Pinkhassik, Eugene
author_role author
author2 Tekobo, Samuel
Garay, Fernando Sebastian
Clayton, Benjamin T.
Thomas, Zachary P.
Lindner, Ernö
Richter, Andrew G.
Pinkhassik, Eugene
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Nanofilm
Nanothin Coating
3-(4-Vinylphenyl)Propane-1-Thiol
Anticorrosive Polymer
topic Nanofilm
Nanothin Coating
3-(4-Vinylphenyl)Propane-1-Thiol
Anticorrosive Polymer
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Robust surface-bound insulating polymer films with controlled thickness in <5 nm range are important for technological advances in diverse disciplines such as electrochemical sensors, molecular electronics, separations, and anticorrosive coatings. Creating these films by simple methods from readily available materials has been a significant challenge. Here we report a newly synthesized molecule combining styrene and thiol moieties, joined via a short linker, that binds to the gold surface, polymerizes, and cross-links polymer chains to form robust films with uniform and controlled thickness and complete surface coverage. Additional layers can be deposited. These films that bridge two- and three-dimensional materials show excellent stability and insulating properties.
Fil: Todd Banner, L.. University of Memphis; Estados Unidos
Fil: Tekobo, Samuel. University of Memphis; Estados Unidos
Fil: Garay, Fernando Sebastian. University of Memphis; Estados Unidos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Clayton, Benjamin T.. University of Memphis; Estados Unidos
Fil: Thomas, Zachary P.. University of Memphis; Estados Unidos
Fil: Lindner, Ernö. University of Memphis; Estados Unidos
Fil: Richter, Andrew G.. University of Memphis; Estados Unidos
Fil: Pinkhassik, Eugene. University of Memphis; Estados Unidos
description Robust surface-bound insulating polymer films with controlled thickness in <5 nm range are important for technological advances in diverse disciplines such as electrochemical sensors, molecular electronics, separations, and anticorrosive coatings. Creating these films by simple methods from readily available materials has been a significant challenge. Here we report a newly synthesized molecule combining styrene and thiol moieties, joined via a short linker, that binds to the gold surface, polymerizes, and cross-links polymer chains to form robust films with uniform and controlled thickness and complete surface coverage. Additional layers can be deposited. These films that bridge two- and three-dimensional materials show excellent stability and insulating properties.
publishDate 2010
dc.date.none.fl_str_mv 2010-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/71485
Todd Banner, L.; Tekobo, Samuel; Garay, Fernando Sebastian; Clayton, Benjamin T.; Thomas, Zachary P.; et al.; Self-limiting robust surface-grafted organic nanofilms; American Chemical Society; Chemistry Of Materials; 22; 7; 4-2010; 2248-2254
0897-4756
1520-5002
CONICET Digital
CONICET
url http://hdl.handle.net/11336/71485
identifier_str_mv Todd Banner, L.; Tekobo, Samuel; Garay, Fernando Sebastian; Clayton, Benjamin T.; Thomas, Zachary P.; et al.; Self-limiting robust surface-grafted organic nanofilms; American Chemical Society; Chemistry Of Materials; 22; 7; 4-2010; 2248-2254
0897-4756
1520-5002
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/cm903024h
info:eu-repo/semantics/altIdentifier/doi/10.1021/cm903024h
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083140563501056
score 13.22299

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