Self-limiting robust surface-grafted organic nanofilms
- Autores
- Todd Banner, L.; Tekobo, Samuel; Garay, Fernando Sebastian; Clayton, Benjamin T.; Thomas, Zachary P.; Lindner, Ernö; Richter, Andrew G.; Pinkhassik, Eugene
- Año de publicación
- 2010
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Robust surface-bound insulating polymer films with controlled thickness in <5 nm range are important for technological advances in diverse disciplines such as electrochemical sensors, molecular electronics, separations, and anticorrosive coatings. Creating these films by simple methods from readily available materials has been a significant challenge. Here we report a newly synthesized molecule combining styrene and thiol moieties, joined via a short linker, that binds to the gold surface, polymerizes, and cross-links polymer chains to form robust films with uniform and controlled thickness and complete surface coverage. Additional layers can be deposited. These films that bridge two- and three-dimensional materials show excellent stability and insulating properties.
Fil: Todd Banner, L.. University of Memphis; Estados Unidos
Fil: Tekobo, Samuel. University of Memphis; Estados Unidos
Fil: Garay, Fernando Sebastian. University of Memphis; Estados Unidos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Clayton, Benjamin T.. University of Memphis; Estados Unidos
Fil: Thomas, Zachary P.. University of Memphis; Estados Unidos
Fil: Lindner, Ernö. University of Memphis; Estados Unidos
Fil: Richter, Andrew G.. University of Memphis; Estados Unidos
Fil: Pinkhassik, Eugene. University of Memphis; Estados Unidos - Materia
-
Nanofilm
Nanothin Coating
3-(4-Vinylphenyl)Propane-1-Thiol
Anticorrosive Polymer - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/71485
Ver los metadatos del registro completo
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3498 |
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spelling |
Self-limiting robust surface-grafted organic nanofilmsTodd Banner, L.Tekobo, SamuelGaray, Fernando SebastianClayton, Benjamin T.Thomas, Zachary P.Lindner, ErnöRichter, Andrew G.Pinkhassik, EugeneNanofilmNanothin Coating3-(4-Vinylphenyl)Propane-1-ThiolAnticorrosive Polymerhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Robust surface-bound insulating polymer films with controlled thickness in <5 nm range are important for technological advances in diverse disciplines such as electrochemical sensors, molecular electronics, separations, and anticorrosive coatings. Creating these films by simple methods from readily available materials has been a significant challenge. Here we report a newly synthesized molecule combining styrene and thiol moieties, joined via a short linker, that binds to the gold surface, polymerizes, and cross-links polymer chains to form robust films with uniform and controlled thickness and complete surface coverage. Additional layers can be deposited. These films that bridge two- and three-dimensional materials show excellent stability and insulating properties.Fil: Todd Banner, L.. University of Memphis; Estados UnidosFil: Tekobo, Samuel. University of Memphis; Estados UnidosFil: Garay, Fernando Sebastian. University of Memphis; Estados Unidos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Clayton, Benjamin T.. University of Memphis; Estados UnidosFil: Thomas, Zachary P.. University of Memphis; Estados UnidosFil: Lindner, Ernö. University of Memphis; Estados UnidosFil: Richter, Andrew G.. University of Memphis; Estados UnidosFil: Pinkhassik, Eugene. University of Memphis; Estados UnidosAmerican Chemical Society2010-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/71485Todd Banner, L.; Tekobo, Samuel; Garay, Fernando Sebastian; Clayton, Benjamin T.; Thomas, Zachary P.; et al.; Self-limiting robust surface-grafted organic nanofilms; American Chemical Society; Chemistry Of Materials; 22; 7; 4-2010; 2248-22540897-47561520-5002CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/cm903024hinfo:eu-repo/semantics/altIdentifier/doi/10.1021/cm903024hinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:03:33Zoai:ri.conicet.gov.ar:11336/71485instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:03:33.617CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Self-limiting robust surface-grafted organic nanofilms |
title |
Self-limiting robust surface-grafted organic nanofilms |
spellingShingle |
Self-limiting robust surface-grafted organic nanofilms Todd Banner, L. Nanofilm Nanothin Coating 3-(4-Vinylphenyl)Propane-1-Thiol Anticorrosive Polymer |
title_short |
Self-limiting robust surface-grafted organic nanofilms |
title_full |
Self-limiting robust surface-grafted organic nanofilms |
title_fullStr |
Self-limiting robust surface-grafted organic nanofilms |
title_full_unstemmed |
Self-limiting robust surface-grafted organic nanofilms |
title_sort |
Self-limiting robust surface-grafted organic nanofilms |
dc.creator.none.fl_str_mv |
Todd Banner, L. Tekobo, Samuel Garay, Fernando Sebastian Clayton, Benjamin T. Thomas, Zachary P. Lindner, Ernö Richter, Andrew G. Pinkhassik, Eugene |
author |
Todd Banner, L. |
author_facet |
Todd Banner, L. Tekobo, Samuel Garay, Fernando Sebastian Clayton, Benjamin T. Thomas, Zachary P. Lindner, Ernö Richter, Andrew G. Pinkhassik, Eugene |
author_role |
author |
author2 |
Tekobo, Samuel Garay, Fernando Sebastian Clayton, Benjamin T. Thomas, Zachary P. Lindner, Ernö Richter, Andrew G. Pinkhassik, Eugene |
author2_role |
author author author author author author author |
dc.subject.none.fl_str_mv |
Nanofilm Nanothin Coating 3-(4-Vinylphenyl)Propane-1-Thiol Anticorrosive Polymer |
topic |
Nanofilm Nanothin Coating 3-(4-Vinylphenyl)Propane-1-Thiol Anticorrosive Polymer |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Robust surface-bound insulating polymer films with controlled thickness in <5 nm range are important for technological advances in diverse disciplines such as electrochemical sensors, molecular electronics, separations, and anticorrosive coatings. Creating these films by simple methods from readily available materials has been a significant challenge. Here we report a newly synthesized molecule combining styrene and thiol moieties, joined via a short linker, that binds to the gold surface, polymerizes, and cross-links polymer chains to form robust films with uniform and controlled thickness and complete surface coverage. Additional layers can be deposited. These films that bridge two- and three-dimensional materials show excellent stability and insulating properties. Fil: Todd Banner, L.. University of Memphis; Estados Unidos Fil: Tekobo, Samuel. University of Memphis; Estados Unidos Fil: Garay, Fernando Sebastian. University of Memphis; Estados Unidos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina Fil: Clayton, Benjamin T.. University of Memphis; Estados Unidos Fil: Thomas, Zachary P.. University of Memphis; Estados Unidos Fil: Lindner, Ernö. University of Memphis; Estados Unidos Fil: Richter, Andrew G.. University of Memphis; Estados Unidos Fil: Pinkhassik, Eugene. University of Memphis; Estados Unidos |
description |
Robust surface-bound insulating polymer films with controlled thickness in <5 nm range are important for technological advances in diverse disciplines such as electrochemical sensors, molecular electronics, separations, and anticorrosive coatings. Creating these films by simple methods from readily available materials has been a significant challenge. Here we report a newly synthesized molecule combining styrene and thiol moieties, joined via a short linker, that binds to the gold surface, polymerizes, and cross-links polymer chains to form robust films with uniform and controlled thickness and complete surface coverage. Additional layers can be deposited. These films that bridge two- and three-dimensional materials show excellent stability and insulating properties. |
publishDate |
2010 |
dc.date.none.fl_str_mv |
2010-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/71485 Todd Banner, L.; Tekobo, Samuel; Garay, Fernando Sebastian; Clayton, Benjamin T.; Thomas, Zachary P.; et al.; Self-limiting robust surface-grafted organic nanofilms; American Chemical Society; Chemistry Of Materials; 22; 7; 4-2010; 2248-2254 0897-4756 1520-5002 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/71485 |
identifier_str_mv |
Todd Banner, L.; Tekobo, Samuel; Garay, Fernando Sebastian; Clayton, Benjamin T.; Thomas, Zachary P.; et al.; Self-limiting robust surface-grafted organic nanofilms; American Chemical Society; Chemistry Of Materials; 22; 7; 4-2010; 2248-2254 0897-4756 1520-5002 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/cm903024h info:eu-repo/semantics/altIdentifier/doi/10.1021/cm903024h |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613853228302336 |
score |
13.070432 |