Compact and general strategy for solving current and potential distribution in electrochemical cells composed of massive monopolar and bipolar electrodes

Autores
Colli, Alejandro Nicolás; Girault, H. H.
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A compact, fast and general algorithm based on Dirichlet boundary conditions for the potential field is derived to enable the calculation of local current distribution, shunt currents and the local potential distribution on massive electrodes in electrochemical cells of any type of geometry in three dimensions, composed of bipolar electrodes at an unknown floating potential and/or terminal monopolar electrodes. The algorithm allows performing the calculation of current-potential distributions and bypass currents for a fixed cell potential (potentiostatic) or a fixed cell current (galvanostatic) enforced to the cell. The proposed approach can be extended to take into account concentration variations of one or several species inside the cell or electrical conductivity variations due to the presence of separators or liquid-gas-solid phases. In order to validate the algorithm, a detailed comparison, between the suggested strategy with experimental results is made in the case of secondary current distribution for i) a segmented one bipolar electrode ii) a cell stack composed of 14 bipolar electrodes in the industrial process of alkaline water electrolysis. The proposed tool can help designers to develop more efficient electrochemical reactors by comparing results using different electrode materials, electrolytes and cell designs.
Fil: Colli, Alejandro Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Ecole Polytechnique Federale de Lausanne; Suiza
Fil: Girault, H. H.. Ecole Polytechnique Federale de Lausanne; Suiza
Materia
algorithm
shunt currents
alkaline water electrolysis
bipolar electrodes
galvanostatic control
potentiostatic control
current distribution
hydrogen-oxygen evolution
potential distribution
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/68067
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Compact and general strategy for solving current and potential distribution in electrochemical cells composed of massive monopolar and bipolar electrodesColli, Alejandro NicolásGirault, H. H.algorithmshunt currentsalkaline water electrolysisbipolar electrodesgalvanostatic controlpotentiostatic controlcurrent distributionhydrogen-oxygen evolutionpotential distributionhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2A compact, fast and general algorithm based on Dirichlet boundary conditions for the potential field is derived to enable the calculation of local current distribution, shunt currents and the local potential distribution on massive electrodes in electrochemical cells of any type of geometry in three dimensions, composed of bipolar electrodes at an unknown floating potential and/or terminal monopolar electrodes. The algorithm allows performing the calculation of current-potential distributions and bypass currents for a fixed cell potential (potentiostatic) or a fixed cell current (galvanostatic) enforced to the cell. The proposed approach can be extended to take into account concentration variations of one or several species inside the cell or electrical conductivity variations due to the presence of separators or liquid-gas-solid phases. In order to validate the algorithm, a detailed comparison, between the suggested strategy with experimental results is made in the case of secondary current distribution for i) a segmented one bipolar electrode ii) a cell stack composed of 14 bipolar electrodes in the industrial process of alkaline water electrolysis. The proposed tool can help designers to develop more efficient electrochemical reactors by comparing results using different electrode materials, electrolytes and cell designs.Fil: Colli, Alejandro Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Ecole Polytechnique Federale de Lausanne; SuizaFil: Girault, H. H.. Ecole Polytechnique Federale de Lausanne; SuizaElectrochemical Society2017-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/68067Colli, Alejandro Nicolás; Girault, H. H.; Compact and general strategy for solving current and potential distribution in electrochemical cells composed of massive monopolar and bipolar electrodes; Electrochemical Society; Journal of the Electrochemical Society; 164; 11; 11-2017; E3465-E34720013-46511945-7111CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://jes.ecsdl.org/content/164/11/E3465info:eu-repo/semantics/altIdentifier/doi/10.1149/2.0471711jesinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:20:24Zoai:ri.conicet.gov.ar:11336/68067instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:20:25.273CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Compact and general strategy for solving current and potential distribution in electrochemical cells composed of massive monopolar and bipolar electrodes
title Compact and general strategy for solving current and potential distribution in electrochemical cells composed of massive monopolar and bipolar electrodes
spellingShingle Compact and general strategy for solving current and potential distribution in electrochemical cells composed of massive monopolar and bipolar electrodes
Colli, Alejandro Nicolás
algorithm
shunt currents
alkaline water electrolysis
bipolar electrodes
galvanostatic control
potentiostatic control
current distribution
hydrogen-oxygen evolution
potential distribution
title_short Compact and general strategy for solving current and potential distribution in electrochemical cells composed of massive monopolar and bipolar electrodes
title_full Compact and general strategy for solving current and potential distribution in electrochemical cells composed of massive monopolar and bipolar electrodes
title_fullStr Compact and general strategy for solving current and potential distribution in electrochemical cells composed of massive monopolar and bipolar electrodes
title_full_unstemmed Compact and general strategy for solving current and potential distribution in electrochemical cells composed of massive monopolar and bipolar electrodes
title_sort Compact and general strategy for solving current and potential distribution in electrochemical cells composed of massive monopolar and bipolar electrodes
dc.creator.none.fl_str_mv Colli, Alejandro Nicolás
Girault, H. H.
author Colli, Alejandro Nicolás
author_facet Colli, Alejandro Nicolás
Girault, H. H.
author_role author
author2 Girault, H. H.
author2_role author
dc.subject.none.fl_str_mv algorithm
shunt currents
alkaline water electrolysis
bipolar electrodes
galvanostatic control
potentiostatic control
current distribution
hydrogen-oxygen evolution
potential distribution
topic algorithm
shunt currents
alkaline water electrolysis
bipolar electrodes
galvanostatic control
potentiostatic control
current distribution
hydrogen-oxygen evolution
potential distribution
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A compact, fast and general algorithm based on Dirichlet boundary conditions for the potential field is derived to enable the calculation of local current distribution, shunt currents and the local potential distribution on massive electrodes in electrochemical cells of any type of geometry in three dimensions, composed of bipolar electrodes at an unknown floating potential and/or terminal monopolar electrodes. The algorithm allows performing the calculation of current-potential distributions and bypass currents for a fixed cell potential (potentiostatic) or a fixed cell current (galvanostatic) enforced to the cell. The proposed approach can be extended to take into account concentration variations of one or several species inside the cell or electrical conductivity variations due to the presence of separators or liquid-gas-solid phases. In order to validate the algorithm, a detailed comparison, between the suggested strategy with experimental results is made in the case of secondary current distribution for i) a segmented one bipolar electrode ii) a cell stack composed of 14 bipolar electrodes in the industrial process of alkaline water electrolysis. The proposed tool can help designers to develop more efficient electrochemical reactors by comparing results using different electrode materials, electrolytes and cell designs.
Fil: Colli, Alejandro Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Ecole Polytechnique Federale de Lausanne; Suiza
Fil: Girault, H. H.. Ecole Polytechnique Federale de Lausanne; Suiza
description A compact, fast and general algorithm based on Dirichlet boundary conditions for the potential field is derived to enable the calculation of local current distribution, shunt currents and the local potential distribution on massive electrodes in electrochemical cells of any type of geometry in three dimensions, composed of bipolar electrodes at an unknown floating potential and/or terminal monopolar electrodes. The algorithm allows performing the calculation of current-potential distributions and bypass currents for a fixed cell potential (potentiostatic) or a fixed cell current (galvanostatic) enforced to the cell. The proposed approach can be extended to take into account concentration variations of one or several species inside the cell or electrical conductivity variations due to the presence of separators or liquid-gas-solid phases. In order to validate the algorithm, a detailed comparison, between the suggested strategy with experimental results is made in the case of secondary current distribution for i) a segmented one bipolar electrode ii) a cell stack composed of 14 bipolar electrodes in the industrial process of alkaline water electrolysis. The proposed tool can help designers to develop more efficient electrochemical reactors by comparing results using different electrode materials, electrolytes and cell designs.
publishDate 2017
dc.date.none.fl_str_mv 2017-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/68067
Colli, Alejandro Nicolás; Girault, H. H.; Compact and general strategy for solving current and potential distribution in electrochemical cells composed of massive monopolar and bipolar electrodes; Electrochemical Society; Journal of the Electrochemical Society; 164; 11; 11-2017; E3465-E3472
0013-4651
1945-7111
CONICET Digital
CONICET
url http://hdl.handle.net/11336/68067
identifier_str_mv Colli, Alejandro Nicolás; Girault, H. H.; Compact and general strategy for solving current and potential distribution in electrochemical cells composed of massive monopolar and bipolar electrodes; Electrochemical Society; Journal of the Electrochemical Society; 164; 11; 11-2017; E3465-E3472
0013-4651
1945-7111
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://jes.ecsdl.org/content/164/11/E3465
info:eu-repo/semantics/altIdentifier/doi/10.1149/2.0471711jes
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Electrochemical Society
publisher.none.fl_str_mv Electrochemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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