Ni and NixCoy alloys electrodeposited on stainless steel AISI 316L for hydrogen evolution reaction

Autores
Gomez, Melisa Julieta; Franceschini, Esteban Andrés; Lacconi, Gabriela Ines
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
NixCoy electrocatalysts for hydrogen evolution reaction (HER) were synthesized by electrodeposition on AISI 316L stainless steel (denoted as SS316L), as a scalable and economical alternative to be used in alkaline electrolyzers. For this, a previous treatment of the SS316L surface was carried out in order to optimize the deposition of different catalytic films containing Ni and NixCoy with different compositions (Ni89Co11, Ni69Co31, and Ni29Co71). The properties of the catalysts were established by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD), and the catalytic activity for HER was evaluated by potentiodynamic experiments in 1 M KOH solutions. An increase in the current density toward the hydrogen evolution reaction was found with these NixCoy electrodes. For the Ni69Co31 catalyst, current density values 112% higher than those recorded with deposited Ni from conventional Watts bath were obtained. The HER current shows a strong dependence on the content of Co on the alloy that is also evidenced in the electrochemical impedance experiments. The efficiency of electrocatalytic activity for HER was increased after an electrochemical aging treatment, indicating the presence of an activation process, for example with Ni89Co11 electrodes, where higher current density for HER was observed.
Fil: Gomez, Melisa Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Franceschini, Esteban Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Lacconi, Gabriela Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
ALKALINE ELECTROLYSIS
ELECTRODEPOSITION
HYDROGEN EVOLUTION REACTION
NICKEL
NICKEL COBALT
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/86345
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/86345
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Ni and NixCoy alloys electrodeposited on stainless steel AISI 316L for hydrogen evolution reactionGomez, Melisa JulietaFranceschini, Esteban AndrésLacconi, Gabriela InesALKALINE ELECTROLYSISELECTRODEPOSITIONHYDROGEN EVOLUTION REACTIONNICKELNICKEL COBALThttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1NixCoy electrocatalysts for hydrogen evolution reaction (HER) were synthesized by electrodeposition on AISI 316L stainless steel (denoted as SS316L), as a scalable and economical alternative to be used in alkaline electrolyzers. For this, a previous treatment of the SS316L surface was carried out in order to optimize the deposition of different catalytic films containing Ni and NixCoy with different compositions (Ni89Co11, Ni69Co31, and Ni29Co71). The properties of the catalysts were established by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD), and the catalytic activity for HER was evaluated by potentiodynamic experiments in 1 M KOH solutions. An increase in the current density toward the hydrogen evolution reaction was found with these NixCoy electrodes. For the Ni69Co31 catalyst, current density values 112% higher than those recorded with deposited Ni from conventional Watts bath were obtained. The HER current shows a strong dependence on the content of Co on the alloy that is also evidenced in the electrochemical impedance experiments. The efficiency of electrocatalytic activity for HER was increased after an electrochemical aging treatment, indicating the presence of an activation process, for example with Ni89Co11 electrodes, where higher current density for HER was observed.Fil: Gomez, Melisa Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Franceschini, Esteban Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Lacconi, Gabriela Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaSpringer New York LLC2018-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/86345Gomez, Melisa Julieta; Franceschini, Esteban Andrés; Lacconi, Gabriela Ines; Ni and NixCoy alloys electrodeposited on stainless steel AISI 316L for hydrogen evolution reaction; Springer New York LLC; Electrocatalysis; 9; 4; 7-2018; 459-4701868-25291868-5994CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://link.springer.com/10.1007/s12678-018-0463-5info:eu-repo/semantics/altIdentifier/doi/10.1007/s12678-018-0463-5info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:37:46Zoai:ri.conicet.gov.ar:11336/86345instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:37:46.985CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Ni and NixCoy alloys electrodeposited on stainless steel AISI 316L for hydrogen evolution reaction
title Ni and NixCoy alloys electrodeposited on stainless steel AISI 316L for hydrogen evolution reaction
spellingShingle Ni and NixCoy alloys electrodeposited on stainless steel AISI 316L for hydrogen evolution reaction
Gomez, Melisa Julieta
ALKALINE ELECTROLYSIS
ELECTRODEPOSITION
HYDROGEN EVOLUTION REACTION
NICKEL
NICKEL COBALT
title_short Ni and NixCoy alloys electrodeposited on stainless steel AISI 316L for hydrogen evolution reaction
title_full Ni and NixCoy alloys electrodeposited on stainless steel AISI 316L for hydrogen evolution reaction
title_fullStr Ni and NixCoy alloys electrodeposited on stainless steel AISI 316L for hydrogen evolution reaction
title_full_unstemmed Ni and NixCoy alloys electrodeposited on stainless steel AISI 316L for hydrogen evolution reaction
title_sort Ni and NixCoy alloys electrodeposited on stainless steel AISI 316L for hydrogen evolution reaction
dc.creator.none.fl_str_mv Gomez, Melisa Julieta
Franceschini, Esteban Andrés
Lacconi, Gabriela Ines
author Gomez, Melisa Julieta
author_facet Gomez, Melisa Julieta
Franceschini, Esteban Andrés
Lacconi, Gabriela Ines
author_role author
author2 Franceschini, Esteban Andrés
Lacconi, Gabriela Ines
author2_role author
author
dc.subject.none.fl_str_mv ALKALINE ELECTROLYSIS
ELECTRODEPOSITION
HYDROGEN EVOLUTION REACTION
NICKEL
NICKEL COBALT
topic ALKALINE ELECTROLYSIS
ELECTRODEPOSITION
HYDROGEN EVOLUTION REACTION
NICKEL
NICKEL COBALT
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv NixCoy electrocatalysts for hydrogen evolution reaction (HER) were synthesized by electrodeposition on AISI 316L stainless steel (denoted as SS316L), as a scalable and economical alternative to be used in alkaline electrolyzers. For this, a previous treatment of the SS316L surface was carried out in order to optimize the deposition of different catalytic films containing Ni and NixCoy with different compositions (Ni89Co11, Ni69Co31, and Ni29Co71). The properties of the catalysts were established by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD), and the catalytic activity for HER was evaluated by potentiodynamic experiments in 1 M KOH solutions. An increase in the current density toward the hydrogen evolution reaction was found with these NixCoy electrodes. For the Ni69Co31 catalyst, current density values 112% higher than those recorded with deposited Ni from conventional Watts bath were obtained. The HER current shows a strong dependence on the content of Co on the alloy that is also evidenced in the electrochemical impedance experiments. The efficiency of electrocatalytic activity for HER was increased after an electrochemical aging treatment, indicating the presence of an activation process, for example with Ni89Co11 electrodes, where higher current density for HER was observed.
Fil: Gomez, Melisa Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Franceschini, Esteban Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Lacconi, Gabriela Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description NixCoy electrocatalysts for hydrogen evolution reaction (HER) were synthesized by electrodeposition on AISI 316L stainless steel (denoted as SS316L), as a scalable and economical alternative to be used in alkaline electrolyzers. For this, a previous treatment of the SS316L surface was carried out in order to optimize the deposition of different catalytic films containing Ni and NixCoy with different compositions (Ni89Co11, Ni69Co31, and Ni29Co71). The properties of the catalysts were established by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD), and the catalytic activity for HER was evaluated by potentiodynamic experiments in 1 M KOH solutions. An increase in the current density toward the hydrogen evolution reaction was found with these NixCoy electrodes. For the Ni69Co31 catalyst, current density values 112% higher than those recorded with deposited Ni from conventional Watts bath were obtained. The HER current shows a strong dependence on the content of Co on the alloy that is also evidenced in the electrochemical impedance experiments. The efficiency of electrocatalytic activity for HER was increased after an electrochemical aging treatment, indicating the presence of an activation process, for example with Ni89Co11 electrodes, where higher current density for HER was observed.
publishDate 2018
dc.date.none.fl_str_mv 2018-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/86345
Gomez, Melisa Julieta; Franceschini, Esteban Andrés; Lacconi, Gabriela Ines; Ni and NixCoy alloys electrodeposited on stainless steel AISI 316L for hydrogen evolution reaction; Springer New York LLC; Electrocatalysis; 9; 4; 7-2018; 459-470
1868-2529
1868-5994
CONICET Digital
CONICET
url http://hdl.handle.net/11336/86345
identifier_str_mv Gomez, Melisa Julieta; Franceschini, Esteban Andrés; Lacconi, Gabriela Ines; Ni and NixCoy alloys electrodeposited on stainless steel AISI 316L for hydrogen evolution reaction; Springer New York LLC; Electrocatalysis; 9; 4; 7-2018; 459-470
1868-2529
1868-5994
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://link.springer.com/10.1007/s12678-018-0463-5
info:eu-repo/semantics/altIdentifier/doi/10.1007/s12678-018-0463-5
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer New York LLC
publisher.none.fl_str_mv Springer New York LLC
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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