Physical Model for the Current-Voltage Hysteresis and Impedance of Halide Perovskite Memristors
- Autores
- Berruet, Mariana; Pérez Martínez, José Carlos; Romero, Beatriz; Gonzales, Cedric; Al Mayouf, Abdullah M.; Guerrero, Antonio; Bisquert, Juan
- Año de publicación
- 2022
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- An investigation of the kinetic behavior of MAPbI3 memristors shows that the onset voltage to a high conducting state depends strongly on the voltage sweep rate, and the impedance spectra generate complex capacitive and inductive patterns. We develop a dynamic model to describe these features and obtain physical insight into the coupling of ionic and electronic properties that produce the resistive switching behavior. The model separates the memristive response into distinct diffusion and transition-state-formation steps that describe well the experimental current-voltage curves at different scan rates and impedance spectra. The ac impedance analysis shows that the halide perovskite memristor response contains the composition of two inductive processes that provide a huge negative capacitance associated with inverted hysteresis. The results provide a new approach to understand some typical characteristics of halide perovskite devices, such as the inductive behavior and hysteresis effects, according to the time scales of internal processes.
Fil: Berruet, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Pérez Martínez, José Carlos. Universitat Jaume I; España. Universidad Rey Juan Carlos; España
Fil: Romero, Beatriz. Universidad Rey Juan Carlos; España
Fil: Gonzales, Cedric. Universitat Jaume I. Instituto de Investigación de Materiales Avanzados.; España
Fil: Al Mayouf, Abdullah M.. King Saud University; Arabia Saudita
Fil: Guerrero, Antonio. Universitat Jaume I; España
Fil: Bisquert, Juan. Universitat Jaume I; España. Yonsei University; Corea del Sur - Materia
-
MEMRISTOR
HALIDE PEROVSKITE
PHYSICAL MODEL - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/212593
Ver los metadatos del registro completo
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Physical Model for the Current-Voltage Hysteresis and Impedance of Halide Perovskite MemristorsBerruet, MarianaPérez Martínez, José CarlosRomero, BeatrizGonzales, CedricAl Mayouf, Abdullah M.Guerrero, AntonioBisquert, JuanMEMRISTORHALIDE PEROVSKITEPHYSICAL MODELhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1An investigation of the kinetic behavior of MAPbI3 memristors shows that the onset voltage to a high conducting state depends strongly on the voltage sweep rate, and the impedance spectra generate complex capacitive and inductive patterns. We develop a dynamic model to describe these features and obtain physical insight into the coupling of ionic and electronic properties that produce the resistive switching behavior. The model separates the memristive response into distinct diffusion and transition-state-formation steps that describe well the experimental current-voltage curves at different scan rates and impedance spectra. The ac impedance analysis shows that the halide perovskite memristor response contains the composition of two inductive processes that provide a huge negative capacitance associated with inverted hysteresis. The results provide a new approach to understand some typical characteristics of halide perovskite devices, such as the inductive behavior and hysteresis effects, according to the time scales of internal processes.Fil: Berruet, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Pérez Martínez, José Carlos. Universitat Jaume I; España. Universidad Rey Juan Carlos; EspañaFil: Romero, Beatriz. Universidad Rey Juan Carlos; EspañaFil: Gonzales, Cedric. Universitat Jaume I. Instituto de Investigación de Materiales Avanzados.; EspañaFil: Al Mayouf, Abdullah M.. King Saud University; Arabia SauditaFil: Guerrero, Antonio. Universitat Jaume I; EspañaFil: Bisquert, Juan. Universitat Jaume I; España. Yonsei University; Corea del SurAmerican Chemical Society2022-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/212593Berruet, Mariana; Pérez Martínez, José Carlos; Romero, Beatriz; Gonzales, Cedric; Al Mayouf, Abdullah M.; et al.; Physical Model for the Current-Voltage Hysteresis and Impedance of Halide Perovskite Memristors; American Chemical Society; ACS Energy Letters; 7; 3; 3-2022; 1214-12222380-81952380-8195CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acsenergylett.2c00121info:eu-repo/semantics/altIdentifier/doi/10.1021/acsenergylett.2c00121info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:09:47Zoai:ri.conicet.gov.ar:11336/212593instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:09:48.076CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Physical Model for the Current-Voltage Hysteresis and Impedance of Halide Perovskite Memristors |
title |
Physical Model for the Current-Voltage Hysteresis and Impedance of Halide Perovskite Memristors |
spellingShingle |
Physical Model for the Current-Voltage Hysteresis and Impedance of Halide Perovskite Memristors Berruet, Mariana MEMRISTOR HALIDE PEROVSKITE PHYSICAL MODEL |
title_short |
Physical Model for the Current-Voltage Hysteresis and Impedance of Halide Perovskite Memristors |
title_full |
Physical Model for the Current-Voltage Hysteresis and Impedance of Halide Perovskite Memristors |
title_fullStr |
Physical Model for the Current-Voltage Hysteresis and Impedance of Halide Perovskite Memristors |
title_full_unstemmed |
Physical Model for the Current-Voltage Hysteresis and Impedance of Halide Perovskite Memristors |
title_sort |
Physical Model for the Current-Voltage Hysteresis and Impedance of Halide Perovskite Memristors |
dc.creator.none.fl_str_mv |
Berruet, Mariana Pérez Martínez, José Carlos Romero, Beatriz Gonzales, Cedric Al Mayouf, Abdullah M. Guerrero, Antonio Bisquert, Juan |
author |
Berruet, Mariana |
author_facet |
Berruet, Mariana Pérez Martínez, José Carlos Romero, Beatriz Gonzales, Cedric Al Mayouf, Abdullah M. Guerrero, Antonio Bisquert, Juan |
author_role |
author |
author2 |
Pérez Martínez, José Carlos Romero, Beatriz Gonzales, Cedric Al Mayouf, Abdullah M. Guerrero, Antonio Bisquert, Juan |
author2_role |
author author author author author author |
dc.subject.none.fl_str_mv |
MEMRISTOR HALIDE PEROVSKITE PHYSICAL MODEL |
topic |
MEMRISTOR HALIDE PEROVSKITE PHYSICAL MODEL |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.3 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
An investigation of the kinetic behavior of MAPbI3 memristors shows that the onset voltage to a high conducting state depends strongly on the voltage sweep rate, and the impedance spectra generate complex capacitive and inductive patterns. We develop a dynamic model to describe these features and obtain physical insight into the coupling of ionic and electronic properties that produce the resistive switching behavior. The model separates the memristive response into distinct diffusion and transition-state-formation steps that describe well the experimental current-voltage curves at different scan rates and impedance spectra. The ac impedance analysis shows that the halide perovskite memristor response contains the composition of two inductive processes that provide a huge negative capacitance associated with inverted hysteresis. The results provide a new approach to understand some typical characteristics of halide perovskite devices, such as the inductive behavior and hysteresis effects, according to the time scales of internal processes. Fil: Berruet, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Pérez Martínez, José Carlos. Universitat Jaume I; España. Universidad Rey Juan Carlos; España Fil: Romero, Beatriz. Universidad Rey Juan Carlos; España Fil: Gonzales, Cedric. Universitat Jaume I. Instituto de Investigación de Materiales Avanzados.; España Fil: Al Mayouf, Abdullah M.. King Saud University; Arabia Saudita Fil: Guerrero, Antonio. Universitat Jaume I; España Fil: Bisquert, Juan. Universitat Jaume I; España. Yonsei University; Corea del Sur |
description |
An investigation of the kinetic behavior of MAPbI3 memristors shows that the onset voltage to a high conducting state depends strongly on the voltage sweep rate, and the impedance spectra generate complex capacitive and inductive patterns. We develop a dynamic model to describe these features and obtain physical insight into the coupling of ionic and electronic properties that produce the resistive switching behavior. The model separates the memristive response into distinct diffusion and transition-state-formation steps that describe well the experimental current-voltage curves at different scan rates and impedance spectra. The ac impedance analysis shows that the halide perovskite memristor response contains the composition of two inductive processes that provide a huge negative capacitance associated with inverted hysteresis. The results provide a new approach to understand some typical characteristics of halide perovskite devices, such as the inductive behavior and hysteresis effects, according to the time scales of internal processes. |
publishDate |
2022 |
dc.date.none.fl_str_mv |
2022-03 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/212593 Berruet, Mariana; Pérez Martínez, José Carlos; Romero, Beatriz; Gonzales, Cedric; Al Mayouf, Abdullah M.; et al.; Physical Model for the Current-Voltage Hysteresis and Impedance of Halide Perovskite Memristors; American Chemical Society; ACS Energy Letters; 7; 3; 3-2022; 1214-1222 2380-8195 2380-8195 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/212593 |
identifier_str_mv |
Berruet, Mariana; Pérez Martínez, José Carlos; Romero, Beatriz; Gonzales, Cedric; Al Mayouf, Abdullah M.; et al.; Physical Model for the Current-Voltage Hysteresis and Impedance of Halide Perovskite Memristors; American Chemical Society; ACS Energy Letters; 7; 3; 3-2022; 1214-1222 2380-8195 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acsenergylett.2c00121 info:eu-repo/semantics/altIdentifier/doi/10.1021/acsenergylett.2c00121 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613980012675072 |
score |
13.070432 |