Electrochemical Determination of Cu(II) Using a Glassy Carbon Electrode Modified with Multiwall Carbon Nanotubes Dispersed in Polyhistidine

Autores
Dalmasso, Pablo Roberto; Pedano, Maria Laura; Rivas, Gustavo Adolfo
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We report the sensitive and selective quantification of Cu(II) at glassy carbon electrodes (GCE) modified with multiwall carbon nanotubes (MWCNT) dispersed in polyhistidine (Polyhis), (GCE/MWCNT[BOND]Polyhis) based on the complexation of Cu(II) by the histidine residues and further reduction by Differential Pulse Voltammetry in acetate buffer solution. The sensitivity was (3.6±0.3)×106 µA M−1, the reproducibility 6.6 %, and the detection limit 75 nM (4.8 µg L−1). The quantification of Cu(II) was highly selective even in the presence of excess of Cd(II), Zn(II), Co(II), Fe(II), Fe(III), Al(III), Pb(II), Cr(III), Mn(II), and Ag(I). The proposed sensor was successfully used for quantifying Cu(II) in tap-water and groundwater samples without any pretreatment.
Fil: Dalmasso, Pablo Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina. Universidad Nacional de Santiago del Estero; Argentina
Fil: Pedano, Maria Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Rivas, Gustavo Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
Copper quantification
Carbon nanotubes dispersion
Polyhistidine
Glassy carbon electrode
Differential pulse voltammetry
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/111909
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/111909
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Electrochemical Determination of Cu(II) Using a Glassy Carbon Electrode Modified with Multiwall Carbon Nanotubes Dispersed in PolyhistidineDalmasso, Pablo RobertoPedano, Maria LauraRivas, Gustavo AdolfoCopper quantificationCarbon nanotubes dispersionPolyhistidineGlassy carbon electrodeDifferential pulse voltammetryhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1We report the sensitive and selective quantification of Cu(II) at glassy carbon electrodes (GCE) modified with multiwall carbon nanotubes (MWCNT) dispersed in polyhistidine (Polyhis), (GCE/MWCNT[BOND]Polyhis) based on the complexation of Cu(II) by the histidine residues and further reduction by Differential Pulse Voltammetry in acetate buffer solution. The sensitivity was (3.6±0.3)×106 µA M−1, the reproducibility 6.6 %, and the detection limit 75 nM (4.8 µg L−1). The quantification of Cu(II) was highly selective even in the presence of excess of Cd(II), Zn(II), Co(II), Fe(II), Fe(III), Al(III), Pb(II), Cr(III), Mn(II), and Ag(I). The proposed sensor was successfully used for quantifying Cu(II) in tap-water and groundwater samples without any pretreatment.Fil: Dalmasso, Pablo Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina. Universidad Nacional de Santiago del Estero; ArgentinaFil: Pedano, Maria Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Rivas, Gustavo Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaWiley VCH Verlag2015-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/111909Dalmasso, Pablo Roberto; Pedano, Maria Laura; Rivas, Gustavo Adolfo; Electrochemical Determination of Cu(II) Using a Glassy Carbon Electrode Modified with Multiwall Carbon Nanotubes Dispersed in Polyhistidine; Wiley VCH Verlag; Electroanalysis; 27; 9; 9-2015; 2164-21701040-0397CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/elan.201500116info:eu-repo/semantics/altIdentifier/doi/10.1002/elan.201500116info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:49:27Zoai:ri.conicet.gov.ar:11336/111909instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:49:27.862CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Electrochemical Determination of Cu(II) Using a Glassy Carbon Electrode Modified with Multiwall Carbon Nanotubes Dispersed in Polyhistidine
title Electrochemical Determination of Cu(II) Using a Glassy Carbon Electrode Modified with Multiwall Carbon Nanotubes Dispersed in Polyhistidine
spellingShingle Electrochemical Determination of Cu(II) Using a Glassy Carbon Electrode Modified with Multiwall Carbon Nanotubes Dispersed in Polyhistidine
Dalmasso, Pablo Roberto
Copper quantification
Carbon nanotubes dispersion
Polyhistidine
Glassy carbon electrode
Differential pulse voltammetry
title_short Electrochemical Determination of Cu(II) Using a Glassy Carbon Electrode Modified with Multiwall Carbon Nanotubes Dispersed in Polyhistidine
title_full Electrochemical Determination of Cu(II) Using a Glassy Carbon Electrode Modified with Multiwall Carbon Nanotubes Dispersed in Polyhistidine
title_fullStr Electrochemical Determination of Cu(II) Using a Glassy Carbon Electrode Modified with Multiwall Carbon Nanotubes Dispersed in Polyhistidine
title_full_unstemmed Electrochemical Determination of Cu(II) Using a Glassy Carbon Electrode Modified with Multiwall Carbon Nanotubes Dispersed in Polyhistidine
title_sort Electrochemical Determination of Cu(II) Using a Glassy Carbon Electrode Modified with Multiwall Carbon Nanotubes Dispersed in Polyhistidine
dc.creator.none.fl_str_mv Dalmasso, Pablo Roberto
Pedano, Maria Laura
Rivas, Gustavo Adolfo
author Dalmasso, Pablo Roberto
author_facet Dalmasso, Pablo Roberto
Pedano, Maria Laura
Rivas, Gustavo Adolfo
author_role author
author2 Pedano, Maria Laura
Rivas, Gustavo Adolfo
author2_role author
author
dc.subject.none.fl_str_mv Copper quantification
Carbon nanotubes dispersion
Polyhistidine
Glassy carbon electrode
Differential pulse voltammetry
topic Copper quantification
Carbon nanotubes dispersion
Polyhistidine
Glassy carbon electrode
Differential pulse voltammetry
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv We report the sensitive and selective quantification of Cu(II) at glassy carbon electrodes (GCE) modified with multiwall carbon nanotubes (MWCNT) dispersed in polyhistidine (Polyhis), (GCE/MWCNT[BOND]Polyhis) based on the complexation of Cu(II) by the histidine residues and further reduction by Differential Pulse Voltammetry in acetate buffer solution. The sensitivity was (3.6±0.3)×106 µA M−1, the reproducibility 6.6 %, and the detection limit 75 nM (4.8 µg L−1). The quantification of Cu(II) was highly selective even in the presence of excess of Cd(II), Zn(II), Co(II), Fe(II), Fe(III), Al(III), Pb(II), Cr(III), Mn(II), and Ag(I). The proposed sensor was successfully used for quantifying Cu(II) in tap-water and groundwater samples without any pretreatment.
Fil: Dalmasso, Pablo Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina. Universidad Nacional de Santiago del Estero; Argentina
Fil: Pedano, Maria Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Rivas, Gustavo Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description We report the sensitive and selective quantification of Cu(II) at glassy carbon electrodes (GCE) modified with multiwall carbon nanotubes (MWCNT) dispersed in polyhistidine (Polyhis), (GCE/MWCNT[BOND]Polyhis) based on the complexation of Cu(II) by the histidine residues and further reduction by Differential Pulse Voltammetry in acetate buffer solution. The sensitivity was (3.6±0.3)×106 µA M−1, the reproducibility 6.6 %, and the detection limit 75 nM (4.8 µg L−1). The quantification of Cu(II) was highly selective even in the presence of excess of Cd(II), Zn(II), Co(II), Fe(II), Fe(III), Al(III), Pb(II), Cr(III), Mn(II), and Ag(I). The proposed sensor was successfully used for quantifying Cu(II) in tap-water and groundwater samples without any pretreatment.
publishDate 2015
dc.date.none.fl_str_mv 2015-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/111909
Dalmasso, Pablo Roberto; Pedano, Maria Laura; Rivas, Gustavo Adolfo; Electrochemical Determination of Cu(II) Using a Glassy Carbon Electrode Modified with Multiwall Carbon Nanotubes Dispersed in Polyhistidine; Wiley VCH Verlag; Electroanalysis; 27; 9; 9-2015; 2164-2170
1040-0397
CONICET Digital
CONICET
url http://hdl.handle.net/11336/111909
identifier_str_mv Dalmasso, Pablo Roberto; Pedano, Maria Laura; Rivas, Gustavo Adolfo; Electrochemical Determination of Cu(II) Using a Glassy Carbon Electrode Modified with Multiwall Carbon Nanotubes Dispersed in Polyhistidine; Wiley VCH Verlag; Electroanalysis; 27; 9; 9-2015; 2164-2170
1040-0397
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/elan.201500116
info:eu-repo/semantics/altIdentifier/doi/10.1002/elan.201500116
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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