Sensing properties, energy transfer mechanism and tuneable particle size processing of luminescent two-dimensional rare earth coordination networks

Autores
Godoy, Agustín Alejandro; Gomez, Germán Ernesto; Kaczmarek, Anna M.; Van Deun, Rik; Furlong, Octavio Javier; Gándara, Felipe; Monge, María A.; Bernini, Maria Celeste; Narda, Griselda Edith
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A new isostructural family of layered coordination networks (CNs) based on rare earth elements and mixed ligands was hydrothermally synthesized and fully characterized. The set of compounds with the general formula [REE(Salicylate)(Succinate)0.5(H2O)] (with REE = Ho or Y) belong to the monoclinic P21/c space group. Top-down methods were implemented in order to obtain nano-sized CN particles for potential application in thin film fabrication. The solid state photoluminescence (SSPL) of the Eu, Tb and Eu/Tb doped samples was explored in terms of excitation/emission spectra, lifetime values and quantification of light emission by the CIE chromaticity calculation. Measurement of the triplet state energy of the ligand at low temperature was carried out by analysing the SSPL of the Y-based compound; energy transfer pathways were studied. According to the high performance of the Tb-doped compound as a green emitter, thermal and chemical sensing assays were carried out.
Fil: Godoy, Agustín Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Kaczmarek, Anna M.. University of Ghent; Bélgica
Fil: Van Deun, Rik. University of Ghent; Bélgica
Fil: Furlong, Octavio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Gándara, Felipe. Instituto de Ciencia de Materiales de Madrid; España
Fil: Monge, María A.. Instituto de Ciencia de Materiales de Madrid; España
Fil: Bernini, Maria Celeste. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Narda, Griselda Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Materia
Sensing Properties
Energy Transfer
Particle Size
Rare Earth Coordination Networks
Luminescence
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/63875
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/63875
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Sensing properties, energy transfer mechanism and tuneable particle size processing of luminescent two-dimensional rare earth coordination networksGodoy, Agustín AlejandroGomez, Germán ErnestoKaczmarek, Anna M.Van Deun, RikFurlong, Octavio JavierGándara, FelipeMonge, María A.Bernini, Maria CelesteNarda, Griselda EdithSensing PropertiesEnergy TransferParticle SizeRare Earth Coordination NetworksLuminescencehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A new isostructural family of layered coordination networks (CNs) based on rare earth elements and mixed ligands was hydrothermally synthesized and fully characterized. The set of compounds with the general formula [REE(Salicylate)(Succinate)0.5(H2O)] (with REE = Ho or Y) belong to the monoclinic P21/c space group. Top-down methods were implemented in order to obtain nano-sized CN particles for potential application in thin film fabrication. The solid state photoluminescence (SSPL) of the Eu, Tb and Eu/Tb doped samples was explored in terms of excitation/emission spectra, lifetime values and quantification of light emission by the CIE chromaticity calculation. Measurement of the triplet state energy of the ligand at low temperature was carried out by analysing the SSPL of the Y-based compound; energy transfer pathways were studied. According to the high performance of the Tb-doped compound as a green emitter, thermal and chemical sensing assays were carried out.Fil: Godoy, Agustín Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Kaczmarek, Anna M.. University of Ghent; BélgicaFil: Van Deun, Rik. University of Ghent; BélgicaFil: Furlong, Octavio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaFil: Gándara, Felipe. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Monge, María A.. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Bernini, Maria Celeste. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Narda, Griselda Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaRoyal Society of Chemistry2017-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/63875Godoy, Agustín Alejandro; Gomez, Germán Ernesto; Kaczmarek, Anna M.; Van Deun, Rik; Furlong, Octavio Javier; et al.; Sensing properties, energy transfer mechanism and tuneable particle size processing of luminescent two-dimensional rare earth coordination networks; Royal Society of Chemistry; Journal of Materials Chemistry C; 5; 47; 1-2017; 12409-124212050-7526CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/c7tc04006ginfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/Content/ArticleLanding/2017/TC/C7TC04006G#!divAbstractinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:14:34Zoai:ri.conicet.gov.ar:11336/63875instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:14:35.11CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Sensing properties, energy transfer mechanism and tuneable particle size processing of luminescent two-dimensional rare earth coordination networks
title Sensing properties, energy transfer mechanism and tuneable particle size processing of luminescent two-dimensional rare earth coordination networks
spellingShingle Sensing properties, energy transfer mechanism and tuneable particle size processing of luminescent two-dimensional rare earth coordination networks
Godoy, Agustín Alejandro
Sensing Properties
Energy Transfer
Particle Size
Rare Earth Coordination Networks
Luminescence
title_short Sensing properties, energy transfer mechanism and tuneable particle size processing of luminescent two-dimensional rare earth coordination networks
title_full Sensing properties, energy transfer mechanism and tuneable particle size processing of luminescent two-dimensional rare earth coordination networks
title_fullStr Sensing properties, energy transfer mechanism and tuneable particle size processing of luminescent two-dimensional rare earth coordination networks
title_full_unstemmed Sensing properties, energy transfer mechanism and tuneable particle size processing of luminescent two-dimensional rare earth coordination networks
title_sort Sensing properties, energy transfer mechanism and tuneable particle size processing of luminescent two-dimensional rare earth coordination networks
dc.creator.none.fl_str_mv Godoy, Agustín Alejandro
Gomez, Germán Ernesto
Kaczmarek, Anna M.
Van Deun, Rik
Furlong, Octavio Javier
Gándara, Felipe
Monge, María A.
Bernini, Maria Celeste
Narda, Griselda Edith
author Godoy, Agustín Alejandro
author_facet Godoy, Agustín Alejandro
Gomez, Germán Ernesto
Kaczmarek, Anna M.
Van Deun, Rik
Furlong, Octavio Javier
Gándara, Felipe
Monge, María A.
Bernini, Maria Celeste
Narda, Griselda Edith
author_role author
author2 Gomez, Germán Ernesto
Kaczmarek, Anna M.
Van Deun, Rik
Furlong, Octavio Javier
Gándara, Felipe
Monge, María A.
Bernini, Maria Celeste
Narda, Griselda Edith
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Sensing Properties
Energy Transfer
Particle Size
Rare Earth Coordination Networks
Luminescence
topic Sensing Properties
Energy Transfer
Particle Size
Rare Earth Coordination Networks
Luminescence
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A new isostructural family of layered coordination networks (CNs) based on rare earth elements and mixed ligands was hydrothermally synthesized and fully characterized. The set of compounds with the general formula [REE(Salicylate)(Succinate)0.5(H2O)] (with REE = Ho or Y) belong to the monoclinic P21/c space group. Top-down methods were implemented in order to obtain nano-sized CN particles for potential application in thin film fabrication. The solid state photoluminescence (SSPL) of the Eu, Tb and Eu/Tb doped samples was explored in terms of excitation/emission spectra, lifetime values and quantification of light emission by the CIE chromaticity calculation. Measurement of the triplet state energy of the ligand at low temperature was carried out by analysing the SSPL of the Y-based compound; energy transfer pathways were studied. According to the high performance of the Tb-doped compound as a green emitter, thermal and chemical sensing assays were carried out.
Fil: Godoy, Agustín Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Kaczmarek, Anna M.. University of Ghent; Bélgica
Fil: Van Deun, Rik. University of Ghent; Bélgica
Fil: Furlong, Octavio Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Gándara, Felipe. Instituto de Ciencia de Materiales de Madrid; España
Fil: Monge, María A.. Instituto de Ciencia de Materiales de Madrid; España
Fil: Bernini, Maria Celeste. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Narda, Griselda Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
description A new isostructural family of layered coordination networks (CNs) based on rare earth elements and mixed ligands was hydrothermally synthesized and fully characterized. The set of compounds with the general formula [REE(Salicylate)(Succinate)0.5(H2O)] (with REE = Ho or Y) belong to the monoclinic P21/c space group. Top-down methods were implemented in order to obtain nano-sized CN particles for potential application in thin film fabrication. The solid state photoluminescence (SSPL) of the Eu, Tb and Eu/Tb doped samples was explored in terms of excitation/emission spectra, lifetime values and quantification of light emission by the CIE chromaticity calculation. Measurement of the triplet state energy of the ligand at low temperature was carried out by analysing the SSPL of the Y-based compound; energy transfer pathways were studied. According to the high performance of the Tb-doped compound as a green emitter, thermal and chemical sensing assays were carried out.
publishDate 2017
dc.date.none.fl_str_mv 2017-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/63875
Godoy, Agustín Alejandro; Gomez, Germán Ernesto; Kaczmarek, Anna M.; Van Deun, Rik; Furlong, Octavio Javier; et al.; Sensing properties, energy transfer mechanism and tuneable particle size processing of luminescent two-dimensional rare earth coordination networks; Royal Society of Chemistry; Journal of Materials Chemistry C; 5; 47; 1-2017; 12409-12421
2050-7526
CONICET Digital
CONICET
url http://hdl.handle.net/11336/63875
identifier_str_mv Godoy, Agustín Alejandro; Gomez, Germán Ernesto; Kaczmarek, Anna M.; Van Deun, Rik; Furlong, Octavio Javier; et al.; Sensing properties, energy transfer mechanism and tuneable particle size processing of luminescent two-dimensional rare earth coordination networks; Royal Society of Chemistry; Journal of Materials Chemistry C; 5; 47; 1-2017; 12409-12421
2050-7526
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1039/c7tc04006g
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/Content/ArticleLanding/2017/TC/C7TC04006G#!divAbstract
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.891075

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