Scheme of thermal compression of hydrogen (TCH) using MmNi4.25Al0.75 recovered with ethyl alcohol and handled under non protective atmospheres

Autores
Obregon, Sergio Alejandro; Esquivel, Marcelo Ricardo Oscar
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A MmNi4.25Al0.75 intermetallic was obtained by low energy mechanical alloying and low temperature heating at 600 °C for 24 h under Ar. The intermetallic was recovered from milling chamber using ethyl alcohol, dried, stored and handled under air at room conditions. Structure was characterized by XRD. A maximum stability temperature of 160 °C was obtained from non-isothermal DSC measurement under air. The kinetics of oxidation at 200 °C was analyzed. A maximum reaction degree (α = 0.1) was obtained after 2500 s of treatment. The hydrogen sorption properties of samples were studied by volumetric measurements. Hydrogen maximum mass percent capacity (mass %) was reached in less than 300 s. The thermodynamic sorption properties were measured. Values of ΔHf = −29 ± 2 kJ mol−1 and ΔSf = 197 ± 10 J mol−1 K−1 were obtained for absorption process and ΔHd = 28 ± 2 kJ mol−1 and ΔSd = 189 + 10 J mol−1 K−1 were obtained for desorption process. From these results, a one-stage of thermal compression of hydrogen is proposed with a standard compression ratio (Rc) of 5.71 in the 25–80 °C range.
Fil: Obregon, Sergio Alejandro. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Universidad Nacional del Comahue; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Esquivel, Marcelo Ricardo Oscar. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Universidad Nacional del Comahue; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
Metal Hydrides
Thermal Compresion of Hydrogen
Dsc
Xrd
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/32441
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/32441
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Scheme of thermal compression of hydrogen (TCH) using MmNi4.25Al0.75 recovered with ethyl alcohol and handled under non protective atmospheresObregon, Sergio AlejandroEsquivel, Marcelo Ricardo OscarMetal HydridesThermal Compresion of HydrogenDscXrdhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A MmNi4.25Al0.75 intermetallic was obtained by low energy mechanical alloying and low temperature heating at 600 °C for 24 h under Ar. The intermetallic was recovered from milling chamber using ethyl alcohol, dried, stored and handled under air at room conditions. Structure was characterized by XRD. A maximum stability temperature of 160 °C was obtained from non-isothermal DSC measurement under air. The kinetics of oxidation at 200 °C was analyzed. A maximum reaction degree (α = 0.1) was obtained after 2500 s of treatment. The hydrogen sorption properties of samples were studied by volumetric measurements. Hydrogen maximum mass percent capacity (mass %) was reached in less than 300 s. The thermodynamic sorption properties were measured. Values of ΔHf = −29 ± 2 kJ mol−1 and ΔSf = 197 ± 10 J mol−1 K−1 were obtained for absorption process and ΔHd = 28 ± 2 kJ mol−1 and ΔSd = 189 + 10 J mol−1 K−1 were obtained for desorption process. From these results, a one-stage of thermal compression of hydrogen is proposed with a standard compression ratio (Rc) of 5.71 in the 25–80 °C range.Fil: Obregon, Sergio Alejandro. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Universidad Nacional del Comahue; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Esquivel, Marcelo Ricardo Oscar. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Universidad Nacional del Comahue; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaElsevier2014-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/32441Esquivel, Marcelo Ricardo Oscar; Obregon, Sergio Alejandro; Scheme of thermal compression of hydrogen (TCH) using MmNi4.25Al0.75 recovered with ethyl alcohol and handled under non protective atmospheres; Elsevier; International Journal of Hydrogen Energy; 39; 16; 3-2014; 8577-85810360-3199CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2014.02.124info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0360319914005229info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:56:45Zoai:ri.conicet.gov.ar:11336/32441instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:56:46.193CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Scheme of thermal compression of hydrogen (TCH) using MmNi4.25Al0.75 recovered with ethyl alcohol and handled under non protective atmospheres
title Scheme of thermal compression of hydrogen (TCH) using MmNi4.25Al0.75 recovered with ethyl alcohol and handled under non protective atmospheres
spellingShingle Scheme of thermal compression of hydrogen (TCH) using MmNi4.25Al0.75 recovered with ethyl alcohol and handled under non protective atmospheres
Obregon, Sergio Alejandro
Metal Hydrides
Thermal Compresion of Hydrogen
Dsc
Xrd
title_short Scheme of thermal compression of hydrogen (TCH) using MmNi4.25Al0.75 recovered with ethyl alcohol and handled under non protective atmospheres
title_full Scheme of thermal compression of hydrogen (TCH) using MmNi4.25Al0.75 recovered with ethyl alcohol and handled under non protective atmospheres
title_fullStr Scheme of thermal compression of hydrogen (TCH) using MmNi4.25Al0.75 recovered with ethyl alcohol and handled under non protective atmospheres
title_full_unstemmed Scheme of thermal compression of hydrogen (TCH) using MmNi4.25Al0.75 recovered with ethyl alcohol and handled under non protective atmospheres
title_sort Scheme of thermal compression of hydrogen (TCH) using MmNi4.25Al0.75 recovered with ethyl alcohol and handled under non protective atmospheres
dc.creator.none.fl_str_mv Obregon, Sergio Alejandro
Esquivel, Marcelo Ricardo Oscar
author Obregon, Sergio Alejandro
author_facet Obregon, Sergio Alejandro
Esquivel, Marcelo Ricardo Oscar
author_role author
author2 Esquivel, Marcelo Ricardo Oscar
author2_role author
dc.subject.none.fl_str_mv Metal Hydrides
Thermal Compresion of Hydrogen
Dsc
Xrd
topic Metal Hydrides
Thermal Compresion of Hydrogen
Dsc
Xrd
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A MmNi4.25Al0.75 intermetallic was obtained by low energy mechanical alloying and low temperature heating at 600 °C for 24 h under Ar. The intermetallic was recovered from milling chamber using ethyl alcohol, dried, stored and handled under air at room conditions. Structure was characterized by XRD. A maximum stability temperature of 160 °C was obtained from non-isothermal DSC measurement under air. The kinetics of oxidation at 200 °C was analyzed. A maximum reaction degree (α = 0.1) was obtained after 2500 s of treatment. The hydrogen sorption properties of samples were studied by volumetric measurements. Hydrogen maximum mass percent capacity (mass %) was reached in less than 300 s. The thermodynamic sorption properties were measured. Values of ΔHf = −29 ± 2 kJ mol−1 and ΔSf = 197 ± 10 J mol−1 K−1 were obtained for absorption process and ΔHd = 28 ± 2 kJ mol−1 and ΔSd = 189 + 10 J mol−1 K−1 were obtained for desorption process. From these results, a one-stage of thermal compression of hydrogen is proposed with a standard compression ratio (Rc) of 5.71 in the 25–80 °C range.
Fil: Obregon, Sergio Alejandro. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Universidad Nacional del Comahue; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Esquivel, Marcelo Ricardo Oscar. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Universidad Nacional del Comahue; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description A MmNi4.25Al0.75 intermetallic was obtained by low energy mechanical alloying and low temperature heating at 600 °C for 24 h under Ar. The intermetallic was recovered from milling chamber using ethyl alcohol, dried, stored and handled under air at room conditions. Structure was characterized by XRD. A maximum stability temperature of 160 °C was obtained from non-isothermal DSC measurement under air. The kinetics of oxidation at 200 °C was analyzed. A maximum reaction degree (α = 0.1) was obtained after 2500 s of treatment. The hydrogen sorption properties of samples were studied by volumetric measurements. Hydrogen maximum mass percent capacity (mass %) was reached in less than 300 s. The thermodynamic sorption properties were measured. Values of ΔHf = −29 ± 2 kJ mol−1 and ΔSf = 197 ± 10 J mol−1 K−1 were obtained for absorption process and ΔHd = 28 ± 2 kJ mol−1 and ΔSd = 189 + 10 J mol−1 K−1 were obtained for desorption process. From these results, a one-stage of thermal compression of hydrogen is proposed with a standard compression ratio (Rc) of 5.71 in the 25–80 °C range.
publishDate 2014
dc.date.none.fl_str_mv 2014-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/32441
Esquivel, Marcelo Ricardo Oscar; Obregon, Sergio Alejandro; Scheme of thermal compression of hydrogen (TCH) using MmNi4.25Al0.75 recovered with ethyl alcohol and handled under non protective atmospheres; Elsevier; International Journal of Hydrogen Energy; 39; 16; 3-2014; 8577-8581
0360-3199
CONICET Digital
CONICET
url http://hdl.handle.net/11336/32441
identifier_str_mv Esquivel, Marcelo Ricardo Oscar; Obregon, Sergio Alejandro; Scheme of thermal compression of hydrogen (TCH) using MmNi4.25Al0.75 recovered with ethyl alcohol and handled under non protective atmospheres; Elsevier; International Journal of Hydrogen Energy; 39; 16; 3-2014; 8577-8581
0360-3199
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2014.02.124
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0360319914005229
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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