KNH2 - KH: a metal amide - hydride solid solution

Autores
Santoru, Antonio; Pistidda, Claudio; Sørby, Magnus H.; Chierotti, Michele R.; Garroni, Sebastian; Pinatel, Eugenio; Karimi, Fahim; Cao, Hujun; Bergemann, Nils; Le, Thi T.; Puszkiel, Julián Atilio; Gobetto, Roberto; Baricco, Marcello; Hauback, Bjorn C.; Klassen, Thomas; Dornheim, Martín
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We report for the first time the formation of a metal amide-hydride solid solution. The dissolution of KH into KNH2 leads to an anionic substitution, which decreases the interaction among NH2 - ions. The rotational properties of the high temperature polymorphs of KNH2 are thereby retained down to room temperature.
Fil: Santoru, Antonio. Helmholtz-zentrum Geesthacht; Alemania. Università di Torino; Italia
Fil: Pistidda, Claudio. Helmholtz-zentrum Geesthacht; Alemania
Fil: Sørby, Magnus H.. Institute for Energy Technology. Physics Department; Noruega
Fil: Chierotti, Michele R.. Università di Torino; Italia
Fil: Garroni, Sebastian. University of Sassari; Italia
Fil: Pinatel, Eugenio. Università di Torino; Italia
Fil: Karimi, Fahim. Helmholtz-zentrum Geesthacht; Alemania
Fil: Cao, Hujun. Helmholtz-zentrum Geesthacht; Alemania
Fil: Bergemann, Nils. Helmholtz-zentrum Geesthacht; Alemania
Fil: Le, Thi T.. Helmholtz-zentrum Geesthacht; Alemania
Fil: Puszkiel, Julián Atilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Gobetto, Roberto. Università di Torino; Italia
Fil: Baricco, Marcello. Università di Torino; Italia
Fil: Hauback, Bjorn C.. Institute for Energy Technology. Physics Department; Noruega
Fil: Klassen, Thomas. Helmholtz-zentrum Geesthacht; Alemania
Fil: Dornheim, Martín. Helmholtz-zentrum Geesthacht; Alemania
Materia
METAL AMIDE
HYDRIDE SOLID SOLUTION
POLYMORPHS
SR-PXD
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/80119
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/80119
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling KNH2 - KH: a metal amide - hydride solid solutionSantoru, AntonioPistidda, ClaudioSørby, Magnus H.Chierotti, Michele R.Garroni, SebastianPinatel, EugenioKarimi, FahimCao, HujunBergemann, NilsLe, Thi T.Puszkiel, Julián AtilioGobetto, RobertoBaricco, MarcelloHauback, Bjorn C.Klassen, ThomasDornheim, MartínMETAL AMIDEHYDRIDE SOLID SOLUTIONPOLYMORPHSSR-PXDhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1We report for the first time the formation of a metal amide-hydride solid solution. The dissolution of KH into KNH2 leads to an anionic substitution, which decreases the interaction among NH2 - ions. The rotational properties of the high temperature polymorphs of KNH2 are thereby retained down to room temperature.Fil: Santoru, Antonio. Helmholtz-zentrum Geesthacht; Alemania. Università di Torino; ItaliaFil: Pistidda, Claudio. Helmholtz-zentrum Geesthacht; AlemaniaFil: Sørby, Magnus H.. Institute for Energy Technology. Physics Department; NoruegaFil: Chierotti, Michele R.. Università di Torino; ItaliaFil: Garroni, Sebastian. University of Sassari; ItaliaFil: Pinatel, Eugenio. Università di Torino; ItaliaFil: Karimi, Fahim. Helmholtz-zentrum Geesthacht; AlemaniaFil: Cao, Hujun. Helmholtz-zentrum Geesthacht; AlemaniaFil: Bergemann, Nils. Helmholtz-zentrum Geesthacht; AlemaniaFil: Le, Thi T.. Helmholtz-zentrum Geesthacht; AlemaniaFil: Puszkiel, Julián Atilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; ArgentinaFil: Gobetto, Roberto. Università di Torino; ItaliaFil: Baricco, Marcello. Università di Torino; ItaliaFil: Hauback, Bjorn C.. Institute for Energy Technology. Physics Department; NoruegaFil: Klassen, Thomas. Helmholtz-zentrum Geesthacht; AlemaniaFil: Dornheim, Martín. Helmholtz-zentrum Geesthacht; AlemaniaRoyal Society of Chemistry2016-09-27info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/80119Santoru, Antonio; Pistidda, Claudio; Sørby, Magnus H.; Chierotti, Michele R.; Garroni, Sebastian; et al.; KNH2 - KH: a metal amide - hydride solid solution; Royal Society of Chemistry; Chemical Communications; 52; 79; 27-9-2016; 11760-117631359-7345CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/c6cc05777binfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2016/CC/C6CC05777B#!divAbstractinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:06:10Zoai:ri.conicet.gov.ar:11336/80119instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:06:10.71CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv KNH2 - KH: a metal amide - hydride solid solution
title KNH2 - KH: a metal amide - hydride solid solution
spellingShingle KNH2 - KH: a metal amide - hydride solid solution
Santoru, Antonio
METAL AMIDE
HYDRIDE SOLID SOLUTION
POLYMORPHS
SR-PXD
title_short KNH2 - KH: a metal amide - hydride solid solution
title_full KNH2 - KH: a metal amide - hydride solid solution
title_fullStr KNH2 - KH: a metal amide - hydride solid solution
title_full_unstemmed KNH2 - KH: a metal amide - hydride solid solution
title_sort KNH2 - KH: a metal amide - hydride solid solution
dc.creator.none.fl_str_mv Santoru, Antonio
Pistidda, Claudio
Sørby, Magnus H.
Chierotti, Michele R.
Garroni, Sebastian
Pinatel, Eugenio
Karimi, Fahim
Cao, Hujun
Bergemann, Nils
Le, Thi T.
Puszkiel, Julián Atilio
Gobetto, Roberto
Baricco, Marcello
Hauback, Bjorn C.
Klassen, Thomas
Dornheim, Martín
author Santoru, Antonio
author_facet Santoru, Antonio
Pistidda, Claudio
Sørby, Magnus H.
Chierotti, Michele R.
Garroni, Sebastian
Pinatel, Eugenio
Karimi, Fahim
Cao, Hujun
Bergemann, Nils
Le, Thi T.
Puszkiel, Julián Atilio
Gobetto, Roberto
Baricco, Marcello
Hauback, Bjorn C.
Klassen, Thomas
Dornheim, Martín
author_role author
author2 Pistidda, Claudio
Sørby, Magnus H.
Chierotti, Michele R.
Garroni, Sebastian
Pinatel, Eugenio
Karimi, Fahim
Cao, Hujun
Bergemann, Nils
Le, Thi T.
Puszkiel, Julián Atilio
Gobetto, Roberto
Baricco, Marcello
Hauback, Bjorn C.
Klassen, Thomas
Dornheim, Martín
author2_role author
author
author
author
author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv METAL AMIDE
HYDRIDE SOLID SOLUTION
POLYMORPHS
SR-PXD
topic METAL AMIDE
HYDRIDE SOLID SOLUTION
POLYMORPHS
SR-PXD
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv We report for the first time the formation of a metal amide-hydride solid solution. The dissolution of KH into KNH2 leads to an anionic substitution, which decreases the interaction among NH2 - ions. The rotational properties of the high temperature polymorphs of KNH2 are thereby retained down to room temperature.
Fil: Santoru, Antonio. Helmholtz-zentrum Geesthacht; Alemania. Università di Torino; Italia
Fil: Pistidda, Claudio. Helmholtz-zentrum Geesthacht; Alemania
Fil: Sørby, Magnus H.. Institute for Energy Technology. Physics Department; Noruega
Fil: Chierotti, Michele R.. Università di Torino; Italia
Fil: Garroni, Sebastian. University of Sassari; Italia
Fil: Pinatel, Eugenio. Università di Torino; Italia
Fil: Karimi, Fahim. Helmholtz-zentrum Geesthacht; Alemania
Fil: Cao, Hujun. Helmholtz-zentrum Geesthacht; Alemania
Fil: Bergemann, Nils. Helmholtz-zentrum Geesthacht; Alemania
Fil: Le, Thi T.. Helmholtz-zentrum Geesthacht; Alemania
Fil: Puszkiel, Julián Atilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Gobetto, Roberto. Università di Torino; Italia
Fil: Baricco, Marcello. Università di Torino; Italia
Fil: Hauback, Bjorn C.. Institute for Energy Technology. Physics Department; Noruega
Fil: Klassen, Thomas. Helmholtz-zentrum Geesthacht; Alemania
Fil: Dornheim, Martín. Helmholtz-zentrum Geesthacht; Alemania
description We report for the first time the formation of a metal amide-hydride solid solution. The dissolution of KH into KNH2 leads to an anionic substitution, which decreases the interaction among NH2 - ions. The rotational properties of the high temperature polymorphs of KNH2 are thereby retained down to room temperature.
publishDate 2016
dc.date.none.fl_str_mv 2016-09-27
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/80119
Santoru, Antonio; Pistidda, Claudio; Sørby, Magnus H.; Chierotti, Michele R.; Garroni, Sebastian; et al.; KNH2 - KH: a metal amide - hydride solid solution; Royal Society of Chemistry; Chemical Communications; 52; 79; 27-9-2016; 11760-11763
1359-7345
CONICET Digital
CONICET
url http://hdl.handle.net/11336/80119
identifier_str_mv Santoru, Antonio; Pistidda, Claudio; Sørby, Magnus H.; Chierotti, Michele R.; Garroni, Sebastian; et al.; KNH2 - KH: a metal amide - hydride solid solution; Royal Society of Chemistry; Chemical Communications; 52; 79; 27-9-2016; 11760-11763
1359-7345
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1039/c6cc05777b
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2016/CC/C6CC05777B#!divAbstract
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269945007702016
score 13.13397

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