Biodiesel Purification Using Polymeric Nanofiltration Composite Membranes Highly Resistant to Harsh Conditions

Autores
Torres, Juan Jose; Toledo Arana, Javier Marcelo; Ochoa, Nelio Ariel; Marchese, Jose; Pagliero, Cecilia Liliana
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Biodiesel as alternative for conventional diesel fuel is mainly produced by the catalytic reaction of triglycerides with an alcohol. In this work, the purification of biodiesel was carried out with two lab-made solvent-resistant composite nanofiltration membranes of poly(vinylidene difluoride) (PVDF) as support and poly(dimethylsiloxane) as coating layer. Biodiesel was obtained from the esterification of partially refined soy oil with bioethanol (EtOH) and NaOH as catalyst. The best biodiesel purification performance was achieved with the PVDF-12SI membrane reaching high retention of glycerol, total glycerides, and soap. PVDF-SI membranes were found to have an excellent stability for biodiesel permeation, achieving a flux recovery ratio of EtOH as high as 0.94 after twenty cycles of use.
Fil: Torres, Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Toledo Arana, Javier Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Ochoa, Nelio Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Marchese, Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Pagliero, Cecilia Liliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
BIODIESEL
ETHYL ESTERS
GLYCERIDES
MEMBRANE PURIFICATION
NANOFILTRATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/86500
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Biodiesel Purification Using Polymeric Nanofiltration Composite Membranes Highly Resistant to Harsh ConditionsTorres, Juan JoseToledo Arana, Javier MarceloOchoa, Nelio ArielMarchese, JosePagliero, Cecilia LilianaBIODIESELETHYL ESTERSGLYCERIDESMEMBRANE PURIFICATIONNANOFILTRATIONhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Biodiesel as alternative for conventional diesel fuel is mainly produced by the catalytic reaction of triglycerides with an alcohol. In this work, the purification of biodiesel was carried out with two lab-made solvent-resistant composite nanofiltration membranes of poly(vinylidene difluoride) (PVDF) as support and poly(dimethylsiloxane) as coating layer. Biodiesel was obtained from the esterification of partially refined soy oil with bioethanol (EtOH) and NaOH as catalyst. The best biodiesel purification performance was achieved with the PVDF-12SI membrane reaching high retention of glycerol, total glycerides, and soap. PVDF-SI membranes were found to have an excellent stability for biodiesel permeation, achieving a flux recovery ratio of EtOH as high as 0.94 after twenty cycles of use.Fil: Torres, Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Toledo Arana, Javier Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Ochoa, Nelio Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaFil: Marchese, Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; ArgentinaFil: Pagliero, Cecilia Liliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaWiley VCH Verlag2018-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/86500Torres, Juan Jose; Toledo Arana, Javier Marcelo; Ochoa, Nelio Ariel; Marchese, Jose; Pagliero, Cecilia Liliana; Biodiesel Purification Using Polymeric Nanofiltration Composite Membranes Highly Resistant to Harsh Conditions; Wiley VCH Verlag; Chemical Enginnering Technology; 41; 2; 2-2018; 253-2600930-7516CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/ceat.201600257info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/ceat.201600257info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:36:48Zoai:ri.conicet.gov.ar:11336/86500instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:36:48.454CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Biodiesel Purification Using Polymeric Nanofiltration Composite Membranes Highly Resistant to Harsh Conditions
title Biodiesel Purification Using Polymeric Nanofiltration Composite Membranes Highly Resistant to Harsh Conditions
spellingShingle Biodiesel Purification Using Polymeric Nanofiltration Composite Membranes Highly Resistant to Harsh Conditions
Torres, Juan Jose
BIODIESEL
ETHYL ESTERS
GLYCERIDES
MEMBRANE PURIFICATION
NANOFILTRATION
title_short Biodiesel Purification Using Polymeric Nanofiltration Composite Membranes Highly Resistant to Harsh Conditions
title_full Biodiesel Purification Using Polymeric Nanofiltration Composite Membranes Highly Resistant to Harsh Conditions
title_fullStr Biodiesel Purification Using Polymeric Nanofiltration Composite Membranes Highly Resistant to Harsh Conditions
title_full_unstemmed Biodiesel Purification Using Polymeric Nanofiltration Composite Membranes Highly Resistant to Harsh Conditions
title_sort Biodiesel Purification Using Polymeric Nanofiltration Composite Membranes Highly Resistant to Harsh Conditions
dc.creator.none.fl_str_mv Torres, Juan Jose
Toledo Arana, Javier Marcelo
Ochoa, Nelio Ariel
Marchese, Jose
Pagliero, Cecilia Liliana
author Torres, Juan Jose
author_facet Torres, Juan Jose
Toledo Arana, Javier Marcelo
Ochoa, Nelio Ariel
Marchese, Jose
Pagliero, Cecilia Liliana
author_role author
author2 Toledo Arana, Javier Marcelo
Ochoa, Nelio Ariel
Marchese, Jose
Pagliero, Cecilia Liliana
author2_role author
author
author
author
dc.subject.none.fl_str_mv BIODIESEL
ETHYL ESTERS
GLYCERIDES
MEMBRANE PURIFICATION
NANOFILTRATION
topic BIODIESEL
ETHYL ESTERS
GLYCERIDES
MEMBRANE PURIFICATION
NANOFILTRATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Biodiesel as alternative for conventional diesel fuel is mainly produced by the catalytic reaction of triglycerides with an alcohol. In this work, the purification of biodiesel was carried out with two lab-made solvent-resistant composite nanofiltration membranes of poly(vinylidene difluoride) (PVDF) as support and poly(dimethylsiloxane) as coating layer. Biodiesel was obtained from the esterification of partially refined soy oil with bioethanol (EtOH) and NaOH as catalyst. The best biodiesel purification performance was achieved with the PVDF-12SI membrane reaching high retention of glycerol, total glycerides, and soap. PVDF-SI membranes were found to have an excellent stability for biodiesel permeation, achieving a flux recovery ratio of EtOH as high as 0.94 after twenty cycles of use.
Fil: Torres, Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Toledo Arana, Javier Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Ochoa, Nelio Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Marchese, Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich". Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Instituto de Física Aplicada "Dr. Jorge Andrés Zgrablich"; Argentina
Fil: Pagliero, Cecilia Liliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description Biodiesel as alternative for conventional diesel fuel is mainly produced by the catalytic reaction of triglycerides with an alcohol. In this work, the purification of biodiesel was carried out with two lab-made solvent-resistant composite nanofiltration membranes of poly(vinylidene difluoride) (PVDF) as support and poly(dimethylsiloxane) as coating layer. Biodiesel was obtained from the esterification of partially refined soy oil with bioethanol (EtOH) and NaOH as catalyst. The best biodiesel purification performance was achieved with the PVDF-12SI membrane reaching high retention of glycerol, total glycerides, and soap. PVDF-SI membranes were found to have an excellent stability for biodiesel permeation, achieving a flux recovery ratio of EtOH as high as 0.94 after twenty cycles of use.
publishDate 2018
dc.date.none.fl_str_mv 2018-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/86500
Torres, Juan Jose; Toledo Arana, Javier Marcelo; Ochoa, Nelio Ariel; Marchese, Jose; Pagliero, Cecilia Liliana; Biodiesel Purification Using Polymeric Nanofiltration Composite Membranes Highly Resistant to Harsh Conditions; Wiley VCH Verlag; Chemical Enginnering Technology; 41; 2; 2-2018; 253-260
0930-7516
CONICET Digital
CONICET
url http://hdl.handle.net/11336/86500
identifier_str_mv Torres, Juan Jose; Toledo Arana, Javier Marcelo; Ochoa, Nelio Ariel; Marchese, Jose; Pagliero, Cecilia Liliana; Biodiesel Purification Using Polymeric Nanofiltration Composite Membranes Highly Resistant to Harsh Conditions; Wiley VCH Verlag; Chemical Enginnering Technology; 41; 2; 2-2018; 253-260
0930-7516
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/ceat.201600257
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/ceat.201600257
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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