Highly Efficient Palladium-Catalyzed Arsination on the Way to Arsine Ligands

Autores
Martín, Sandra Elizabeth
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Since arsines are drawing particular attention as ligands in metal-catalyzed reactions, the development of new methods to obtain organoarsines is increasingly recognized as central in the synthesis of new ligands. Transition metal-catalyzed reactions with organoheteroatom compounds are widely used to acquire different heteroatom-contained compounds. This article reviews a highly efficient one-pot, two-step Pd-catalyzed arsination with n-Bu3SnAsPh2 and diverse electrophiles. The cross-coupling reactions of these stannanes with ArI afforded the functionalized triarylarsines, and with RfI as electrophiles new perfluoroalkylarsines were achieved. By following this methodology, a biphenyl arsine ligand was acquired. The use of the commercially available, air-stable, and inexpensive AsPh3 as the initial reagent and the one-pot process make this methodology a useful approach to obtaining a wide range of organoarsines.
Fil: Martín, Sandra Elizabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
Arsination
Pd-Catalysis
Arsine Ligands
Perfluoroalkylarsines
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/70363
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Highly Efficient Palladium-Catalyzed Arsination on the Way to Arsine LigandsMartín, Sandra ElizabethArsinationPd-CatalysisArsine LigandsPerfluoroalkylarsineshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Since arsines are drawing particular attention as ligands in metal-catalyzed reactions, the development of new methods to obtain organoarsines is increasingly recognized as central in the synthesis of new ligands. Transition metal-catalyzed reactions with organoheteroatom compounds are widely used to acquire different heteroatom-contained compounds. This article reviews a highly efficient one-pot, two-step Pd-catalyzed arsination with n-Bu3SnAsPh2 and diverse electrophiles. The cross-coupling reactions of these stannanes with ArI afforded the functionalized triarylarsines, and with RfI as electrophiles new perfluoroalkylarsines were achieved. By following this methodology, a biphenyl arsine ligand was acquired. The use of the commercially available, air-stable, and inexpensive AsPh3 as the initial reagent and the one-pot process make this methodology a useful approach to obtaining a wide range of organoarsines.Fil: Martín, Sandra Elizabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaTeknoscienze Publisher2011-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/70363Martín, Sandra Elizabeth; Highly Efficient Palladium-Catalyzed Arsination on the Way to Arsine Ligands; Teknoscienze Publisher; ChemInform; 42; 25; 6-2011; no-no0931-75971973-8250CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/chin.201125243info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:57:39Zoai:ri.conicet.gov.ar:11336/70363instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:57:39.434CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Highly Efficient Palladium-Catalyzed Arsination on the Way to Arsine Ligands
title Highly Efficient Palladium-Catalyzed Arsination on the Way to Arsine Ligands
spellingShingle Highly Efficient Palladium-Catalyzed Arsination on the Way to Arsine Ligands
Martín, Sandra Elizabeth
Arsination
Pd-Catalysis
Arsine Ligands
Perfluoroalkylarsines
title_short Highly Efficient Palladium-Catalyzed Arsination on the Way to Arsine Ligands
title_full Highly Efficient Palladium-Catalyzed Arsination on the Way to Arsine Ligands
title_fullStr Highly Efficient Palladium-Catalyzed Arsination on the Way to Arsine Ligands
title_full_unstemmed Highly Efficient Palladium-Catalyzed Arsination on the Way to Arsine Ligands
title_sort Highly Efficient Palladium-Catalyzed Arsination on the Way to Arsine Ligands
dc.creator.none.fl_str_mv Martín, Sandra Elizabeth
author Martín, Sandra Elizabeth
author_facet Martín, Sandra Elizabeth
author_role author
dc.subject.none.fl_str_mv Arsination
Pd-Catalysis
Arsine Ligands
Perfluoroalkylarsines
topic Arsination
Pd-Catalysis
Arsine Ligands
Perfluoroalkylarsines
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Since arsines are drawing particular attention as ligands in metal-catalyzed reactions, the development of new methods to obtain organoarsines is increasingly recognized as central in the synthesis of new ligands. Transition metal-catalyzed reactions with organoheteroatom compounds are widely used to acquire different heteroatom-contained compounds. This article reviews a highly efficient one-pot, two-step Pd-catalyzed arsination with n-Bu3SnAsPh2 and diverse electrophiles. The cross-coupling reactions of these stannanes with ArI afforded the functionalized triarylarsines, and with RfI as electrophiles new perfluoroalkylarsines were achieved. By following this methodology, a biphenyl arsine ligand was acquired. The use of the commercially available, air-stable, and inexpensive AsPh3 as the initial reagent and the one-pot process make this methodology a useful approach to obtaining a wide range of organoarsines.
Fil: Martín, Sandra Elizabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description Since arsines are drawing particular attention as ligands in metal-catalyzed reactions, the development of new methods to obtain organoarsines is increasingly recognized as central in the synthesis of new ligands. Transition metal-catalyzed reactions with organoheteroatom compounds are widely used to acquire different heteroatom-contained compounds. This article reviews a highly efficient one-pot, two-step Pd-catalyzed arsination with n-Bu3SnAsPh2 and diverse electrophiles. The cross-coupling reactions of these stannanes with ArI afforded the functionalized triarylarsines, and with RfI as electrophiles new perfluoroalkylarsines were achieved. By following this methodology, a biphenyl arsine ligand was acquired. The use of the commercially available, air-stable, and inexpensive AsPh3 as the initial reagent and the one-pot process make this methodology a useful approach to obtaining a wide range of organoarsines.
publishDate 2011
dc.date.none.fl_str_mv 2011-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/70363
Martín, Sandra Elizabeth; Highly Efficient Palladium-Catalyzed Arsination on the Way to Arsine Ligands; Teknoscienze Publisher; ChemInform; 42; 25; 6-2011; no-no
0931-7597
1973-8250
CONICET Digital
CONICET
url http://hdl.handle.net/11336/70363
identifier_str_mv Martín, Sandra Elizabeth; Highly Efficient Palladium-Catalyzed Arsination on the Way to Arsine Ligands; Teknoscienze Publisher; ChemInform; 42; 25; 6-2011; no-no
0931-7597
1973-8250
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/chin.201125243
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Teknoscienze Publisher
publisher.none.fl_str_mv Teknoscienze Publisher
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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