Palladium-catalyzed arsination reactions and their applications on the synthesis of arsine ligands

Autores
Uberman, Paula Marina; Martín, Sandra Elizabeth
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In the synthesis of new ligands for metal-catalyzed reactions, arsines are attracting particular attention, because arsine ligands have been shown to be better ligands than structurally related phosphines in several catalyzed reactions. However, the synthesis and applications of arsine ligands is not widely extended in the literature. One of the main barriers to develop new arsine ligands is found in the synthetic methodologies to obtain arsine compounds. Therefore, to expand the applications of arsine ligands it is necessary to develop new synthetic strategies. To improve the classic arsination reactions metal-catalyzed C-As bond formation reactions appears to be a promising approach. This article highlights the palladium-catalyzed arsination reactions, providing the synthetic approaches used to obtain arsines. In addition, the few described examples of other metal-catalyzed arsination reactions are included. The synthesis of structurally diverse arsine ligands by catalyzed arsination reactions is summarized, as well as the most relevant issues of their applications in homogeneous catalysis.
Fil: Uberman, Paula Marina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Martín, Sandra Elizabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
ARSINE LIGANDS
ARYL ARSINES
CATALYZED ARSINATION
COUPLING REACTIONS
HECK
PALLADIUM
PD-CATALYZED ARSINATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/85437
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Palladium-catalyzed arsination reactions and their applications on the synthesis of arsine ligandsUberman, Paula MarinaMartín, Sandra ElizabethARSINE LIGANDSARYL ARSINESCATALYZED ARSINATIONCOUPLING REACTIONSHECKPALLADIUMPD-CATALYZED ARSINATIONhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In the synthesis of new ligands for metal-catalyzed reactions, arsines are attracting particular attention, because arsine ligands have been shown to be better ligands than structurally related phosphines in several catalyzed reactions. However, the synthesis and applications of arsine ligands is not widely extended in the literature. One of the main barriers to develop new arsine ligands is found in the synthetic methodologies to obtain arsine compounds. Therefore, to expand the applications of arsine ligands it is necessary to develop new synthetic strategies. To improve the classic arsination reactions metal-catalyzed C-As bond formation reactions appears to be a promising approach. This article highlights the palladium-catalyzed arsination reactions, providing the synthetic approaches used to obtain arsines. In addition, the few described examples of other metal-catalyzed arsination reactions are included. The synthesis of structurally diverse arsine ligands by catalyzed arsination reactions is summarized, as well as the most relevant issues of their applications in homogeneous catalysis.Fil: Uberman, Paula Marina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Martín, Sandra Elizabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaBentham Science Publishers2018-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/85437Uberman, Paula Marina; Martín, Sandra Elizabeth; Palladium-catalyzed arsination reactions and their applications on the synthesis of arsine ligands; Bentham Science Publishers; Current Organic Chemistry; 22; 24; 10-2018; 2394-24061385-2728CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.eurekaselect.com/166673/articleinfo:eu-repo/semantics/altIdentifier/doi/10.2174/1385272822666181026120728info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:00:44Zoai:ri.conicet.gov.ar:11336/85437instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:00:45.221CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Palladium-catalyzed arsination reactions and their applications on the synthesis of arsine ligands
title Palladium-catalyzed arsination reactions and their applications on the synthesis of arsine ligands
spellingShingle Palladium-catalyzed arsination reactions and their applications on the synthesis of arsine ligands
Uberman, Paula Marina
ARSINE LIGANDS
ARYL ARSINES
CATALYZED ARSINATION
COUPLING REACTIONS
HECK
PALLADIUM
PD-CATALYZED ARSINATION
title_short Palladium-catalyzed arsination reactions and their applications on the synthesis of arsine ligands
title_full Palladium-catalyzed arsination reactions and their applications on the synthesis of arsine ligands
title_fullStr Palladium-catalyzed arsination reactions and their applications on the synthesis of arsine ligands
title_full_unstemmed Palladium-catalyzed arsination reactions and their applications on the synthesis of arsine ligands
title_sort Palladium-catalyzed arsination reactions and their applications on the synthesis of arsine ligands
dc.creator.none.fl_str_mv Uberman, Paula Marina
Martín, Sandra Elizabeth
author Uberman, Paula Marina
author_facet Uberman, Paula Marina
Martín, Sandra Elizabeth
author_role author
author2 Martín, Sandra Elizabeth
author2_role author
dc.subject.none.fl_str_mv ARSINE LIGANDS
ARYL ARSINES
CATALYZED ARSINATION
COUPLING REACTIONS
HECK
PALLADIUM
PD-CATALYZED ARSINATION
topic ARSINE LIGANDS
ARYL ARSINES
CATALYZED ARSINATION
COUPLING REACTIONS
HECK
PALLADIUM
PD-CATALYZED ARSINATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In the synthesis of new ligands for metal-catalyzed reactions, arsines are attracting particular attention, because arsine ligands have been shown to be better ligands than structurally related phosphines in several catalyzed reactions. However, the synthesis and applications of arsine ligands is not widely extended in the literature. One of the main barriers to develop new arsine ligands is found in the synthetic methodologies to obtain arsine compounds. Therefore, to expand the applications of arsine ligands it is necessary to develop new synthetic strategies. To improve the classic arsination reactions metal-catalyzed C-As bond formation reactions appears to be a promising approach. This article highlights the palladium-catalyzed arsination reactions, providing the synthetic approaches used to obtain arsines. In addition, the few described examples of other metal-catalyzed arsination reactions are included. The synthesis of structurally diverse arsine ligands by catalyzed arsination reactions is summarized, as well as the most relevant issues of their applications in homogeneous catalysis.
Fil: Uberman, Paula Marina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Martín, Sandra Elizabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description In the synthesis of new ligands for metal-catalyzed reactions, arsines are attracting particular attention, because arsine ligands have been shown to be better ligands than structurally related phosphines in several catalyzed reactions. However, the synthesis and applications of arsine ligands is not widely extended in the literature. One of the main barriers to develop new arsine ligands is found in the synthetic methodologies to obtain arsine compounds. Therefore, to expand the applications of arsine ligands it is necessary to develop new synthetic strategies. To improve the classic arsination reactions metal-catalyzed C-As bond formation reactions appears to be a promising approach. This article highlights the palladium-catalyzed arsination reactions, providing the synthetic approaches used to obtain arsines. In addition, the few described examples of other metal-catalyzed arsination reactions are included. The synthesis of structurally diverse arsine ligands by catalyzed arsination reactions is summarized, as well as the most relevant issues of their applications in homogeneous catalysis.
publishDate 2018
dc.date.none.fl_str_mv 2018-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/85437
Uberman, Paula Marina; Martín, Sandra Elizabeth; Palladium-catalyzed arsination reactions and their applications on the synthesis of arsine ligands; Bentham Science Publishers; Current Organic Chemistry; 22; 24; 10-2018; 2394-2406
1385-2728
CONICET Digital
CONICET
url http://hdl.handle.net/11336/85437
identifier_str_mv Uberman, Paula Marina; Martín, Sandra Elizabeth; Palladium-catalyzed arsination reactions and their applications on the synthesis of arsine ligands; Bentham Science Publishers; Current Organic Chemistry; 22; 24; 10-2018; 2394-2406
1385-2728
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.eurekaselect.com/166673/article
info:eu-repo/semantics/altIdentifier/doi/10.2174/1385272822666181026120728
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Bentham Science Publishers
publisher.none.fl_str_mv Bentham Science Publishers
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842979902469439488
score 12.493442

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