A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism

Autores
Paz, Cristian; Burgos, Viviana; Suarez, Sebastian; Baggio, Ricardo Fortunato
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The title compound, dendocarbin A [systematic name: (1R,5aS,9aS,9bR)-1-hydroxy-6,6,9a-trimethyldodecahydronaphtho[1,2-c]furan-3-one], C15H22O3, is a sesquiterpene lactone isolated from Drimys winteri var chilensis. The monoclinic phase described herein displays an identical molecular structure to the orthorhombic phase that we reported previously [Paz Robles et al. (2014). Acta Cryst. C70, 1007-1010], while varying significantly in chain pitch, and can thus be considered as a borderline case of one-dimensional isostructural polymorphism.
Fil: Paz, Cristian. Universidad de La Frontera; Chile
Fil: Burgos, Viviana. Universidad de La Frontera; Chile
Fil: Suarez, Sebastian. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica; Argentina
Materia
DENDOCARBIN A
DRIMYS WINTERI EXTRACT
ISOSTRUCTURAL POLYMORPHISM
MONOCLINIC POLYMORPHIC FORM CRYSTAL STRUCTURE
NATURAL PRODUCT
SESQUITERPENE LACTONE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/98548

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network_name_str CONICET Digital (CONICET)
spelling A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphismPaz, CristianBurgos, VivianaSuarez, SebastianBaggio, Ricardo FortunatoDENDOCARBIN ADRIMYS WINTERI EXTRACTISOSTRUCTURAL POLYMORPHISMMONOCLINIC POLYMORPHIC FORM CRYSTAL STRUCTURENATURAL PRODUCTSESQUITERPENE LACTONEhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The title compound, dendocarbin A [systematic name: (1R,5aS,9aS,9bR)-1-hydroxy-6,6,9a-trimethyldodecahydronaphtho[1,2-c]furan-3-one], C15H22O3, is a sesquiterpene lactone isolated from Drimys winteri var chilensis. The monoclinic phase described herein displays an identical molecular structure to the orthorhombic phase that we reported previously [Paz Robles et al. (2014). Acta Cryst. C70, 1007-1010], while varying significantly in chain pitch, and can thus be considered as a borderline case of one-dimensional isostructural polymorphism.Fil: Paz, Cristian. Universidad de La Frontera; ChileFil: Burgos, Viviana. Universidad de La Frontera; ChileFil: Suarez, Sebastian. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica; ArgentinaInternational Union of Crystallography2015-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/98548Paz, Cristian; Burgos, Viviana; Suarez, Sebastian; Baggio, Ricardo Fortunato; A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism; International Union of Crystallography; Acta Crystallographica Section C: Structural Chemistry; 71; 4-2015; 294-2970108-27012053-2296CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S2053229615004994info:eu-repo/semantics/altIdentifier/doi/10.1107/S2053229615004994info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:00:31Zoai:ri.conicet.gov.ar:11336/98548instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:00:31.629CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism
title A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism
spellingShingle A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism
Paz, Cristian
DENDOCARBIN A
DRIMYS WINTERI EXTRACT
ISOSTRUCTURAL POLYMORPHISM
MONOCLINIC POLYMORPHIC FORM CRYSTAL STRUCTURE
NATURAL PRODUCT
SESQUITERPENE LACTONE
title_short A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism
title_full A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism
title_fullStr A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism
title_full_unstemmed A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism
title_sort A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism
dc.creator.none.fl_str_mv Paz, Cristian
Burgos, Viviana
Suarez, Sebastian
Baggio, Ricardo Fortunato
author Paz, Cristian
author_facet Paz, Cristian
Burgos, Viviana
Suarez, Sebastian
Baggio, Ricardo Fortunato
author_role author
author2 Burgos, Viviana
Suarez, Sebastian
Baggio, Ricardo Fortunato
author2_role author
author
author
dc.subject.none.fl_str_mv DENDOCARBIN A
DRIMYS WINTERI EXTRACT
ISOSTRUCTURAL POLYMORPHISM
MONOCLINIC POLYMORPHIC FORM CRYSTAL STRUCTURE
NATURAL PRODUCT
SESQUITERPENE LACTONE
topic DENDOCARBIN A
DRIMYS WINTERI EXTRACT
ISOSTRUCTURAL POLYMORPHISM
MONOCLINIC POLYMORPHIC FORM CRYSTAL STRUCTURE
NATURAL PRODUCT
SESQUITERPENE LACTONE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The title compound, dendocarbin A [systematic name: (1R,5aS,9aS,9bR)-1-hydroxy-6,6,9a-trimethyldodecahydronaphtho[1,2-c]furan-3-one], C15H22O3, is a sesquiterpene lactone isolated from Drimys winteri var chilensis. The monoclinic phase described herein displays an identical molecular structure to the orthorhombic phase that we reported previously [Paz Robles et al. (2014). Acta Cryst. C70, 1007-1010], while varying significantly in chain pitch, and can thus be considered as a borderline case of one-dimensional isostructural polymorphism.
Fil: Paz, Cristian. Universidad de La Frontera; Chile
Fil: Burgos, Viviana. Universidad de La Frontera; Chile
Fil: Suarez, Sebastian. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica; Argentina
description The title compound, dendocarbin A [systematic name: (1R,5aS,9aS,9bR)-1-hydroxy-6,6,9a-trimethyldodecahydronaphtho[1,2-c]furan-3-one], C15H22O3, is a sesquiterpene lactone isolated from Drimys winteri var chilensis. The monoclinic phase described herein displays an identical molecular structure to the orthorhombic phase that we reported previously [Paz Robles et al. (2014). Acta Cryst. C70, 1007-1010], while varying significantly in chain pitch, and can thus be considered as a borderline case of one-dimensional isostructural polymorphism.
publishDate 2015
dc.date.none.fl_str_mv 2015-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/98548
Paz, Cristian; Burgos, Viviana; Suarez, Sebastian; Baggio, Ricardo Fortunato; A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism; International Union of Crystallography; Acta Crystallographica Section C: Structural Chemistry; 71; 4-2015; 294-297
0108-2701
2053-2296
CONICET Digital
CONICET
url http://hdl.handle.net/11336/98548
identifier_str_mv Paz, Cristian; Burgos, Viviana; Suarez, Sebastian; Baggio, Ricardo Fortunato; A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism; International Union of Crystallography; Acta Crystallographica Section C: Structural Chemistry; 71; 4-2015; 294-297
0108-2701
2053-2296
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S2053229615004994
info:eu-repo/semantics/altIdentifier/doi/10.1107/S2053229615004994
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv International Union of Crystallography
publisher.none.fl_str_mv International Union of Crystallography
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432