Dependence of the network structure of cured styrene butadiene rubber on the sulphur content

Autores
Salgueiro, Walter Alberto; Marzocca, Angel José; Somoza, A.; Consolati, G.; Cerveny, S.; Quassollo Infanzon, Gonzalo Emiliano; Goyanes, Silvia Nair
Año de publicación
2004
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
An investigation about the dependence of the physical properties of styrene-butadiene rubber copolymers (cured with different sulphur content, in order to obtain various networks) on the crosslink density was carried out by means of dynamical mechanical analysis, differential scanning calorimetry and positron annihilation lifetime spectroscopy. SBR specimens were cured with different sulphur content, in order to obtain various networks. On increasing the crosslink density, the glass transition temperature increases and the fractional free volume decreases. The thermal expansion coefficient of the free volume decreases in the rubbery phase by increasing the crosslink density, owing to the slower rate of expansion of nanoholes; furthermore, it seems influenced by the percentage of polysulfide density. The density of nanoholes is independent of the temperature, but decreases on adding sulphur. The results can be framed within the Simha-Somcynsky free volume theory. © 2004 Published by Elsevier Ltd.
Fil: Salgueiro, Walter Alberto. Universidad Nacional del Centro de la Provincia de Buenos Aires; Argentina
Fil: Marzocca, Angel José. Univ. N.; Argentina
Fil: Somoza, A.. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina. Fisica; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires; Argentina
Fil: Consolati, G.. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Cerveny, S.. Univ. N.; Argentina. Politecnico di Milano; Italia
Fil: Quassollo Infanzon, Gonzalo Emiliano. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina
Fil: Goyanes, Silvia Nair. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina
Materia
Free Volume
Nanohole
Sbr Copolymer
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/73413
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Dependence of the network structure of cured styrene butadiene rubber on the sulphur contentSalgueiro, Walter AlbertoMarzocca, Angel JoséSomoza, A.Consolati, G.Cerveny, S.Quassollo Infanzon, Gonzalo EmilianoGoyanes, Silvia NairFree VolumeNanoholeSbr Copolymerhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1An investigation about the dependence of the physical properties of styrene-butadiene rubber copolymers (cured with different sulphur content, in order to obtain various networks) on the crosslink density was carried out by means of dynamical mechanical analysis, differential scanning calorimetry and positron annihilation lifetime spectroscopy. SBR specimens were cured with different sulphur content, in order to obtain various networks. On increasing the crosslink density, the glass transition temperature increases and the fractional free volume decreases. The thermal expansion coefficient of the free volume decreases in the rubbery phase by increasing the crosslink density, owing to the slower rate of expansion of nanoholes; furthermore, it seems influenced by the percentage of polysulfide density. The density of nanoholes is independent of the temperature, but decreases on adding sulphur. The results can be framed within the Simha-Somcynsky free volume theory. © 2004 Published by Elsevier Ltd.Fil: Salgueiro, Walter Alberto. Universidad Nacional del Centro de la Provincia de Buenos Aires; ArgentinaFil: Marzocca, Angel José. Univ. N.; ArgentinaFil: Somoza, A.. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina. Fisica; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires; ArgentinaFil: Consolati, G.. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Cerveny, S.. Univ. N.; Argentina. Politecnico di Milano; ItaliaFil: Quassollo Infanzon, Gonzalo Emiliano. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; ArgentinaFil: Goyanes, Silvia Nair. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; ArgentinaElsevier2004-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/73413Salgueiro, Walter Alberto; Marzocca, Angel José; Somoza, A.; Consolati, G.; Cerveny, S.; et al.; Dependence of the network structure of cured styrene butadiene rubber on the sulphur content; Elsevier; Polymer; 45; 17; 12-2004; 6037-60440032-3861CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymer.2004.05.008info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:05:25Zoai:ri.conicet.gov.ar:11336/73413instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:05:25.802CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Dependence of the network structure of cured styrene butadiene rubber on the sulphur content
title Dependence of the network structure of cured styrene butadiene rubber on the sulphur content
spellingShingle Dependence of the network structure of cured styrene butadiene rubber on the sulphur content
Salgueiro, Walter Alberto
Free Volume
Nanohole
Sbr Copolymer
title_short Dependence of the network structure of cured styrene butadiene rubber on the sulphur content
title_full Dependence of the network structure of cured styrene butadiene rubber on the sulphur content
title_fullStr Dependence of the network structure of cured styrene butadiene rubber on the sulphur content
title_full_unstemmed Dependence of the network structure of cured styrene butadiene rubber on the sulphur content
title_sort Dependence of the network structure of cured styrene butadiene rubber on the sulphur content
dc.creator.none.fl_str_mv Salgueiro, Walter Alberto
Marzocca, Angel José
Somoza, A.
Consolati, G.
Cerveny, S.
Quassollo Infanzon, Gonzalo Emiliano
Goyanes, Silvia Nair
author Salgueiro, Walter Alberto
author_facet Salgueiro, Walter Alberto
Marzocca, Angel José
Somoza, A.
Consolati, G.
Cerveny, S.
Quassollo Infanzon, Gonzalo Emiliano
Goyanes, Silvia Nair
author_role author
author2 Marzocca, Angel José
Somoza, A.
Consolati, G.
Cerveny, S.
Quassollo Infanzon, Gonzalo Emiliano
Goyanes, Silvia Nair
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Free Volume
Nanohole
Sbr Copolymer
topic Free Volume
Nanohole
Sbr Copolymer
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv An investigation about the dependence of the physical properties of styrene-butadiene rubber copolymers (cured with different sulphur content, in order to obtain various networks) on the crosslink density was carried out by means of dynamical mechanical analysis, differential scanning calorimetry and positron annihilation lifetime spectroscopy. SBR specimens were cured with different sulphur content, in order to obtain various networks. On increasing the crosslink density, the glass transition temperature increases and the fractional free volume decreases. The thermal expansion coefficient of the free volume decreases in the rubbery phase by increasing the crosslink density, owing to the slower rate of expansion of nanoholes; furthermore, it seems influenced by the percentage of polysulfide density. The density of nanoholes is independent of the temperature, but decreases on adding sulphur. The results can be framed within the Simha-Somcynsky free volume theory. © 2004 Published by Elsevier Ltd.
Fil: Salgueiro, Walter Alberto. Universidad Nacional del Centro de la Provincia de Buenos Aires; Argentina
Fil: Marzocca, Angel José. Univ. N.; Argentina
Fil: Somoza, A.. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina. Fisica; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires; Argentina
Fil: Consolati, G.. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Cerveny, S.. Univ. N.; Argentina. Politecnico di Milano; Italia
Fil: Quassollo Infanzon, Gonzalo Emiliano. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina
Fil: Goyanes, Silvia Nair. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina
description An investigation about the dependence of the physical properties of styrene-butadiene rubber copolymers (cured with different sulphur content, in order to obtain various networks) on the crosslink density was carried out by means of dynamical mechanical analysis, differential scanning calorimetry and positron annihilation lifetime spectroscopy. SBR specimens were cured with different sulphur content, in order to obtain various networks. On increasing the crosslink density, the glass transition temperature increases and the fractional free volume decreases. The thermal expansion coefficient of the free volume decreases in the rubbery phase by increasing the crosslink density, owing to the slower rate of expansion of nanoholes; furthermore, it seems influenced by the percentage of polysulfide density. The density of nanoholes is independent of the temperature, but decreases on adding sulphur. The results can be framed within the Simha-Somcynsky free volume theory. © 2004 Published by Elsevier Ltd.
publishDate 2004
dc.date.none.fl_str_mv 2004-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/73413
Salgueiro, Walter Alberto; Marzocca, Angel José; Somoza, A.; Consolati, G.; Cerveny, S.; et al.; Dependence of the network structure of cured styrene butadiene rubber on the sulphur content; Elsevier; Polymer; 45; 17; 12-2004; 6037-6044
0032-3861
CONICET Digital
CONICET
url http://hdl.handle.net/11336/73413
identifier_str_mv Salgueiro, Walter Alberto; Marzocca, Angel José; Somoza, A.; Consolati, G.; Cerveny, S.; et al.; Dependence of the network structure of cured styrene butadiene rubber on the sulphur content; Elsevier; Polymer; 45; 17; 12-2004; 6037-6044
0032-3861
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymer.2004.05.008
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846781332593573888
score 12.982451

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