Dependence of the network structure of cured styrene butadiene rubber on the sulphur content
- Autores
- Salgueiro, Walter Alberto; Marzocca, Angel José; Somoza, A.; Consolati, G.; Cerveny, S.; Quassollo Infanzon, Gonzalo Emiliano; Goyanes, Silvia Nair
- Año de publicación
- 2004
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- An investigation about the dependence of the physical properties of styrene-butadiene rubber copolymers (cured with different sulphur content, in order to obtain various networks) on the crosslink density was carried out by means of dynamical mechanical analysis, differential scanning calorimetry and positron annihilation lifetime spectroscopy. SBR specimens were cured with different sulphur content, in order to obtain various networks. On increasing the crosslink density, the glass transition temperature increases and the fractional free volume decreases. The thermal expansion coefficient of the free volume decreases in the rubbery phase by increasing the crosslink density, owing to the slower rate of expansion of nanoholes; furthermore, it seems influenced by the percentage of polysulfide density. The density of nanoholes is independent of the temperature, but decreases on adding sulphur. The results can be framed within the Simha-Somcynsky free volume theory. © 2004 Published by Elsevier Ltd.
Fil: Salgueiro, Walter Alberto. Universidad Nacional del Centro de la Provincia de Buenos Aires; Argentina
Fil: Marzocca, Angel José. Univ. N.; Argentina
Fil: Somoza, A.. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina. Fisica; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires; Argentina
Fil: Consolati, G.. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Cerveny, S.. Univ. N.; Argentina. Politecnico di Milano; Italia
Fil: Quassollo Infanzon, Gonzalo Emiliano. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina
Fil: Goyanes, Silvia Nair. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina - Materia
-
Free Volume
Nanohole
Sbr Copolymer - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/73413
Ver los metadatos del registro completo
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Dependence of the network structure of cured styrene butadiene rubber on the sulphur contentSalgueiro, Walter AlbertoMarzocca, Angel JoséSomoza, A.Consolati, G.Cerveny, S.Quassollo Infanzon, Gonzalo EmilianoGoyanes, Silvia NairFree VolumeNanoholeSbr Copolymerhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1An investigation about the dependence of the physical properties of styrene-butadiene rubber copolymers (cured with different sulphur content, in order to obtain various networks) on the crosslink density was carried out by means of dynamical mechanical analysis, differential scanning calorimetry and positron annihilation lifetime spectroscopy. SBR specimens were cured with different sulphur content, in order to obtain various networks. On increasing the crosslink density, the glass transition temperature increases and the fractional free volume decreases. The thermal expansion coefficient of the free volume decreases in the rubbery phase by increasing the crosslink density, owing to the slower rate of expansion of nanoholes; furthermore, it seems influenced by the percentage of polysulfide density. The density of nanoholes is independent of the temperature, but decreases on adding sulphur. The results can be framed within the Simha-Somcynsky free volume theory. © 2004 Published by Elsevier Ltd.Fil: Salgueiro, Walter Alberto. Universidad Nacional del Centro de la Provincia de Buenos Aires; ArgentinaFil: Marzocca, Angel José. Univ. N.; ArgentinaFil: Somoza, A.. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina. Fisica; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires; ArgentinaFil: Consolati, G.. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Cerveny, S.. Univ. N.; Argentina. Politecnico di Milano; ItaliaFil: Quassollo Infanzon, Gonzalo Emiliano. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; ArgentinaFil: Goyanes, Silvia Nair. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; ArgentinaElsevier2004-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/73413Salgueiro, Walter Alberto; Marzocca, Angel José; Somoza, A.; Consolati, G.; Cerveny, S.; et al.; Dependence of the network structure of cured styrene butadiene rubber on the sulphur content; Elsevier; Polymer; 45; 17; 12-2004; 6037-60440032-3861CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymer.2004.05.008info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:37:16Zoai:ri.conicet.gov.ar:11336/73413instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:37:16.991CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Dependence of the network structure of cured styrene butadiene rubber on the sulphur content |
title |
Dependence of the network structure of cured styrene butadiene rubber on the sulphur content |
spellingShingle |
Dependence of the network structure of cured styrene butadiene rubber on the sulphur content Salgueiro, Walter Alberto Free Volume Nanohole Sbr Copolymer |
title_short |
Dependence of the network structure of cured styrene butadiene rubber on the sulphur content |
title_full |
Dependence of the network structure of cured styrene butadiene rubber on the sulphur content |
title_fullStr |
Dependence of the network structure of cured styrene butadiene rubber on the sulphur content |
title_full_unstemmed |
Dependence of the network structure of cured styrene butadiene rubber on the sulphur content |
title_sort |
Dependence of the network structure of cured styrene butadiene rubber on the sulphur content |
dc.creator.none.fl_str_mv |
Salgueiro, Walter Alberto Marzocca, Angel José Somoza, A. Consolati, G. Cerveny, S. Quassollo Infanzon, Gonzalo Emiliano Goyanes, Silvia Nair |
author |
Salgueiro, Walter Alberto |
author_facet |
Salgueiro, Walter Alberto Marzocca, Angel José Somoza, A. Consolati, G. Cerveny, S. Quassollo Infanzon, Gonzalo Emiliano Goyanes, Silvia Nair |
author_role |
author |
author2 |
Marzocca, Angel José Somoza, A. Consolati, G. Cerveny, S. Quassollo Infanzon, Gonzalo Emiliano Goyanes, Silvia Nair |
author2_role |
author author author author author author |
dc.subject.none.fl_str_mv |
Free Volume Nanohole Sbr Copolymer |
topic |
Free Volume Nanohole Sbr Copolymer |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.3 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
An investigation about the dependence of the physical properties of styrene-butadiene rubber copolymers (cured with different sulphur content, in order to obtain various networks) on the crosslink density was carried out by means of dynamical mechanical analysis, differential scanning calorimetry and positron annihilation lifetime spectroscopy. SBR specimens were cured with different sulphur content, in order to obtain various networks. On increasing the crosslink density, the glass transition temperature increases and the fractional free volume decreases. The thermal expansion coefficient of the free volume decreases in the rubbery phase by increasing the crosslink density, owing to the slower rate of expansion of nanoholes; furthermore, it seems influenced by the percentage of polysulfide density. The density of nanoholes is independent of the temperature, but decreases on adding sulphur. The results can be framed within the Simha-Somcynsky free volume theory. © 2004 Published by Elsevier Ltd. Fil: Salgueiro, Walter Alberto. Universidad Nacional del Centro de la Provincia de Buenos Aires; Argentina Fil: Marzocca, Angel José. Univ. N.; Argentina Fil: Somoza, A.. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina. Fisica; Argentina. Universidad Nacional del Centro de la Provincia de Buenos Aires; Argentina Fil: Consolati, G.. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Cerveny, S.. Univ. N.; Argentina. Politecnico di Milano; Italia Fil: Quassollo Infanzon, Gonzalo Emiliano. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina Fil: Goyanes, Silvia Nair. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina |
description |
An investigation about the dependence of the physical properties of styrene-butadiene rubber copolymers (cured with different sulphur content, in order to obtain various networks) on the crosslink density was carried out by means of dynamical mechanical analysis, differential scanning calorimetry and positron annihilation lifetime spectroscopy. SBR specimens were cured with different sulphur content, in order to obtain various networks. On increasing the crosslink density, the glass transition temperature increases and the fractional free volume decreases. The thermal expansion coefficient of the free volume decreases in the rubbery phase by increasing the crosslink density, owing to the slower rate of expansion of nanoholes; furthermore, it seems influenced by the percentage of polysulfide density. The density of nanoholes is independent of the temperature, but decreases on adding sulphur. The results can be framed within the Simha-Somcynsky free volume theory. © 2004 Published by Elsevier Ltd. |
publishDate |
2004 |
dc.date.none.fl_str_mv |
2004-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/73413 Salgueiro, Walter Alberto; Marzocca, Angel José; Somoza, A.; Consolati, G.; Cerveny, S.; et al.; Dependence of the network structure of cured styrene butadiene rubber on the sulphur content; Elsevier; Polymer; 45; 17; 12-2004; 6037-6044 0032-3861 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/73413 |
identifier_str_mv |
Salgueiro, Walter Alberto; Marzocca, Angel José; Somoza, A.; Consolati, G.; Cerveny, S.; et al.; Dependence of the network structure of cured styrene butadiene rubber on the sulphur content; Elsevier; Polymer; 45; 17; 12-2004; 6037-6044 0032-3861 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.polymer.2004.05.008 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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13.070432 |