Polyvinyl alcohol-polyethylenglycol blends with tungstophosphoric acid addition: Synthesis and characterization
- Autores
- Monopoli, Víctor D.; Pizzio, Luis Rene; Blanco, Mirta Noemi
- Año de publicación
- 2008
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- New materials, based on a Keggin-structured compound (tungstophosphoric acid) immobilized in a polymeric matrix formed by a blend of polyvinyl alcohol and polyethylenglycol with 400, 2000, and 6000 Da molecular weight, were prepared and characterized. Hydrogels with physical type links were produced, using the freezing-thawing technique, and are an alternative to the matrices traditionally obtained by developing chemical links by the use of cross-linkers. The supported tungstophosphoric acid retained its Keggin primary structure intact. There is evidence of a heteropolyacid-polymeric matrix interaction, which could occur between the [PW12O40]3- Keggin anions and protonated hydroxyl groups C-OH2 + of the support. An effective immobilization was achieved, because there was no anion solubilization when the materials were put in contact with toluene at reflux. By differential scanning calorimetry and thermogravimetrical analysis, it was observed that the materials containing tungstophosphoric acid can be used as catalysts in reactions carried out at temperatures lower than 160-200 °C, without degradation of the solids, the temperature being dependent on the tungstophosphoric acid content and, at a lesser extent, on the polyethylenglycol molecular weight.
Fil: Monopoli, Víctor D.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Blanco, Mirta Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina - Materia
-
Freezing-Thawing
Polyethylenglycol
Polyvinyl Alcohol
Tungstophosphoric Acid - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/54008
Ver los metadatos del registro completo
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Polyvinyl alcohol-polyethylenglycol blends with tungstophosphoric acid addition: Synthesis and characterizationMonopoli, Víctor D.Pizzio, Luis ReneBlanco, Mirta NoemiFreezing-ThawingPolyethylenglycolPolyvinyl AlcoholTungstophosphoric Acidhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2New materials, based on a Keggin-structured compound (tungstophosphoric acid) immobilized in a polymeric matrix formed by a blend of polyvinyl alcohol and polyethylenglycol with 400, 2000, and 6000 Da molecular weight, were prepared and characterized. Hydrogels with physical type links were produced, using the freezing-thawing technique, and are an alternative to the matrices traditionally obtained by developing chemical links by the use of cross-linkers. The supported tungstophosphoric acid retained its Keggin primary structure intact. There is evidence of a heteropolyacid-polymeric matrix interaction, which could occur between the [PW12O40]3- Keggin anions and protonated hydroxyl groups C-OH2 + of the support. An effective immobilization was achieved, because there was no anion solubilization when the materials were put in contact with toluene at reflux. By differential scanning calorimetry and thermogravimetrical analysis, it was observed that the materials containing tungstophosphoric acid can be used as catalysts in reactions carried out at temperatures lower than 160-200 °C, without degradation of the solids, the temperature being dependent on the tungstophosphoric acid content and, at a lesser extent, on the polyethylenglycol molecular weight.Fil: Monopoli, Víctor D.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Blanco, Mirta Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaElsevier Science Sa2008-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/54008Monopoli, Víctor D.; Pizzio, Luis Rene; Blanco, Mirta Noemi; Polyvinyl alcohol-polyethylenglycol blends with tungstophosphoric acid addition: Synthesis and characterization; Elsevier Science Sa; Materials Chemistry and Physics; 108; 2-3; 4-2008; 331-3360254-0584CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.matchemphys.2007.09.042info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0254058407006116info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:51:02Zoai:ri.conicet.gov.ar:11336/54008instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:51:02.869CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Polyvinyl alcohol-polyethylenglycol blends with tungstophosphoric acid addition: Synthesis and characterization |
title |
Polyvinyl alcohol-polyethylenglycol blends with tungstophosphoric acid addition: Synthesis and characterization |
spellingShingle |
Polyvinyl alcohol-polyethylenglycol blends with tungstophosphoric acid addition: Synthesis and characterization Monopoli, Víctor D. Freezing-Thawing Polyethylenglycol Polyvinyl Alcohol Tungstophosphoric Acid |
title_short |
Polyvinyl alcohol-polyethylenglycol blends with tungstophosphoric acid addition: Synthesis and characterization |
title_full |
Polyvinyl alcohol-polyethylenglycol blends with tungstophosphoric acid addition: Synthesis and characterization |
title_fullStr |
Polyvinyl alcohol-polyethylenglycol blends with tungstophosphoric acid addition: Synthesis and characterization |
title_full_unstemmed |
Polyvinyl alcohol-polyethylenglycol blends with tungstophosphoric acid addition: Synthesis and characterization |
title_sort |
Polyvinyl alcohol-polyethylenglycol blends with tungstophosphoric acid addition: Synthesis and characterization |
dc.creator.none.fl_str_mv |
Monopoli, Víctor D. Pizzio, Luis Rene Blanco, Mirta Noemi |
author |
Monopoli, Víctor D. |
author_facet |
Monopoli, Víctor D. Pizzio, Luis Rene Blanco, Mirta Noemi |
author_role |
author |
author2 |
Pizzio, Luis Rene Blanco, Mirta Noemi |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Freezing-Thawing Polyethylenglycol Polyvinyl Alcohol Tungstophosphoric Acid |
topic |
Freezing-Thawing Polyethylenglycol Polyvinyl Alcohol Tungstophosphoric Acid |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
New materials, based on a Keggin-structured compound (tungstophosphoric acid) immobilized in a polymeric matrix formed by a blend of polyvinyl alcohol and polyethylenglycol with 400, 2000, and 6000 Da molecular weight, were prepared and characterized. Hydrogels with physical type links were produced, using the freezing-thawing technique, and are an alternative to the matrices traditionally obtained by developing chemical links by the use of cross-linkers. The supported tungstophosphoric acid retained its Keggin primary structure intact. There is evidence of a heteropolyacid-polymeric matrix interaction, which could occur between the [PW12O40]3- Keggin anions and protonated hydroxyl groups C-OH2 + of the support. An effective immobilization was achieved, because there was no anion solubilization when the materials were put in contact with toluene at reflux. By differential scanning calorimetry and thermogravimetrical analysis, it was observed that the materials containing tungstophosphoric acid can be used as catalysts in reactions carried out at temperatures lower than 160-200 °C, without degradation of the solids, the temperature being dependent on the tungstophosphoric acid content and, at a lesser extent, on the polyethylenglycol molecular weight. Fil: Monopoli, Víctor D.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina Fil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina Fil: Blanco, Mirta Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina |
description |
New materials, based on a Keggin-structured compound (tungstophosphoric acid) immobilized in a polymeric matrix formed by a blend of polyvinyl alcohol and polyethylenglycol with 400, 2000, and 6000 Da molecular weight, were prepared and characterized. Hydrogels with physical type links were produced, using the freezing-thawing technique, and are an alternative to the matrices traditionally obtained by developing chemical links by the use of cross-linkers. The supported tungstophosphoric acid retained its Keggin primary structure intact. There is evidence of a heteropolyacid-polymeric matrix interaction, which could occur between the [PW12O40]3- Keggin anions and protonated hydroxyl groups C-OH2 + of the support. An effective immobilization was achieved, because there was no anion solubilization when the materials were put in contact with toluene at reflux. By differential scanning calorimetry and thermogravimetrical analysis, it was observed that the materials containing tungstophosphoric acid can be used as catalysts in reactions carried out at temperatures lower than 160-200 °C, without degradation of the solids, the temperature being dependent on the tungstophosphoric acid content and, at a lesser extent, on the polyethylenglycol molecular weight. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/54008 Monopoli, Víctor D.; Pizzio, Luis Rene; Blanco, Mirta Noemi; Polyvinyl alcohol-polyethylenglycol blends with tungstophosphoric acid addition: Synthesis and characterization; Elsevier Science Sa; Materials Chemistry and Physics; 108; 2-3; 4-2008; 331-336 0254-0584 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/54008 |
identifier_str_mv |
Monopoli, Víctor D.; Pizzio, Luis Rene; Blanco, Mirta Noemi; Polyvinyl alcohol-polyethylenglycol blends with tungstophosphoric acid addition: Synthesis and characterization; Elsevier Science Sa; Materials Chemistry and Physics; 108; 2-3; 4-2008; 331-336 0254-0584 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.matchemphys.2007.09.042 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0254058407006116 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science Sa |
publisher.none.fl_str_mv |
Elsevier Science Sa |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1842269069800112128 |
score |
13.13397 |