Encapsulation of Clay Within Polymer Particles in a High Solids Aqueous Dispersion

Autores
Reyes, Yury; Peruzzo, Pablo Jose; Fernández, Mercedes; Paulis, Maria; Leiza, Jose R.
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
By using a two-step polymerization process, it was possible to encapsulate clay platelets within polymer particles dispersed in water. First, seed polymer particles with chemically bonded clay were obtained by batch miniemulsion polymerization. Then, the clay was buried within the particles by the addition of neat monomer in a second step. The final stable dispersions can have a solids content of up to 50 wt %. Transmission electron microscopy images clearly show the presence of clay platelets inside the polymer colloids, although they are not totally exfoliated. The obtained nanocomposites showed an increase in both the storage modulus in the rubbery state and the water resistance as the clay content increases. The approach presented here might be useful for encapsulating other high-aspect ratio nanofillers.
Fil: Reyes, Yury. Universidad del Pais Vasco. POLYMAT; España
Fil: Peruzzo, Pablo Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad del Pais Vasco. POLYMAT; España
Fil: Fernández, Mercedes. Universidad del Pais Vasco. POLYMAT; España
Fil: Paulis, Maria. Universidad del Pais Vasco. POLYMAT; España
Fil: Leiza, Jose R.. Universidad del Pais Vasco. POLYMAT; España
Materia
Clay Encapsulation
(Mini)Emulsion Polymerization
Hybrid Particles
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5311
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Encapsulation of Clay Within Polymer Particles in a High Solids Aqueous DispersionReyes, YuryPeruzzo, Pablo JoseFernández, MercedesPaulis, MariaLeiza, Jose R.Clay Encapsulation(Mini)Emulsion PolymerizationHybrid Particleshttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2By using a two-step polymerization process, it was possible to encapsulate clay platelets within polymer particles dispersed in water. First, seed polymer particles with chemically bonded clay were obtained by batch miniemulsion polymerization. Then, the clay was buried within the particles by the addition of neat monomer in a second step. The final stable dispersions can have a solids content of up to 50 wt %. Transmission electron microscopy images clearly show the presence of clay platelets inside the polymer colloids, although they are not totally exfoliated. The obtained nanocomposites showed an increase in both the storage modulus in the rubbery state and the water resistance as the clay content increases. The approach presented here might be useful for encapsulating other high-aspect ratio nanofillers.Fil: Reyes, Yury. Universidad del Pais Vasco. POLYMAT; EspañaFil: Peruzzo, Pablo Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad del Pais Vasco. POLYMAT; EspañaFil: Fernández, Mercedes. Universidad del Pais Vasco. POLYMAT; EspañaFil: Paulis, Maria. Universidad del Pais Vasco. POLYMAT; EspañaFil: Leiza, Jose R.. Universidad del Pais Vasco. POLYMAT; EspañaAmerican Chemical Society2013-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5311Reyes, Yury; Peruzzo, Pablo Jose; Fernández, Mercedes; Paulis, Maria; Leiza, Jose R.; Encapsulation of Clay Within Polymer Particles in a High Solids Aqueous Dispersion; American Chemical Society; Langmuir; 29; 31; 7-2013; 9849-98560743-7463enginfo:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/la401301sinfo:eu-repo/semantics/altIdentifier/doi/10.1021/la401301sinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:09:25Zoai:ri.conicet.gov.ar:11336/5311instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:09:25.885CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Encapsulation of Clay Within Polymer Particles in a High Solids Aqueous Dispersion
title Encapsulation of Clay Within Polymer Particles in a High Solids Aqueous Dispersion
spellingShingle Encapsulation of Clay Within Polymer Particles in a High Solids Aqueous Dispersion
Reyes, Yury
Clay Encapsulation
(Mini)Emulsion Polymerization
Hybrid Particles
title_short Encapsulation of Clay Within Polymer Particles in a High Solids Aqueous Dispersion
title_full Encapsulation of Clay Within Polymer Particles in a High Solids Aqueous Dispersion
title_fullStr Encapsulation of Clay Within Polymer Particles in a High Solids Aqueous Dispersion
title_full_unstemmed Encapsulation of Clay Within Polymer Particles in a High Solids Aqueous Dispersion
title_sort Encapsulation of Clay Within Polymer Particles in a High Solids Aqueous Dispersion
dc.creator.none.fl_str_mv Reyes, Yury
Peruzzo, Pablo Jose
Fernández, Mercedes
Paulis, Maria
Leiza, Jose R.
author Reyes, Yury
author_facet Reyes, Yury
Peruzzo, Pablo Jose
Fernández, Mercedes
Paulis, Maria
Leiza, Jose R.
author_role author
author2 Peruzzo, Pablo Jose
Fernández, Mercedes
Paulis, Maria
Leiza, Jose R.
author2_role author
author
author
author
dc.subject.none.fl_str_mv Clay Encapsulation
(Mini)Emulsion Polymerization
Hybrid Particles
topic Clay Encapsulation
(Mini)Emulsion Polymerization
Hybrid Particles
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv By using a two-step polymerization process, it was possible to encapsulate clay platelets within polymer particles dispersed in water. First, seed polymer particles with chemically bonded clay were obtained by batch miniemulsion polymerization. Then, the clay was buried within the particles by the addition of neat monomer in a second step. The final stable dispersions can have a solids content of up to 50 wt %. Transmission electron microscopy images clearly show the presence of clay platelets inside the polymer colloids, although they are not totally exfoliated. The obtained nanocomposites showed an increase in both the storage modulus in the rubbery state and the water resistance as the clay content increases. The approach presented here might be useful for encapsulating other high-aspect ratio nanofillers.
Fil: Reyes, Yury. Universidad del Pais Vasco. POLYMAT; España
Fil: Peruzzo, Pablo Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad del Pais Vasco. POLYMAT; España
Fil: Fernández, Mercedes. Universidad del Pais Vasco. POLYMAT; España
Fil: Paulis, Maria. Universidad del Pais Vasco. POLYMAT; España
Fil: Leiza, Jose R.. Universidad del Pais Vasco. POLYMAT; España
description By using a two-step polymerization process, it was possible to encapsulate clay platelets within polymer particles dispersed in water. First, seed polymer particles with chemically bonded clay were obtained by batch miniemulsion polymerization. Then, the clay was buried within the particles by the addition of neat monomer in a second step. The final stable dispersions can have a solids content of up to 50 wt %. Transmission electron microscopy images clearly show the presence of clay platelets inside the polymer colloids, although they are not totally exfoliated. The obtained nanocomposites showed an increase in both the storage modulus in the rubbery state and the water resistance as the clay content increases. The approach presented here might be useful for encapsulating other high-aspect ratio nanofillers.
publishDate 2013
dc.date.none.fl_str_mv 2013-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5311
Reyes, Yury; Peruzzo, Pablo Jose; Fernández, Mercedes; Paulis, Maria; Leiza, Jose R.; Encapsulation of Clay Within Polymer Particles in a High Solids Aqueous Dispersion; American Chemical Society; Langmuir; 29; 31; 7-2013; 9849-9856
0743-7463
url http://hdl.handle.net/11336/5311
identifier_str_mv Reyes, Yury; Peruzzo, Pablo Jose; Fernández, Mercedes; Paulis, Maria; Leiza, Jose R.; Encapsulation of Clay Within Polymer Particles in a High Solids Aqueous Dispersion; American Chemical Society; Langmuir; 29; 31; 7-2013; 9849-9856
0743-7463
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/la401301s
info:eu-repo/semantics/altIdentifier/doi/10.1021/la401301s
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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