Mass-transfer study and copper ions removal using a modified hydrocyclone as electrochemical reactor

Autores
Resio, L. C.; Gonzalez Perez, Omar; Bisang, Jose Maria
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Mass-transfer coefficients between an electrolyte solution and the wall of a hydrocyclone were experimentally determined by using the electrochemical technique. The local mass-transfer coefficients were measured as a function of the axial distance from the entrance changing the inlet volumetric flow rate and the underflow stream. An enhancement of mass-transfer was observed in comparison to that predicted for developing axial flow in an annular duct, being the cylindrical part more active than the conical one. The global mass-transfer coefficient in the cylindrical region depends on the Reynolds number raised to an exponent of 0.79, in accordance with the mass-transfer behavior of decaying annular swirl flow. The modified hydrocyclone was also examined for the removal of copper from dilute synthetic solutions. A diminution of copper concentration from 400 ppm to 40 ppm was achieved after 60 minutes of electrolysis in a recirculating system and the contaminant was recovered as a metal powder separated by the hydrocyclone. The space time yield and the specific energy consumption were 12.5 kg m-3 h-1 and 4.9 kWh kg-1, respectively, with a cumulative current efficiency of 54%, showing that the modified hydrocyclone is a suitable reactor for the electrochemical treatment of effluents.
Fil: Resio, L. C.. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina
Fil: Gonzalez Perez, Omar. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Bisang, Jose Maria. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Materia
Electrochemical Engineering
Environment
Mass-Transfer
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/67988
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Mass-transfer study and copper ions removal using a modified hydrocyclone as electrochemical reactorResio, L. C.Gonzalez Perez, OmarBisang, Jose MariaElectrochemical EngineeringEnvironmentMass-Transferhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Mass-transfer coefficients between an electrolyte solution and the wall of a hydrocyclone were experimentally determined by using the electrochemical technique. The local mass-transfer coefficients were measured as a function of the axial distance from the entrance changing the inlet volumetric flow rate and the underflow stream. An enhancement of mass-transfer was observed in comparison to that predicted for developing axial flow in an annular duct, being the cylindrical part more active than the conical one. The global mass-transfer coefficient in the cylindrical region depends on the Reynolds number raised to an exponent of 0.79, in accordance with the mass-transfer behavior of decaying annular swirl flow. The modified hydrocyclone was also examined for the removal of copper from dilute synthetic solutions. A diminution of copper concentration from 400 ppm to 40 ppm was achieved after 60 minutes of electrolysis in a recirculating system and the contaminant was recovered as a metal powder separated by the hydrocyclone. The space time yield and the specific energy consumption were 12.5 kg m-3 h-1 and 4.9 kWh kg-1, respectively, with a cumulative current efficiency of 54%, showing that the modified hydrocyclone is a suitable reactor for the electrochemical treatment of effluents.Fil: Resio, L. C.. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; ArgentinaFil: Gonzalez Perez, Omar. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Bisang, Jose Maria. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaElectrochemical Society2017-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/67988Resio, L. C.; Gonzalez Perez, Omar; Bisang, Jose Maria; Mass-transfer study and copper ions removal using a modified hydrocyclone as electrochemical reactor; Electrochemical Society; Journal of the Electrochemical Society; 164; 14; 1-2017; E529-E5350013-46511945-7111CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://jes.ecsdl.org/lookup/doi/10.1149/2.0911714jesinfo:eu-repo/semantics/altIdentifier/doi/10.1149/2.0911714jesinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:08:51Zoai:ri.conicet.gov.ar:11336/67988instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:08:51.935CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Mass-transfer study and copper ions removal using a modified hydrocyclone as electrochemical reactor
title Mass-transfer study and copper ions removal using a modified hydrocyclone as electrochemical reactor
spellingShingle Mass-transfer study and copper ions removal using a modified hydrocyclone as electrochemical reactor
Resio, L. C.
Electrochemical Engineering
Environment
Mass-Transfer
title_short Mass-transfer study and copper ions removal using a modified hydrocyclone as electrochemical reactor
title_full Mass-transfer study and copper ions removal using a modified hydrocyclone as electrochemical reactor
title_fullStr Mass-transfer study and copper ions removal using a modified hydrocyclone as electrochemical reactor
title_full_unstemmed Mass-transfer study and copper ions removal using a modified hydrocyclone as electrochemical reactor
title_sort Mass-transfer study and copper ions removal using a modified hydrocyclone as electrochemical reactor
dc.creator.none.fl_str_mv Resio, L. C.
Gonzalez Perez, Omar
Bisang, Jose Maria
author Resio, L. C.
author_facet Resio, L. C.
Gonzalez Perez, Omar
Bisang, Jose Maria
author_role author
author2 Gonzalez Perez, Omar
Bisang, Jose Maria
author2_role author
author
dc.subject.none.fl_str_mv Electrochemical Engineering
Environment
Mass-Transfer
topic Electrochemical Engineering
Environment
Mass-Transfer
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Mass-transfer coefficients between an electrolyte solution and the wall of a hydrocyclone were experimentally determined by using the electrochemical technique. The local mass-transfer coefficients were measured as a function of the axial distance from the entrance changing the inlet volumetric flow rate and the underflow stream. An enhancement of mass-transfer was observed in comparison to that predicted for developing axial flow in an annular duct, being the cylindrical part more active than the conical one. The global mass-transfer coefficient in the cylindrical region depends on the Reynolds number raised to an exponent of 0.79, in accordance with the mass-transfer behavior of decaying annular swirl flow. The modified hydrocyclone was also examined for the removal of copper from dilute synthetic solutions. A diminution of copper concentration from 400 ppm to 40 ppm was achieved after 60 minutes of electrolysis in a recirculating system and the contaminant was recovered as a metal powder separated by the hydrocyclone. The space time yield and the specific energy consumption were 12.5 kg m-3 h-1 and 4.9 kWh kg-1, respectively, with a cumulative current efficiency of 54%, showing that the modified hydrocyclone is a suitable reactor for the electrochemical treatment of effluents.
Fil: Resio, L. C.. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina
Fil: Gonzalez Perez, Omar. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Bisang, Jose Maria. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
description Mass-transfer coefficients between an electrolyte solution and the wall of a hydrocyclone were experimentally determined by using the electrochemical technique. The local mass-transfer coefficients were measured as a function of the axial distance from the entrance changing the inlet volumetric flow rate and the underflow stream. An enhancement of mass-transfer was observed in comparison to that predicted for developing axial flow in an annular duct, being the cylindrical part more active than the conical one. The global mass-transfer coefficient in the cylindrical region depends on the Reynolds number raised to an exponent of 0.79, in accordance with the mass-transfer behavior of decaying annular swirl flow. The modified hydrocyclone was also examined for the removal of copper from dilute synthetic solutions. A diminution of copper concentration from 400 ppm to 40 ppm was achieved after 60 minutes of electrolysis in a recirculating system and the contaminant was recovered as a metal powder separated by the hydrocyclone. The space time yield and the specific energy consumption were 12.5 kg m-3 h-1 and 4.9 kWh kg-1, respectively, with a cumulative current efficiency of 54%, showing that the modified hydrocyclone is a suitable reactor for the electrochemical treatment of effluents.
publishDate 2017
dc.date.none.fl_str_mv 2017-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/67988
Resio, L. C.; Gonzalez Perez, Omar; Bisang, Jose Maria; Mass-transfer study and copper ions removal using a modified hydrocyclone as electrochemical reactor; Electrochemical Society; Journal of the Electrochemical Society; 164; 14; 1-2017; E529-E535
0013-4651
1945-7111
CONICET Digital
CONICET
url http://hdl.handle.net/11336/67988
identifier_str_mv Resio, L. C.; Gonzalez Perez, Omar; Bisang, Jose Maria; Mass-transfer study and copper ions removal using a modified hydrocyclone as electrochemical reactor; Electrochemical Society; Journal of the Electrochemical Society; 164; 14; 1-2017; E529-E535
0013-4651
1945-7111
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://jes.ecsdl.org/lookup/doi/10.1149/2.0911714jes
info:eu-repo/semantics/altIdentifier/doi/10.1149/2.0911714jes
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Electrochemical Society
publisher.none.fl_str_mv Electrochemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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