Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment
- Autores
- del Grosso, Mariela Fernanda; Chappa, Veronica Cecilia; Garcia Bermudez, Gerardo Jose; Forlerer, Elena; Behar, M.
- Año de publicación
- 2008
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The damage processes induced by swift heavy ions (SHI), can be very different to those induced by classical low ionising particles. This is dueto the high electronic stopping power of SHI. Ultra high molecular weight polyethylene (UHMWPE) was irradiated with 6.77 MeV helium and12.5 MeV carbon beams and fluences ranging from 1011 to 1013 cm−2 and 2×1010 to 5×1013 cm−2, respectively. Structural changes at thepolymer near surface region were studied by means of infrared spectroscopy measurements and wear resistance tests. With FTIR spectroscopy westudied the changes in crystallinity, double bond C_C, trans-vynilene and graphite formation and the evolution of methylene group as a functionof fluence. The experiments have determined that exists an optimum ion fluence value, that depends on the ion mass and energy, at which the wearresistance increases of about 85% respect to the unirradiated polymer. For helium this value is 2×1012 cm−2 and for carbon 4×1011 cm−2. Atthese fluence values no sign of graphite was found by FTIR studies. Using a Monte Carlo simulation program we determined that the surface areaaffected by the track core of the incoming ions was less than 19 and 35% for helium and carbon respectively.
Fil: del Grosso, Mariela Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Chappa, Veronica Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Garcia Bermudez, Gerardo Jose. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Forlerer, Elena. Comisión Nacional de Energía Atómica; Argentina
Fil: Behar, M.. No especifíca; - Materia
-
UHMWPE
Swift Heavy ions
Ion fluence analysis
FTIR spectroscopy - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/244170
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oai:ri.conicet.gov.ar:11336/244170 |
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Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardmentdel Grosso, Mariela FernandaChappa, Veronica CeciliaGarcia Bermudez, Gerardo JoseForlerer, ElenaBehar, M.UHMWPESwift Heavy ionsIon fluence analysisFTIR spectroscopyhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The damage processes induced by swift heavy ions (SHI), can be very different to those induced by classical low ionising particles. This is dueto the high electronic stopping power of SHI. Ultra high molecular weight polyethylene (UHMWPE) was irradiated with 6.77 MeV helium and12.5 MeV carbon beams and fluences ranging from 1011 to 1013 cm−2 and 2×1010 to 5×1013 cm−2, respectively. Structural changes at thepolymer near surface region were studied by means of infrared spectroscopy measurements and wear resistance tests. With FTIR spectroscopy westudied the changes in crystallinity, double bond C_C, trans-vynilene and graphite formation and the evolution of methylene group as a functionof fluence. The experiments have determined that exists an optimum ion fluence value, that depends on the ion mass and energy, at which the wearresistance increases of about 85% respect to the unirradiated polymer. For helium this value is 2×1012 cm−2 and for carbon 4×1011 cm−2. Atthese fluence values no sign of graphite was found by FTIR studies. Using a Monte Carlo simulation program we determined that the surface areaaffected by the track core of the incoming ions was less than 19 and 35% for helium and carbon respectively.Fil: del Grosso, Mariela Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Chappa, Veronica Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Garcia Bermudez, Gerardo Jose. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Forlerer, Elena. Comisión Nacional de Energía Atómica; ArgentinaFil: Behar, M.. No especifíca;Elsevier Science SA2008-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/244170del Grosso, Mariela Fernanda; Chappa, Veronica Cecilia; Garcia Bermudez, Gerardo Jose; Forlerer, Elena; Behar, M.; Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment; Elsevier Science SA; Surface and Coatings Technology; 202; 17; 5-2008; 4227-42320257-8972CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0257897208001916info:eu-repo/semantics/altIdentifier/doi/10.1016/j.surfcoat.2008.03.016info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:47:59Zoai:ri.conicet.gov.ar:11336/244170instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:47:59.402CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment |
title |
Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment |
spellingShingle |
Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment del Grosso, Mariela Fernanda UHMWPE Swift Heavy ions Ion fluence analysis FTIR spectroscopy |
title_short |
Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment |
title_full |
Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment |
title_fullStr |
Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment |
title_full_unstemmed |
Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment |
title_sort |
Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment |
dc.creator.none.fl_str_mv |
del Grosso, Mariela Fernanda Chappa, Veronica Cecilia Garcia Bermudez, Gerardo Jose Forlerer, Elena Behar, M. |
author |
del Grosso, Mariela Fernanda |
author_facet |
del Grosso, Mariela Fernanda Chappa, Veronica Cecilia Garcia Bermudez, Gerardo Jose Forlerer, Elena Behar, M. |
author_role |
author |
author2 |
Chappa, Veronica Cecilia Garcia Bermudez, Gerardo Jose Forlerer, Elena Behar, M. |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
UHMWPE Swift Heavy ions Ion fluence analysis FTIR spectroscopy |
topic |
UHMWPE Swift Heavy ions Ion fluence analysis FTIR spectroscopy |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.3 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The damage processes induced by swift heavy ions (SHI), can be very different to those induced by classical low ionising particles. This is dueto the high electronic stopping power of SHI. Ultra high molecular weight polyethylene (UHMWPE) was irradiated with 6.77 MeV helium and12.5 MeV carbon beams and fluences ranging from 1011 to 1013 cm−2 and 2×1010 to 5×1013 cm−2, respectively. Structural changes at thepolymer near surface region were studied by means of infrared spectroscopy measurements and wear resistance tests. With FTIR spectroscopy westudied the changes in crystallinity, double bond C_C, trans-vynilene and graphite formation and the evolution of methylene group as a functionof fluence. The experiments have determined that exists an optimum ion fluence value, that depends on the ion mass and energy, at which the wearresistance increases of about 85% respect to the unirradiated polymer. For helium this value is 2×1012 cm−2 and for carbon 4×1011 cm−2. Atthese fluence values no sign of graphite was found by FTIR studies. Using a Monte Carlo simulation program we determined that the surface areaaffected by the track core of the incoming ions was less than 19 and 35% for helium and carbon respectively. Fil: del Grosso, Mariela Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Chappa, Veronica Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Garcia Bermudez, Gerardo Jose. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Forlerer, Elena. Comisión Nacional de Energía Atómica; Argentina Fil: Behar, M.. No especifíca; |
description |
The damage processes induced by swift heavy ions (SHI), can be very different to those induced by classical low ionising particles. This is dueto the high electronic stopping power of SHI. Ultra high molecular weight polyethylene (UHMWPE) was irradiated with 6.77 MeV helium and12.5 MeV carbon beams and fluences ranging from 1011 to 1013 cm−2 and 2×1010 to 5×1013 cm−2, respectively. Structural changes at thepolymer near surface region were studied by means of infrared spectroscopy measurements and wear resistance tests. With FTIR spectroscopy westudied the changes in crystallinity, double bond C_C, trans-vynilene and graphite formation and the evolution of methylene group as a functionof fluence. The experiments have determined that exists an optimum ion fluence value, that depends on the ion mass and energy, at which the wearresistance increases of about 85% respect to the unirradiated polymer. For helium this value is 2×1012 cm−2 and for carbon 4×1011 cm−2. Atthese fluence values no sign of graphite was found by FTIR studies. Using a Monte Carlo simulation program we determined that the surface areaaffected by the track core of the incoming ions was less than 19 and 35% for helium and carbon respectively. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-05 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/244170 del Grosso, Mariela Fernanda; Chappa, Veronica Cecilia; Garcia Bermudez, Gerardo Jose; Forlerer, Elena; Behar, M.; Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment; Elsevier Science SA; Surface and Coatings Technology; 202; 17; 5-2008; 4227-4232 0257-8972 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/244170 |
identifier_str_mv |
del Grosso, Mariela Fernanda; Chappa, Veronica Cecilia; Garcia Bermudez, Gerardo Jose; Forlerer, Elena; Behar, M.; Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment; Elsevier Science SA; Surface and Coatings Technology; 202; 17; 5-2008; 4227-4232 0257-8972 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0257897208001916 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.surfcoat.2008.03.016 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science SA |
publisher.none.fl_str_mv |
Elsevier Science SA |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613493443002368 |
score |
13.070432 |