Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment

Autores
del Grosso, Mariela Fernanda; Chappa, Veronica Cecilia; Garcia Bermudez, Gerardo Jose; Forlerer, Elena; Behar, M.
Año de publicación
2008
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The damage processes induced by swift heavy ions (SHI), can be very different to those induced by classical low ionising particles. This is dueto the high electronic stopping power of SHI. Ultra high molecular weight polyethylene (UHMWPE) was irradiated with 6.77 MeV helium and12.5 MeV carbon beams and fluences ranging from 1011 to 1013 cm−2 and 2×1010 to 5×1013 cm−2, respectively. Structural changes at thepolymer near surface region were studied by means of infrared spectroscopy measurements and wear resistance tests. With FTIR spectroscopy westudied the changes in crystallinity, double bond C_C, trans-vynilene and graphite formation and the evolution of methylene group as a functionof fluence. The experiments have determined that exists an optimum ion fluence value, that depends on the ion mass and energy, at which the wearresistance increases of about 85% respect to the unirradiated polymer. For helium this value is 2×1012 cm−2 and for carbon 4×1011 cm−2. Atthese fluence values no sign of graphite was found by FTIR studies. Using a Monte Carlo simulation program we determined that the surface areaaffected by the track core of the incoming ions was less than 19 and 35% for helium and carbon respectively.
Fil: del Grosso, Mariela Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Chappa, Veronica Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Garcia Bermudez, Gerardo Jose. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Forlerer, Elena. Comisión Nacional de Energía Atómica; Argentina
Fil: Behar, M.. No especifíca;
Materia
UHMWPE
Swift Heavy ions
Ion fluence analysis
FTIR spectroscopy
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/244170
Acceder
id CONICETDig_12d291df27407e3f50badb66dfccbb9a
oai_identifier_str oai:ri.conicet.gov.ar:11336/244170
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardmentdel Grosso, Mariela FernandaChappa, Veronica CeciliaGarcia Bermudez, Gerardo JoseForlerer, ElenaBehar, M.UHMWPESwift Heavy ionsIon fluence analysisFTIR spectroscopyhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1The damage processes induced by swift heavy ions (SHI), can be very different to those induced by classical low ionising particles. This is dueto the high electronic stopping power of SHI. Ultra high molecular weight polyethylene (UHMWPE) was irradiated with 6.77 MeV helium and12.5 MeV carbon beams and fluences ranging from 1011 to 1013 cm−2 and 2×1010 to 5×1013 cm−2, respectively. Structural changes at thepolymer near surface region were studied by means of infrared spectroscopy measurements and wear resistance tests. With FTIR spectroscopy westudied the changes in crystallinity, double bond C_C, trans-vynilene and graphite formation and the evolution of methylene group as a functionof fluence. The experiments have determined that exists an optimum ion fluence value, that depends on the ion mass and energy, at which the wearresistance increases of about 85% respect to the unirradiated polymer. For helium this value is 2×1012 cm−2 and for carbon 4×1011 cm−2. Atthese fluence values no sign of graphite was found by FTIR studies. Using a Monte Carlo simulation program we determined that the surface areaaffected by the track core of the incoming ions was less than 19 and 35% for helium and carbon respectively.Fil: del Grosso, Mariela Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Chappa, Veronica Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Garcia Bermudez, Gerardo Jose. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Forlerer, Elena. Comisión Nacional de Energía Atómica; ArgentinaFil: Behar, M.. No especifíca;Elsevier Science SA2008-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/244170del Grosso, Mariela Fernanda; Chappa, Veronica Cecilia; Garcia Bermudez, Gerardo Jose; Forlerer, Elena; Behar, M.; Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment; Elsevier Science SA; Surface and Coatings Technology; 202; 17; 5-2008; 4227-42320257-8972CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0257897208001916info:eu-repo/semantics/altIdentifier/doi/10.1016/j.surfcoat.2008.03.016info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:16:50Zoai:ri.conicet.gov.ar:11336/244170instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:16:50.686CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment
title Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment
spellingShingle Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment
del Grosso, Mariela Fernanda
UHMWPE
Swift Heavy ions
Ion fluence analysis
FTIR spectroscopy
title_short Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment
title_full Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment
title_fullStr Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment
title_full_unstemmed Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment
title_sort Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment
dc.creator.none.fl_str_mv del Grosso, Mariela Fernanda
Chappa, Veronica Cecilia
Garcia Bermudez, Gerardo Jose
Forlerer, Elena
Behar, M.
author del Grosso, Mariela Fernanda
author_facet del Grosso, Mariela Fernanda
Chappa, Veronica Cecilia
Garcia Bermudez, Gerardo Jose
Forlerer, Elena
Behar, M.
author_role author
author2 Chappa, Veronica Cecilia
Garcia Bermudez, Gerardo Jose
Forlerer, Elena
Behar, M.
author2_role author
author
author
author
dc.subject.none.fl_str_mv UHMWPE
Swift Heavy ions
Ion fluence analysis
FTIR spectroscopy
topic UHMWPE
Swift Heavy ions
Ion fluence analysis
FTIR spectroscopy
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The damage processes induced by swift heavy ions (SHI), can be very different to those induced by classical low ionising particles. This is dueto the high electronic stopping power of SHI. Ultra high molecular weight polyethylene (UHMWPE) was irradiated with 6.77 MeV helium and12.5 MeV carbon beams and fluences ranging from 1011 to 1013 cm−2 and 2×1010 to 5×1013 cm−2, respectively. Structural changes at thepolymer near surface region were studied by means of infrared spectroscopy measurements and wear resistance tests. With FTIR spectroscopy westudied the changes in crystallinity, double bond C_C, trans-vynilene and graphite formation and the evolution of methylene group as a functionof fluence. The experiments have determined that exists an optimum ion fluence value, that depends on the ion mass and energy, at which the wearresistance increases of about 85% respect to the unirradiated polymer. For helium this value is 2×1012 cm−2 and for carbon 4×1011 cm−2. Atthese fluence values no sign of graphite was found by FTIR studies. Using a Monte Carlo simulation program we determined that the surface areaaffected by the track core of the incoming ions was less than 19 and 35% for helium and carbon respectively.
Fil: del Grosso, Mariela Fernanda. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Chappa, Veronica Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Garcia Bermudez, Gerardo Jose. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Forlerer, Elena. Comisión Nacional de Energía Atómica; Argentina
Fil: Behar, M.. No especifíca;
description The damage processes induced by swift heavy ions (SHI), can be very different to those induced by classical low ionising particles. This is dueto the high electronic stopping power of SHI. Ultra high molecular weight polyethylene (UHMWPE) was irradiated with 6.77 MeV helium and12.5 MeV carbon beams and fluences ranging from 1011 to 1013 cm−2 and 2×1010 to 5×1013 cm−2, respectively. Structural changes at thepolymer near surface region were studied by means of infrared spectroscopy measurements and wear resistance tests. With FTIR spectroscopy westudied the changes in crystallinity, double bond C_C, trans-vynilene and graphite formation and the evolution of methylene group as a functionof fluence. The experiments have determined that exists an optimum ion fluence value, that depends on the ion mass and energy, at which the wearresistance increases of about 85% respect to the unirradiated polymer. For helium this value is 2×1012 cm−2 and for carbon 4×1011 cm−2. Atthese fluence values no sign of graphite was found by FTIR studies. Using a Monte Carlo simulation program we determined that the surface areaaffected by the track core of the incoming ions was less than 19 and 35% for helium and carbon respectively.
publishDate 2008
dc.date.none.fl_str_mv 2008-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/244170
del Grosso, Mariela Fernanda; Chappa, Veronica Cecilia; Garcia Bermudez, Gerardo Jose; Forlerer, Elena; Behar, M.; Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment; Elsevier Science SA; Surface and Coatings Technology; 202; 17; 5-2008; 4227-4232
0257-8972
CONICET Digital
CONICET
url http://hdl.handle.net/11336/244170
identifier_str_mv del Grosso, Mariela Fernanda; Chappa, Veronica Cecilia; Garcia Bermudez, Gerardo Jose; Forlerer, Elena; Behar, M.; Surface characterization of ultra high molecular weight polyethylene modified by swift heavy ion beam bombardment; Elsevier Science SA; Surface and Coatings Technology; 202; 17; 5-2008; 4227-4232
0257-8972
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0257897208001916
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.surfcoat.2008.03.016
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science SA
publisher.none.fl_str_mv Elsevier Science SA
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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