Lithium extraction from β-spodumene through chlorination with chlorine gas
- Autores
- Barbosa, Lucía Isabel; Valente, Norma Graciela; Orozco, R. P.; Gonzalez, Jorge Alberto
- Año de publicación
- 2014
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The extraction of lithium by means of the chlorination roasting of b-spodumene has been studied in the temperature range from 1000 to 1100 C for periods of time from 0 to 180 min. The roasting was carried out in a fixed bed reactor using pure gaseous Cl2 as chlorinating agent. The reactants and products were characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), atomic absorption spectrometry (AAS), scanning electron microscopy (SEM) and electron probe microanalysis (EPMA). The roasting of b-spodumene with pure Cl2 at 1100 C for the period of 150 min led to quantitative extraction of lithium as lithium chloride. The solid products of the reaction of b-spodumene with Cl2 were found to be Al6Si2-O13 (mullite), and Si2O (cristobalite).
Fil: Barbosa, Lucía Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Valente, Norma Graciela. Universidad Nacional de Cuyo; Argentina
Fil: Orozco, R. P.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Gonzalez, Jorge Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina - Materia
-
Lithium
Extraction
Chlorination
Chlorine
Gas - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/31756
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Lithium extraction from β-spodumene through chlorination with chlorine gasBarbosa, Lucía IsabelValente, Norma GracielaOrozco, R. P.Gonzalez, Jorge AlbertoLithiumExtractionChlorinationChlorineGashttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The extraction of lithium by means of the chlorination roasting of b-spodumene has been studied in the temperature range from 1000 to 1100 C for periods of time from 0 to 180 min. The roasting was carried out in a fixed bed reactor using pure gaseous Cl2 as chlorinating agent. The reactants and products were characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), atomic absorption spectrometry (AAS), scanning electron microscopy (SEM) and electron probe microanalysis (EPMA). The roasting of b-spodumene with pure Cl2 at 1100 C for the period of 150 min led to quantitative extraction of lithium as lithium chloride. The solid products of the reaction of b-spodumene with Cl2 were found to be Al6Si2-O13 (mullite), and Si2O (cristobalite).Fil: Barbosa, Lucía Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Valente, Norma Graciela. Universidad Nacional de Cuyo; ArgentinaFil: Orozco, R. P.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Gonzalez, Jorge Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaElsevier2014-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31756Barbosa, Lucía Isabel; Valente, Norma Graciela; Orozco, R. P.; Gonzalez, Jorge Alberto; Lithium extraction from β-spodumene through chlorination with chlorine gas; Elsevier; Minerals Engineering; 56; 2-2014; 29-340892-6875CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0892687513003506info:eu-repo/semantics/altIdentifier/doi/10.1016/j.mineng.2013.10.026info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:58:49Zoai:ri.conicet.gov.ar:11336/31756instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:58:50.042CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Lithium extraction from β-spodumene through chlorination with chlorine gas |
title |
Lithium extraction from β-spodumene through chlorination with chlorine gas |
spellingShingle |
Lithium extraction from β-spodumene through chlorination with chlorine gas Barbosa, Lucía Isabel Lithium Extraction Chlorination Chlorine Gas |
title_short |
Lithium extraction from β-spodumene through chlorination with chlorine gas |
title_full |
Lithium extraction from β-spodumene through chlorination with chlorine gas |
title_fullStr |
Lithium extraction from β-spodumene through chlorination with chlorine gas |
title_full_unstemmed |
Lithium extraction from β-spodumene through chlorination with chlorine gas |
title_sort |
Lithium extraction from β-spodumene through chlorination with chlorine gas |
dc.creator.none.fl_str_mv |
Barbosa, Lucía Isabel Valente, Norma Graciela Orozco, R. P. Gonzalez, Jorge Alberto |
author |
Barbosa, Lucía Isabel |
author_facet |
Barbosa, Lucía Isabel Valente, Norma Graciela Orozco, R. P. Gonzalez, Jorge Alberto |
author_role |
author |
author2 |
Valente, Norma Graciela Orozco, R. P. Gonzalez, Jorge Alberto |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Lithium Extraction Chlorination Chlorine Gas |
topic |
Lithium Extraction Chlorination Chlorine Gas |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The extraction of lithium by means of the chlorination roasting of b-spodumene has been studied in the temperature range from 1000 to 1100 C for periods of time from 0 to 180 min. The roasting was carried out in a fixed bed reactor using pure gaseous Cl2 as chlorinating agent. The reactants and products were characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), atomic absorption spectrometry (AAS), scanning electron microscopy (SEM) and electron probe microanalysis (EPMA). The roasting of b-spodumene with pure Cl2 at 1100 C for the period of 150 min led to quantitative extraction of lithium as lithium chloride. The solid products of the reaction of b-spodumene with Cl2 were found to be Al6Si2-O13 (mullite), and Si2O (cristobalite). Fil: Barbosa, Lucía Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina Fil: Valente, Norma Graciela. Universidad Nacional de Cuyo; Argentina Fil: Orozco, R. P.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina Fil: Gonzalez, Jorge Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina |
description |
The extraction of lithium by means of the chlorination roasting of b-spodumene has been studied in the temperature range from 1000 to 1100 C for periods of time from 0 to 180 min. The roasting was carried out in a fixed bed reactor using pure gaseous Cl2 as chlorinating agent. The reactants and products were characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), atomic absorption spectrometry (AAS), scanning electron microscopy (SEM) and electron probe microanalysis (EPMA). The roasting of b-spodumene with pure Cl2 at 1100 C for the period of 150 min led to quantitative extraction of lithium as lithium chloride. The solid products of the reaction of b-spodumene with Cl2 were found to be Al6Si2-O13 (mullite), and Si2O (cristobalite). |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-02 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/31756 Barbosa, Lucía Isabel; Valente, Norma Graciela; Orozco, R. P.; Gonzalez, Jorge Alberto; Lithium extraction from β-spodumene through chlorination with chlorine gas; Elsevier; Minerals Engineering; 56; 2-2014; 29-34 0892-6875 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/31756 |
identifier_str_mv |
Barbosa, Lucía Isabel; Valente, Norma Graciela; Orozco, R. P.; Gonzalez, Jorge Alberto; Lithium extraction from β-spodumene through chlorination with chlorine gas; Elsevier; Minerals Engineering; 56; 2-2014; 29-34 0892-6875 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0892687513003506 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.mineng.2013.10.026 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842269544840691712 |
score |
13.13397 |