Marine emissions of methanethiol increase aerosol cooling in the Southern Ocean

Autores
Wohl, Charel; Villamayor, Julián; Galí, Martí; Mahajan, Anoop S.; Fernandez, Rafael Pedro; Cuevas, Carlos A.; Bossolasco, Adriana Gabriela; Li, Qinyi; Kettle, Anthony J.; Williams, Tara; Sarda Esteve, Roland; Gros, Valérie; Simó, Rafel; Saiz López, Alfonso
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Ocean-emitted dimethyl sulfide (DMS) is a major source of climate-cooling aerosols. However, most of the marine biogenic sulfur cycling is not routed to DMS but to methanethiol (MeSH), another volatile whose reactivity has hitherto hampered measurements. Therefore, the global emissions and climate impact of MeSH remain unexplored. We compiled a database of seawater MeSH concentrations, identified their statistical predictors, and produced monthly fields of global marine MeSH emissions adding to DMS emissions. Implemented into a global chemistry-climate model, MeSH emissions increase the sulfate aerosol burden by 30 to 70% over the Southern Ocean and enhance the aerosol cooling effect while depleting atmospheric oxidants and increasing DMS lifetime and transport. Accounting for MeSH emissions reduces the radiative bias of current climate models in this climatically relevant region. Methanethiol is a significant contributor to global ocean sulfur emissions and to sulfate aerosol cooling over the Southern Ocean.
Fil: Wohl, Charel. Consejo Superior de Investigaciones Científicas. Instituto de Ciencias del Mar; España. University of East Anglia; Reino Unido
Fil: Villamayor, Julián. Consejo Superior de Investigaciones Científicas; España. Instituto de Química Física Blas Cabrera; Argentina
Fil: Galí, Martí. Consejo Superior de Investigaciones Científicas. Instituto de Ciencias del Mar; España
Fil: Mahajan, Anoop S.. Ministry of Earth Sciences. Indian Institute of Tropical Meteorology. Centre for Climate Change Research; India
Fil: Fernandez, Rafael Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina
Fil: Cuevas, Carlos A.. Consejo Superior de Investigaciones Científicas; España. Instituto de Química Física Blas Cabrera; Argentina
Fil: Bossolasco, Adriana Gabriela. Universidad Nacional de Tucumán. Instituto de Física del Noroeste Argentino. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet Noa Sur. Instituto de Física del Noroeste Argentino; Argentina. Consejo Superior de Investigaciones Científicas; España. Instituto de Química Física Blas Cabrera; Argentina
Fil: Li, Qinyi. Shandong University; China
Fil: Kettle, Anthony J.. Météo France; Francia
Fil: Williams, Tara. Old Dominion University; Estados Unidos
Fil: Sarda Esteve, Roland. Aboratoire Des Sciences Du Climat Et de Lenvironnement; Francia
Fil: Gros, Valérie. Laboratoire Des Sciences Du Climat Et de Lenvironnen; Francia
Fil: Simó, Rafel. Consejo Superior de Investigaciones Científicas. Instituto de Ciencias del Mar; España
Fil: Saiz López, Alfonso. Consejo Superior de Investigaciones Científicas; España. Instituto de Química Física Blas Cabrera; Argentina
Materia
Methanethiol
CESM modeling
Aerosols
Southern Ocean
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/257158
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/257158
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Marine emissions of methanethiol increase aerosol cooling in the Southern OceanWohl, CharelVillamayor, JuliánGalí, MartíMahajan, Anoop S.Fernandez, Rafael PedroCuevas, Carlos A.Bossolasco, Adriana GabrielaLi, QinyiKettle, Anthony J.Williams, TaraSarda Esteve, RolandGros, ValérieSimó, RafelSaiz López, AlfonsoMethanethiolCESM modelingAerosolsSouthern Oceanhttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1Ocean-emitted dimethyl sulfide (DMS) is a major source of climate-cooling aerosols. However, most of the marine biogenic sulfur cycling is not routed to DMS but to methanethiol (MeSH), another volatile whose reactivity has hitherto hampered measurements. Therefore, the global emissions and climate impact of MeSH remain unexplored. We compiled a database of seawater MeSH concentrations, identified their statistical predictors, and produced monthly fields of global marine MeSH emissions adding to DMS emissions. Implemented into a global chemistry-climate model, MeSH emissions increase the sulfate aerosol burden by 30 to 70% over the Southern Ocean and enhance the aerosol cooling effect while depleting atmospheric oxidants and increasing DMS lifetime and transport. Accounting for MeSH emissions reduces the radiative bias of current climate models in this climatically relevant region. Methanethiol is a significant contributor to global ocean sulfur emissions and to sulfate aerosol cooling over the Southern Ocean.Fil: Wohl, Charel. Consejo Superior de Investigaciones Científicas. Instituto de Ciencias del Mar; España. University of East Anglia; Reino UnidoFil: Villamayor, Julián. Consejo Superior de Investigaciones Científicas; España. Instituto de Química Física Blas Cabrera; ArgentinaFil: Galí, Martí. Consejo Superior de Investigaciones Científicas. Instituto de Ciencias del Mar; EspañaFil: Mahajan, Anoop S.. Ministry of Earth Sciences. Indian Institute of Tropical Meteorology. Centre for Climate Change Research; IndiaFil: Fernandez, Rafael Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; ArgentinaFil: Cuevas, Carlos A.. Consejo Superior de Investigaciones Científicas; España. Instituto de Química Física Blas Cabrera; ArgentinaFil: Bossolasco, Adriana Gabriela. Universidad Nacional de Tucumán. Instituto de Física del Noroeste Argentino. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet Noa Sur. Instituto de Física del Noroeste Argentino; Argentina. Consejo Superior de Investigaciones Científicas; España. Instituto de Química Física Blas Cabrera; ArgentinaFil: Li, Qinyi. Shandong University; ChinaFil: Kettle, Anthony J.. Météo France; FranciaFil: Williams, Tara. Old Dominion University; Estados UnidosFil: Sarda Esteve, Roland. Aboratoire Des Sciences Du Climat Et de Lenvironnement; FranciaFil: Gros, Valérie. Laboratoire Des Sciences Du Climat Et de Lenvironnen; FranciaFil: Simó, Rafel. Consejo Superior de Investigaciones Científicas. Instituto de Ciencias del Mar; EspañaFil: Saiz López, Alfonso. Consejo Superior de Investigaciones Científicas; España. Instituto de Química Física Blas Cabrera; ArgentinaScience Advances is the American Association for the Advancement of Science2024-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/257158Wohl, Charel; Villamayor, Julián; Galí, Martí; Mahajan, Anoop S.; Fernandez, Rafael Pedro; et al.; Marine emissions of methanethiol increase aerosol cooling in the Southern Ocean; Science Advances is the American Association for the Advancement of Science; Science Advances; 10; 48; 11-2024; 1-92375-2548CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.science.org/doi/10.1126/sciadv.adq2465info:eu-repo/semantics/altIdentifier/doi/10.1126/sciadv.adq2465info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:55:36Zoai:ri.conicet.gov.ar:11336/257158instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:55:37.193CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Marine emissions of methanethiol increase aerosol cooling in the Southern Ocean
title Marine emissions of methanethiol increase aerosol cooling in the Southern Ocean
spellingShingle Marine emissions of methanethiol increase aerosol cooling in the Southern Ocean
Wohl, Charel
Methanethiol
CESM modeling
Aerosols
Southern Ocean
title_short Marine emissions of methanethiol increase aerosol cooling in the Southern Ocean
title_full Marine emissions of methanethiol increase aerosol cooling in the Southern Ocean
title_fullStr Marine emissions of methanethiol increase aerosol cooling in the Southern Ocean
title_full_unstemmed Marine emissions of methanethiol increase aerosol cooling in the Southern Ocean
title_sort Marine emissions of methanethiol increase aerosol cooling in the Southern Ocean
dc.creator.none.fl_str_mv Wohl, Charel
Villamayor, Julián
Galí, Martí
Mahajan, Anoop S.
Fernandez, Rafael Pedro
Cuevas, Carlos A.
Bossolasco, Adriana Gabriela
Li, Qinyi
Kettle, Anthony J.
Williams, Tara
Sarda Esteve, Roland
Gros, Valérie
Simó, Rafel
Saiz López, Alfonso
author Wohl, Charel
author_facet Wohl, Charel
Villamayor, Julián
Galí, Martí
Mahajan, Anoop S.
Fernandez, Rafael Pedro
Cuevas, Carlos A.
Bossolasco, Adriana Gabriela
Li, Qinyi
Kettle, Anthony J.
Williams, Tara
Sarda Esteve, Roland
Gros, Valérie
Simó, Rafel
Saiz López, Alfonso
author_role author
author2 Villamayor, Julián
Galí, Martí
Mahajan, Anoop S.
Fernandez, Rafael Pedro
Cuevas, Carlos A.
Bossolasco, Adriana Gabriela
Li, Qinyi
Kettle, Anthony J.
Williams, Tara
Sarda Esteve, Roland
Gros, Valérie
Simó, Rafel
Saiz López, Alfonso
author2_role author
author
author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Methanethiol
CESM modeling
Aerosols
Southern Ocean
topic Methanethiol
CESM modeling
Aerosols
Southern Ocean
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Ocean-emitted dimethyl sulfide (DMS) is a major source of climate-cooling aerosols. However, most of the marine biogenic sulfur cycling is not routed to DMS but to methanethiol (MeSH), another volatile whose reactivity has hitherto hampered measurements. Therefore, the global emissions and climate impact of MeSH remain unexplored. We compiled a database of seawater MeSH concentrations, identified their statistical predictors, and produced monthly fields of global marine MeSH emissions adding to DMS emissions. Implemented into a global chemistry-climate model, MeSH emissions increase the sulfate aerosol burden by 30 to 70% over the Southern Ocean and enhance the aerosol cooling effect while depleting atmospheric oxidants and increasing DMS lifetime and transport. Accounting for MeSH emissions reduces the radiative bias of current climate models in this climatically relevant region. Methanethiol is a significant contributor to global ocean sulfur emissions and to sulfate aerosol cooling over the Southern Ocean.
Fil: Wohl, Charel. Consejo Superior de Investigaciones Científicas. Instituto de Ciencias del Mar; España. University of East Anglia; Reino Unido
Fil: Villamayor, Julián. Consejo Superior de Investigaciones Científicas; España. Instituto de Química Física Blas Cabrera; Argentina
Fil: Galí, Martí. Consejo Superior de Investigaciones Científicas. Instituto de Ciencias del Mar; España
Fil: Mahajan, Anoop S.. Ministry of Earth Sciences. Indian Institute of Tropical Meteorology. Centre for Climate Change Research; India
Fil: Fernandez, Rafael Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina
Fil: Cuevas, Carlos A.. Consejo Superior de Investigaciones Científicas; España. Instituto de Química Física Blas Cabrera; Argentina
Fil: Bossolasco, Adriana Gabriela. Universidad Nacional de Tucumán. Instituto de Física del Noroeste Argentino. - Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet Noa Sur. Instituto de Física del Noroeste Argentino; Argentina. Consejo Superior de Investigaciones Científicas; España. Instituto de Química Física Blas Cabrera; Argentina
Fil: Li, Qinyi. Shandong University; China
Fil: Kettle, Anthony J.. Météo France; Francia
Fil: Williams, Tara. Old Dominion University; Estados Unidos
Fil: Sarda Esteve, Roland. Aboratoire Des Sciences Du Climat Et de Lenvironnement; Francia
Fil: Gros, Valérie. Laboratoire Des Sciences Du Climat Et de Lenvironnen; Francia
Fil: Simó, Rafel. Consejo Superior de Investigaciones Científicas. Instituto de Ciencias del Mar; España
Fil: Saiz López, Alfonso. Consejo Superior de Investigaciones Científicas; España. Instituto de Química Física Blas Cabrera; Argentina
description Ocean-emitted dimethyl sulfide (DMS) is a major source of climate-cooling aerosols. However, most of the marine biogenic sulfur cycling is not routed to DMS but to methanethiol (MeSH), another volatile whose reactivity has hitherto hampered measurements. Therefore, the global emissions and climate impact of MeSH remain unexplored. We compiled a database of seawater MeSH concentrations, identified their statistical predictors, and produced monthly fields of global marine MeSH emissions adding to DMS emissions. Implemented into a global chemistry-climate model, MeSH emissions increase the sulfate aerosol burden by 30 to 70% over the Southern Ocean and enhance the aerosol cooling effect while depleting atmospheric oxidants and increasing DMS lifetime and transport. Accounting for MeSH emissions reduces the radiative bias of current climate models in this climatically relevant region. Methanethiol is a significant contributor to global ocean sulfur emissions and to sulfate aerosol cooling over the Southern Ocean.
publishDate 2024
dc.date.none.fl_str_mv 2024-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/257158
Wohl, Charel; Villamayor, Julián; Galí, Martí; Mahajan, Anoop S.; Fernandez, Rafael Pedro; et al.; Marine emissions of methanethiol increase aerosol cooling in the Southern Ocean; Science Advances is the American Association for the Advancement of Science; Science Advances; 10; 48; 11-2024; 1-9
2375-2548
CONICET Digital
CONICET
url http://hdl.handle.net/11336/257158
identifier_str_mv Wohl, Charel; Villamayor, Julián; Galí, Martí; Mahajan, Anoop S.; Fernandez, Rafael Pedro; et al.; Marine emissions of methanethiol increase aerosol cooling in the Southern Ocean; Science Advances is the American Association for the Advancement of Science; Science Advances; 10; 48; 11-2024; 1-9
2375-2548
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.science.org/doi/10.1126/sciadv.adq2465
info:eu-repo/semantics/altIdentifier/doi/10.1126/sciadv.adq2465
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Science Advances is the American Association for the Advancement of Science
publisher.none.fl_str_mv Science Advances is the American Association for the Advancement of Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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