Interaction of magnetic nanoparticles with phospholipid films adsorbed at a liquid/liquid interface

Autores
Cámara, Candelaria Inés; Monzon, Lorena Maria Aranzazu; Coey, J.M.D.; Yudi, Lidia Mabel
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The interaction of Co hexagonal magnetic nanoparticles (MNPs) with distearoyl phosphatidyl glycerol(DSPG) and distearoyl phosphatidic acid (DSPA) films adsorbed at a water/1,2-dichloroethane interface isstudied employing cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), capacitycurves and interfacial pressure–area isotherms. DSPA and DSPG adsorb at the interface forming homo-genous films and producing a blocking effect on the transfer process of tetraethyl ammonium (TEA+),used as a probe cation. In the presence of Co NPs this effect is reversed and the reversible transferprocess for TEA+is reestablished, to a greater or lesser extent depending on the structuration of the film.Co–DSPA hybrid films have a homogeneous structure while Co-DSPG films present different domains.Moreover, the presence of Co on DSPA film modifies the partition coefficient of the organic electrolyteinto the hydrocarbon layer.
Fil: Cámara, Candelaria Inés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Monzon, Lorena Maria Aranzazu. Trinity College Dublin; Irlanda
Fil: Coey, J.M.D.. Trinity College Dublin; Irlanda
Fil: Yudi, Lidia Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
Cobalt
Magnetic Nanoparticles
Phospholipids Monolayers
Liquid/Liquid Interfaces
Ion Transfer
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31502
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/31502
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Interaction of magnetic nanoparticles with phospholipid films adsorbed at a liquid/liquid interfaceCámara, Candelaria InésMonzon, Lorena Maria AranzazuCoey, J.M.D.Yudi, Lidia MabelCobaltMagnetic NanoparticlesPhospholipids MonolayersLiquid/Liquid InterfacesIon Transferhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The interaction of Co hexagonal magnetic nanoparticles (MNPs) with distearoyl phosphatidyl glycerol(DSPG) and distearoyl phosphatidic acid (DSPA) films adsorbed at a water/1,2-dichloroethane interface isstudied employing cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), capacitycurves and interfacial pressure–area isotherms. DSPA and DSPG adsorb at the interface forming homo-genous films and producing a blocking effect on the transfer process of tetraethyl ammonium (TEA+),used as a probe cation. In the presence of Co NPs this effect is reversed and the reversible transferprocess for TEA+is reestablished, to a greater or lesser extent depending on the structuration of the film.Co–DSPA hybrid films have a homogeneous structure while Co-DSPG films present different domains.Moreover, the presence of Co on DSPA film modifies the partition coefficient of the organic electrolyteinto the hydrocarbon layer.Fil: Cámara, Candelaria Inés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Monzon, Lorena Maria Aranzazu. Trinity College Dublin; IrlandaFil: Coey, J.M.D.. Trinity College Dublin; IrlandaFil: Yudi, Lidia Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaRoyal Society of Chemistry2014-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31502Cámara, Candelaria Inés; Monzon, Lorena Maria Aranzazu; Coey, J.M.D.; Yudi, Lidia Mabel; Interaction of magnetic nanoparticles with phospholipid films adsorbed at a liquid/liquid interface; Royal Society of Chemistry; Physical Chemistry Chemical Physics; 17; 10-2014; 414-4211463-9076CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/C4CP04464Ainfo:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2015/CP/C4CP04464Ainfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:14:31Zoai:ri.conicet.gov.ar:11336/31502instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:14:31.743CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Interaction of magnetic nanoparticles with phospholipid films adsorbed at a liquid/liquid interface
title Interaction of magnetic nanoparticles with phospholipid films adsorbed at a liquid/liquid interface
spellingShingle Interaction of magnetic nanoparticles with phospholipid films adsorbed at a liquid/liquid interface
Cámara, Candelaria Inés
Cobalt
Magnetic Nanoparticles
Phospholipids Monolayers
Liquid/Liquid Interfaces
Ion Transfer
title_short Interaction of magnetic nanoparticles with phospholipid films adsorbed at a liquid/liquid interface
title_full Interaction of magnetic nanoparticles with phospholipid films adsorbed at a liquid/liquid interface
title_fullStr Interaction of magnetic nanoparticles with phospholipid films adsorbed at a liquid/liquid interface
title_full_unstemmed Interaction of magnetic nanoparticles with phospholipid films adsorbed at a liquid/liquid interface
title_sort Interaction of magnetic nanoparticles with phospholipid films adsorbed at a liquid/liquid interface
dc.creator.none.fl_str_mv Cámara, Candelaria Inés
Monzon, Lorena Maria Aranzazu
Coey, J.M.D.
Yudi, Lidia Mabel
author Cámara, Candelaria Inés
author_facet Cámara, Candelaria Inés
Monzon, Lorena Maria Aranzazu
Coey, J.M.D.
Yudi, Lidia Mabel
author_role author
author2 Monzon, Lorena Maria Aranzazu
Coey, J.M.D.
Yudi, Lidia Mabel
author2_role author
author
author
dc.subject.none.fl_str_mv Cobalt
Magnetic Nanoparticles
Phospholipids Monolayers
Liquid/Liquid Interfaces
Ion Transfer
topic Cobalt
Magnetic Nanoparticles
Phospholipids Monolayers
Liquid/Liquid Interfaces
Ion Transfer
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The interaction of Co hexagonal magnetic nanoparticles (MNPs) with distearoyl phosphatidyl glycerol(DSPG) and distearoyl phosphatidic acid (DSPA) films adsorbed at a water/1,2-dichloroethane interface isstudied employing cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), capacitycurves and interfacial pressure–area isotherms. DSPA and DSPG adsorb at the interface forming homo-genous films and producing a blocking effect on the transfer process of tetraethyl ammonium (TEA+),used as a probe cation. In the presence of Co NPs this effect is reversed and the reversible transferprocess for TEA+is reestablished, to a greater or lesser extent depending on the structuration of the film.Co–DSPA hybrid films have a homogeneous structure while Co-DSPG films present different domains.Moreover, the presence of Co on DSPA film modifies the partition coefficient of the organic electrolyteinto the hydrocarbon layer.
Fil: Cámara, Candelaria Inés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Monzon, Lorena Maria Aranzazu. Trinity College Dublin; Irlanda
Fil: Coey, J.M.D.. Trinity College Dublin; Irlanda
Fil: Yudi, Lidia Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description The interaction of Co hexagonal magnetic nanoparticles (MNPs) with distearoyl phosphatidyl glycerol(DSPG) and distearoyl phosphatidic acid (DSPA) films adsorbed at a water/1,2-dichloroethane interface isstudied employing cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), capacitycurves and interfacial pressure–area isotherms. DSPA and DSPG adsorb at the interface forming homo-genous films and producing a blocking effect on the transfer process of tetraethyl ammonium (TEA+),used as a probe cation. In the presence of Co NPs this effect is reversed and the reversible transferprocess for TEA+is reestablished, to a greater or lesser extent depending on the structuration of the film.Co–DSPA hybrid films have a homogeneous structure while Co-DSPG films present different domains.Moreover, the presence of Co on DSPA film modifies the partition coefficient of the organic electrolyteinto the hydrocarbon layer.
publishDate 2014
dc.date.none.fl_str_mv 2014-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31502
Cámara, Candelaria Inés; Monzon, Lorena Maria Aranzazu; Coey, J.M.D.; Yudi, Lidia Mabel; Interaction of magnetic nanoparticles with phospholipid films adsorbed at a liquid/liquid interface; Royal Society of Chemistry; Physical Chemistry Chemical Physics; 17; 10-2014; 414-421
1463-9076
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31502
identifier_str_mv Cámara, Candelaria Inés; Monzon, Lorena Maria Aranzazu; Coey, J.M.D.; Yudi, Lidia Mabel; Interaction of magnetic nanoparticles with phospholipid films adsorbed at a liquid/liquid interface; Royal Society of Chemistry; Physical Chemistry Chemical Physics; 17; 10-2014; 414-421
1463-9076
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1039/C4CP04464A
info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2015/CP/C4CP04464A
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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