Optimization and characterization of electroless co-deposited PdRu membranes: Effect of the plating variables on morphology

Autores
Braun, Fernando; Tarditi, Ana Maria; Cornaglia, Laura Maria
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
PdRu films were successfully synthesized on top of non-porous stainless steel supports by electroless co-deposition. The effect of synthesis variables on morphology, substrate adherence, bulk and surface composition was studied. The microstructure and morphology of the samples were analyzed by X-ray diffraction and scanning electron microscopy. Homogeneous and defect-free PdRu films were obtained employing baths at low pH, moderate to high agitation speeds, high concentration of hydrazine, using EDTA as a stabilizer and temperatures near 50°C. Films characterized by X-ray photoelectron spectroscopy showed Pd segregation after annealing the sample at 400°C in H2 (5%)/Ar in the load-lock chamber of the spectrometer. The optimized conditions were employed to synthesize a PdRu composite membrane on top of a tubular porous stainless steel substrate (0.1μm grade). Hydrogen permeation was measured over a 350-450°C temperature range and a trans-membrane pressure up to 100kPa. The PdRu membrane showed good performance with a hydrogen permeability of 6.5×10-9molm-1s-1Pa-0.5 and a selectivity higher than 1700.
Fil: Braun, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Tarditi, Ana Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
Co-Deposition
Electroless Plating
Pdru Membrane
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/52874
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Optimization and characterization of electroless co-deposited PdRu membranes: Effect of the plating variables on morphologyBraun, FernandoTarditi, Ana MariaCornaglia, Laura MariaCo-DepositionElectroless PlatingPdru Membranehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1PdRu films were successfully synthesized on top of non-porous stainless steel supports by electroless co-deposition. The effect of synthesis variables on morphology, substrate adherence, bulk and surface composition was studied. The microstructure and morphology of the samples were analyzed by X-ray diffraction and scanning electron microscopy. Homogeneous and defect-free PdRu films were obtained employing baths at low pH, moderate to high agitation speeds, high concentration of hydrazine, using EDTA as a stabilizer and temperatures near 50°C. Films characterized by X-ray photoelectron spectroscopy showed Pd segregation after annealing the sample at 400°C in H2 (5%)/Ar in the load-lock chamber of the spectrometer. The optimized conditions were employed to synthesize a PdRu composite membrane on top of a tubular porous stainless steel substrate (0.1μm grade). Hydrogen permeation was measured over a 350-450°C temperature range and a trans-membrane pressure up to 100kPa. The PdRu membrane showed good performance with a hydrogen permeability of 6.5×10-9molm-1s-1Pa-0.5 and a selectivity higher than 1700.Fil: Braun, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Tarditi, Ana Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2011-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/52874Braun, Fernando; Tarditi, Ana Maria; Cornaglia, Laura Maria; Optimization and characterization of electroless co-deposited PdRu membranes: Effect of the plating variables on morphology; Elsevier Science; Journal of Membrane Science; 382; 1-2; 10-2011; 252-2610376-7388CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.memsci.2011.08.019info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0376738811005965info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:36:05Zoai:ri.conicet.gov.ar:11336/52874instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:36:05.432CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Optimization and characterization of electroless co-deposited PdRu membranes: Effect of the plating variables on morphology
title Optimization and characterization of electroless co-deposited PdRu membranes: Effect of the plating variables on morphology
spellingShingle Optimization and characterization of electroless co-deposited PdRu membranes: Effect of the plating variables on morphology
Braun, Fernando
Co-Deposition
Electroless Plating
Pdru Membrane
title_short Optimization and characterization of electroless co-deposited PdRu membranes: Effect of the plating variables on morphology
title_full Optimization and characterization of electroless co-deposited PdRu membranes: Effect of the plating variables on morphology
title_fullStr Optimization and characterization of electroless co-deposited PdRu membranes: Effect of the plating variables on morphology
title_full_unstemmed Optimization and characterization of electroless co-deposited PdRu membranes: Effect of the plating variables on morphology
title_sort Optimization and characterization of electroless co-deposited PdRu membranes: Effect of the plating variables on morphology
dc.creator.none.fl_str_mv Braun, Fernando
Tarditi, Ana Maria
Cornaglia, Laura Maria
author Braun, Fernando
author_facet Braun, Fernando
Tarditi, Ana Maria
Cornaglia, Laura Maria
author_role author
author2 Tarditi, Ana Maria
Cornaglia, Laura Maria
author2_role author
author
dc.subject.none.fl_str_mv Co-Deposition
Electroless Plating
Pdru Membrane
topic Co-Deposition
Electroless Plating
Pdru Membrane
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv PdRu films were successfully synthesized on top of non-porous stainless steel supports by electroless co-deposition. The effect of synthesis variables on morphology, substrate adherence, bulk and surface composition was studied. The microstructure and morphology of the samples were analyzed by X-ray diffraction and scanning electron microscopy. Homogeneous and defect-free PdRu films were obtained employing baths at low pH, moderate to high agitation speeds, high concentration of hydrazine, using EDTA as a stabilizer and temperatures near 50°C. Films characterized by X-ray photoelectron spectroscopy showed Pd segregation after annealing the sample at 400°C in H2 (5%)/Ar in the load-lock chamber of the spectrometer. The optimized conditions were employed to synthesize a PdRu composite membrane on top of a tubular porous stainless steel substrate (0.1μm grade). Hydrogen permeation was measured over a 350-450°C temperature range and a trans-membrane pressure up to 100kPa. The PdRu membrane showed good performance with a hydrogen permeability of 6.5×10-9molm-1s-1Pa-0.5 and a selectivity higher than 1700.
Fil: Braun, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Tarditi, Ana Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description PdRu films were successfully synthesized on top of non-porous stainless steel supports by electroless co-deposition. The effect of synthesis variables on morphology, substrate adherence, bulk and surface composition was studied. The microstructure and morphology of the samples were analyzed by X-ray diffraction and scanning electron microscopy. Homogeneous and defect-free PdRu films were obtained employing baths at low pH, moderate to high agitation speeds, high concentration of hydrazine, using EDTA as a stabilizer and temperatures near 50°C. Films characterized by X-ray photoelectron spectroscopy showed Pd segregation after annealing the sample at 400°C in H2 (5%)/Ar in the load-lock chamber of the spectrometer. The optimized conditions were employed to synthesize a PdRu composite membrane on top of a tubular porous stainless steel substrate (0.1μm grade). Hydrogen permeation was measured over a 350-450°C temperature range and a trans-membrane pressure up to 100kPa. The PdRu membrane showed good performance with a hydrogen permeability of 6.5×10-9molm-1s-1Pa-0.5 and a selectivity higher than 1700.
publishDate 2011
dc.date.none.fl_str_mv 2011-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/52874
Braun, Fernando; Tarditi, Ana Maria; Cornaglia, Laura Maria; Optimization and characterization of electroless co-deposited PdRu membranes: Effect of the plating variables on morphology; Elsevier Science; Journal of Membrane Science; 382; 1-2; 10-2011; 252-261
0376-7388
CONICET Digital
CONICET
url http://hdl.handle.net/11336/52874
identifier_str_mv Braun, Fernando; Tarditi, Ana Maria; Cornaglia, Laura Maria; Optimization and characterization of electroless co-deposited PdRu membranes: Effect of the plating variables on morphology; Elsevier Science; Journal of Membrane Science; 382; 1-2; 10-2011; 252-261
0376-7388
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.memsci.2011.08.019
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0376738811005965
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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