Total Synthesis and Structural Elucidation of Cryptolatifolione
- Autores
- Novaes, Luiz F. T.; Sarotti, Ariel Marcelo; Pilli, Ronaldo A.
- Año de publicación
- 2015
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- An enantioselective total synthesis of Cryptolatifolione and its C-8 epimer is presented in a protecting-group-free fashion. The synthesis relied on the use of a catalytic double Krische allylation, catalytic olefin metathesis and a C-H oxidation. Comparison of spectroscopical data of the synthetic isomers and natural product made possible the unequivocally elucidation of the absolute configuration of Cryptolatifolione.
Fil: Novaes, Luiz F. T.. Universidade Estadual de Campinas; Brasil
Fil: Sarotti, Ariel Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina
Fil: Pilli, Ronaldo A.. Universidade Estadual de Campinas; Brasil - Materia
-
Total Synthesis
Cryptolatilfolione
Stereochemical Assignment - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/6046
Ver los metadatos del registro completo
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Total Synthesis and Structural Elucidation of CryptolatifolioneNovaes, Luiz F. T.Sarotti, Ariel MarceloPilli, Ronaldo A.Total SynthesisCryptolatilfolioneStereochemical Assignmenthttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1An enantioselective total synthesis of Cryptolatifolione and its C-8 epimer is presented in a protecting-group-free fashion. The synthesis relied on the use of a catalytic double Krische allylation, catalytic olefin metathesis and a C-H oxidation. Comparison of spectroscopical data of the synthetic isomers and natural product made possible the unequivocally elucidation of the absolute configuration of Cryptolatifolione.Fil: Novaes, Luiz F. T.. Universidade Estadual de Campinas; BrasilFil: Sarotti, Ariel Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; ArgentinaFil: Pilli, Ronaldo A.. Universidade Estadual de Campinas; BrasilRoyal Society of Chemistry2015-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/6046Novaes, Luiz F. T.; Sarotti, Ariel Marcelo; Pilli, Ronaldo A.; Total Synthesis and Structural Elucidation of Cryptolatifolione; Royal Society of Chemistry; RSC Advances; 5; 66; 6-2015; 53471-534762046-2069enginfo:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2015/RA/C5RA09186Ainfo:eu-repo/semantics/altIdentifier/doi/10.1039/C5RA09186Ainfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:22:03Zoai:ri.conicet.gov.ar:11336/6046instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:22:03.518CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Total Synthesis and Structural Elucidation of Cryptolatifolione |
title |
Total Synthesis and Structural Elucidation of Cryptolatifolione |
spellingShingle |
Total Synthesis and Structural Elucidation of Cryptolatifolione Novaes, Luiz F. T. Total Synthesis Cryptolatilfolione Stereochemical Assignment |
title_short |
Total Synthesis and Structural Elucidation of Cryptolatifolione |
title_full |
Total Synthesis and Structural Elucidation of Cryptolatifolione |
title_fullStr |
Total Synthesis and Structural Elucidation of Cryptolatifolione |
title_full_unstemmed |
Total Synthesis and Structural Elucidation of Cryptolatifolione |
title_sort |
Total Synthesis and Structural Elucidation of Cryptolatifolione |
dc.creator.none.fl_str_mv |
Novaes, Luiz F. T. Sarotti, Ariel Marcelo Pilli, Ronaldo A. |
author |
Novaes, Luiz F. T. |
author_facet |
Novaes, Luiz F. T. Sarotti, Ariel Marcelo Pilli, Ronaldo A. |
author_role |
author |
author2 |
Sarotti, Ariel Marcelo Pilli, Ronaldo A. |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Total Synthesis Cryptolatilfolione Stereochemical Assignment |
topic |
Total Synthesis Cryptolatilfolione Stereochemical Assignment |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
An enantioselective total synthesis of Cryptolatifolione and its C-8 epimer is presented in a protecting-group-free fashion. The synthesis relied on the use of a catalytic double Krische allylation, catalytic olefin metathesis and a C-H oxidation. Comparison of spectroscopical data of the synthetic isomers and natural product made possible the unequivocally elucidation of the absolute configuration of Cryptolatifolione. Fil: Novaes, Luiz F. T.. Universidade Estadual de Campinas; Brasil Fil: Sarotti, Ariel Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Rosario. Instituto de Química Rosario; Argentina Fil: Pilli, Ronaldo A.. Universidade Estadual de Campinas; Brasil |
description |
An enantioselective total synthesis of Cryptolatifolione and its C-8 epimer is presented in a protecting-group-free fashion. The synthesis relied on the use of a catalytic double Krische allylation, catalytic olefin metathesis and a C-H oxidation. Comparison of spectroscopical data of the synthetic isomers and natural product made possible the unequivocally elucidation of the absolute configuration of Cryptolatifolione. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-06 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/6046 Novaes, Luiz F. T.; Sarotti, Ariel Marcelo; Pilli, Ronaldo A.; Total Synthesis and Structural Elucidation of Cryptolatifolione; Royal Society of Chemistry; RSC Advances; 5; 66; 6-2015; 53471-53476 2046-2069 |
url |
http://hdl.handle.net/11336/6046 |
identifier_str_mv |
Novaes, Luiz F. T.; Sarotti, Ariel Marcelo; Pilli, Ronaldo A.; Total Synthesis and Structural Elucidation of Cryptolatifolione; Royal Society of Chemistry; RSC Advances; 5; 66; 6-2015; 53471-53476 2046-2069 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2015/RA/C5RA09186A info:eu-repo/semantics/altIdentifier/doi/10.1039/C5RA09186A |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Royal Society of Chemistry |
publisher.none.fl_str_mv |
Royal Society of Chemistry |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844614211266674688 |
score |
13.070432 |