Transmittance correlation of porous silicon multilayers used as a chemical sensor platform

Autores
Osorio, Edith; Urteaga, Raul; Juarez, H.; Koropecki, Roberto Roman
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This work presents a system of two optical microcavities made of mesoporous silicon that have been ana-lyzed as a platform for either chemical sensing or biosensing. When a porous microcavity is exposed toan analyte, the effective refractive index of its layers change, and its optical transmittance shifts towardslower wavenumbers. We constructed a device that employs two identical porous silicon microcavities,one of them is allowed to be in contact with the analyte, whereas the other remains unexposed. The trans-mitted intensity of the system results in the integrated product of the transmittances of both multilayers,which can be approximated to the autocorrelation function of the transmittance of the microcavity. Itsvalue depends on the analyte concentration, so it can be used for sensing purposes. This results in a sensorthat requires neither a wavelength-sensitive detector nor a monochromatic source of illumination, andis robust to changes in temperature, because it only depends on the relative changes in the microcavities.The sensor?s response can be optimized by modifying the angular position of the second microcavity. Asensor based on this principle is demonstrated for isopropyl alcohol detection. The minimum concentra-tion change that can be measured is about 30 ppm, which is equivalent to a minimum measurable changeof refractive index of 5 × 10−5
Fil: Osorio, Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; Argentina
Fil: Urteaga, Raul. Universidad Nacional del Litoral. Facultad de Ingeniería y Ciencias Hídricas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; Argentina
Fil: Juarez, H.. Benemérita Universidad Autónoma de Puebla; México
Fil: Koropecki, Roberto Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; Argentina
Materia
Porous Silicon
Correlation Transmittance
Chemical Sensors
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/30550

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spelling Transmittance correlation of porous silicon multilayers used as a chemical sensor platformOsorio, EdithUrteaga, RaulJuarez, H.Koropecki, Roberto RomanPorous SiliconCorrelation TransmittanceChemical Sensorshttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1This work presents a system of two optical microcavities made of mesoporous silicon that have been ana-lyzed as a platform for either chemical sensing or biosensing. When a porous microcavity is exposed toan analyte, the effective refractive index of its layers change, and its optical transmittance shifts towardslower wavenumbers. We constructed a device that employs two identical porous silicon microcavities,one of them is allowed to be in contact with the analyte, whereas the other remains unexposed. The trans-mitted intensity of the system results in the integrated product of the transmittances of both multilayers,which can be approximated to the autocorrelation function of the transmittance of the microcavity. Itsvalue depends on the analyte concentration, so it can be used for sensing purposes. This results in a sensorthat requires neither a wavelength-sensitive detector nor a monochromatic source of illumination, andis robust to changes in temperature, because it only depends on the relative changes in the microcavities.The sensor?s response can be optimized by modifying the angular position of the second microcavity. Asensor based on this principle is demonstrated for isopropyl alcohol detection. The minimum concentra-tion change that can be measured is about 30 ppm, which is equivalent to a minimum measurable changeof refractive index of 5 × 10−5Fil: Osorio, Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; ArgentinaFil: Urteaga, Raul. Universidad Nacional del Litoral. Facultad de Ingeniería y Ciencias Hídricas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; ArgentinaFil: Juarez, H.. Benemérita Universidad Autónoma de Puebla; MéxicoFil: Koropecki, Roberto Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; ArgentinaElsevier2015-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/30550Osorio, Edith; Urteaga, Raul; Juarez, H.; Koropecki, Roberto Roman; Transmittance correlation of porous silicon multilayers used as a chemical sensor platform; Elsevier; Sensors and Actuators B: Chemical; 213; 2-2015; 164-1700925-4005CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.snb.2015.02.058info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0925400515002312info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:20:22Zoai:ri.conicet.gov.ar:11336/30550instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:20:23.239CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Transmittance correlation of porous silicon multilayers used as a chemical sensor platform
title Transmittance correlation of porous silicon multilayers used as a chemical sensor platform
spellingShingle Transmittance correlation of porous silicon multilayers used as a chemical sensor platform
Osorio, Edith
Porous Silicon
Correlation Transmittance
Chemical Sensors
title_short Transmittance correlation of porous silicon multilayers used as a chemical sensor platform
title_full Transmittance correlation of porous silicon multilayers used as a chemical sensor platform
title_fullStr Transmittance correlation of porous silicon multilayers used as a chemical sensor platform
title_full_unstemmed Transmittance correlation of porous silicon multilayers used as a chemical sensor platform
title_sort Transmittance correlation of porous silicon multilayers used as a chemical sensor platform
dc.creator.none.fl_str_mv Osorio, Edith
Urteaga, Raul
Juarez, H.
Koropecki, Roberto Roman
author Osorio, Edith
author_facet Osorio, Edith
Urteaga, Raul
Juarez, H.
Koropecki, Roberto Roman
author_role author
author2 Urteaga, Raul
Juarez, H.
Koropecki, Roberto Roman
author2_role author
author
author
dc.subject.none.fl_str_mv Porous Silicon
Correlation Transmittance
Chemical Sensors
topic Porous Silicon
Correlation Transmittance
Chemical Sensors
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv This work presents a system of two optical microcavities made of mesoporous silicon that have been ana-lyzed as a platform for either chemical sensing or biosensing. When a porous microcavity is exposed toan analyte, the effective refractive index of its layers change, and its optical transmittance shifts towardslower wavenumbers. We constructed a device that employs two identical porous silicon microcavities,one of them is allowed to be in contact with the analyte, whereas the other remains unexposed. The trans-mitted intensity of the system results in the integrated product of the transmittances of both multilayers,which can be approximated to the autocorrelation function of the transmittance of the microcavity. Itsvalue depends on the analyte concentration, so it can be used for sensing purposes. This results in a sensorthat requires neither a wavelength-sensitive detector nor a monochromatic source of illumination, andis robust to changes in temperature, because it only depends on the relative changes in the microcavities.The sensor?s response can be optimized by modifying the angular position of the second microcavity. Asensor based on this principle is demonstrated for isopropyl alcohol detection. The minimum concentra-tion change that can be measured is about 30 ppm, which is equivalent to a minimum measurable changeof refractive index of 5 × 10−5
Fil: Osorio, Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; Argentina
Fil: Urteaga, Raul. Universidad Nacional del Litoral. Facultad de Ingeniería y Ciencias Hídricas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; Argentina
Fil: Juarez, H.. Benemérita Universidad Autónoma de Puebla; México
Fil: Koropecki, Roberto Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; Argentina
description This work presents a system of two optical microcavities made of mesoporous silicon that have been ana-lyzed as a platform for either chemical sensing or biosensing. When a porous microcavity is exposed toan analyte, the effective refractive index of its layers change, and its optical transmittance shifts towardslower wavenumbers. We constructed a device that employs two identical porous silicon microcavities,one of them is allowed to be in contact with the analyte, whereas the other remains unexposed. The trans-mitted intensity of the system results in the integrated product of the transmittances of both multilayers,which can be approximated to the autocorrelation function of the transmittance of the microcavity. Itsvalue depends on the analyte concentration, so it can be used for sensing purposes. This results in a sensorthat requires neither a wavelength-sensitive detector nor a monochromatic source of illumination, andis robust to changes in temperature, because it only depends on the relative changes in the microcavities.The sensor?s response can be optimized by modifying the angular position of the second microcavity. Asensor based on this principle is demonstrated for isopropyl alcohol detection. The minimum concentra-tion change that can be measured is about 30 ppm, which is equivalent to a minimum measurable changeof refractive index of 5 × 10−5
publishDate 2015
dc.date.none.fl_str_mv 2015-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/30550
Osorio, Edith; Urteaga, Raul; Juarez, H.; Koropecki, Roberto Roman; Transmittance correlation of porous silicon multilayers used as a chemical sensor platform; Elsevier; Sensors and Actuators B: Chemical; 213; 2-2015; 164-170
0925-4005
CONICET Digital
CONICET
url http://hdl.handle.net/11336/30550
identifier_str_mv Osorio, Edith; Urteaga, Raul; Juarez, H.; Koropecki, Roberto Roman; Transmittance correlation of porous silicon multilayers used as a chemical sensor platform; Elsevier; Sensors and Actuators B: Chemical; 213; 2-2015; 164-170
0925-4005
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.snb.2015.02.058
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0925400515002312
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
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instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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