A Model System for the Thermodynamic Analysis of Reaction‐Induced Phase Separation: Solutions of Polystyrene in Bifunctional Epoxy/Amine Monomers
- Autores
- Zucchi, Ileana Alicia; Galante, Maria Jose; Borrajo Fernandez, Julio; Williams, Roberto Juan Jose
- Año de publicación
- 2004
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- A model system, consisting of a linear polymer dissolved in a bifunctional monomer/co‐monomer solvent, was selected to test the applicability of the Flory‐Huggins (FH) theory in the absence of the usual assumptions present in the analysis of modified thermosetting polymers. Solutions of two almost monodisperse polystyrenes (PS, equation image = 83 000 or 217 000), in diglycidyl ether of bisphenol A (DGEBA) and in stoichiometric DGEBA/BA (benzylamine) solutions, exhibited an upper critical solution temperature (UCST) behavior. Cloud‐point curves (CPC) were fitted with the FH model using an interaction parameter depending on both temperature and concentration, χ = (a + b/T)/(1 − cϕ2), where ϕ2 represents the volume fraction of PS. A group‐contribution method provided a reasonable explanation of the observed trends. Cloud‐point times in the course of the DGEBA/BA stepwise polymerization, carried out at 70 °C and 80 °C, were determined for solutions containing 2.5 to 15 wt.‐% PS (equation image = 83 000). Times were transformed to conversions using kinetic curves determined by Fourier Transform Infrared Spectroscopy (FT‐IR) and Size Exclusion Chromatography (SEC). The analysis of cloud‐point conversions with the FH model was performed considering the (ideal) distribution of epoxy/amine species generated as a function of conversion. An empirical fitting of cloud‐point curves was possible with the use of an interaction parameter decreasing with conversion. Possibilities of improving the thermodynamic description of a polymerization‐induced phase separation are discussed.
Fil: Zucchi, Ileana Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Galante, Maria Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Borrajo Fernandez, Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina - Materia
-
BLENDS
PHASE SEPARATION
POLYSTYRENE
STEP-GROWTH POLYMERIZATION
THERMODYNAMICS - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/94730
Ver los metadatos del registro completo
id |
CONICETDig_099cd5becae6df04259440df69b6fff9 |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/94730 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
A Model System for the Thermodynamic Analysis of Reaction‐Induced Phase Separation: Solutions of Polystyrene in Bifunctional Epoxy/Amine MonomersZucchi, Ileana AliciaGalante, Maria JoseBorrajo Fernandez, JulioWilliams, Roberto Juan JoseBLENDSPHASE SEPARATIONPOLYSTYRENESTEP-GROWTH POLYMERIZATIONTHERMODYNAMICShttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2A model system, consisting of a linear polymer dissolved in a bifunctional monomer/co‐monomer solvent, was selected to test the applicability of the Flory‐Huggins (FH) theory in the absence of the usual assumptions present in the analysis of modified thermosetting polymers. Solutions of two almost monodisperse polystyrenes (PS, equation image = 83 000 or 217 000), in diglycidyl ether of bisphenol A (DGEBA) and in stoichiometric DGEBA/BA (benzylamine) solutions, exhibited an upper critical solution temperature (UCST) behavior. Cloud‐point curves (CPC) were fitted with the FH model using an interaction parameter depending on both temperature and concentration, χ = (a + b/T)/(1 − cϕ2), where ϕ2 represents the volume fraction of PS. A group‐contribution method provided a reasonable explanation of the observed trends. Cloud‐point times in the course of the DGEBA/BA stepwise polymerization, carried out at 70 °C and 80 °C, were determined for solutions containing 2.5 to 15 wt.‐% PS (equation image = 83 000). Times were transformed to conversions using kinetic curves determined by Fourier Transform Infrared Spectroscopy (FT‐IR) and Size Exclusion Chromatography (SEC). The analysis of cloud‐point conversions with the FH model was performed considering the (ideal) distribution of epoxy/amine species generated as a function of conversion. An empirical fitting of cloud‐point curves was possible with the use of an interaction parameter decreasing with conversion. Possibilities of improving the thermodynamic description of a polymerization‐induced phase separation are discussed.Fil: Zucchi, Ileana Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Galante, Maria Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Borrajo Fernandez, Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaWiley VCH Verlag2004-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/94730Zucchi, Ileana Alicia; Galante, Maria Jose; Borrajo Fernandez, Julio; Williams, Roberto Juan Jose; A Model System for the Thermodynamic Analysis of Reaction‐Induced Phase Separation: Solutions of Polystyrene in Bifunctional Epoxy/Amine Monomers; Wiley VCH Verlag; Macromolecular Chemistry And Physics; 205; 5; 3-2004; 676-6831022-1352CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/macp.200300106info:eu-repo/semantics/altIdentifier/doi/10.1002/macp.200300106info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:09:36Zoai:ri.conicet.gov.ar:11336/94730instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:09:36.338CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
A Model System for the Thermodynamic Analysis of Reaction‐Induced Phase Separation: Solutions of Polystyrene in Bifunctional Epoxy/Amine Monomers |
title |
A Model System for the Thermodynamic Analysis of Reaction‐Induced Phase Separation: Solutions of Polystyrene in Bifunctional Epoxy/Amine Monomers |
spellingShingle |
A Model System for the Thermodynamic Analysis of Reaction‐Induced Phase Separation: Solutions of Polystyrene in Bifunctional Epoxy/Amine Monomers Zucchi, Ileana Alicia BLENDS PHASE SEPARATION POLYSTYRENE STEP-GROWTH POLYMERIZATION THERMODYNAMICS |
title_short |
A Model System for the Thermodynamic Analysis of Reaction‐Induced Phase Separation: Solutions of Polystyrene in Bifunctional Epoxy/Amine Monomers |
title_full |
A Model System for the Thermodynamic Analysis of Reaction‐Induced Phase Separation: Solutions of Polystyrene in Bifunctional Epoxy/Amine Monomers |
title_fullStr |
A Model System for the Thermodynamic Analysis of Reaction‐Induced Phase Separation: Solutions of Polystyrene in Bifunctional Epoxy/Amine Monomers |
title_full_unstemmed |
A Model System for the Thermodynamic Analysis of Reaction‐Induced Phase Separation: Solutions of Polystyrene in Bifunctional Epoxy/Amine Monomers |
title_sort |
A Model System for the Thermodynamic Analysis of Reaction‐Induced Phase Separation: Solutions of Polystyrene in Bifunctional Epoxy/Amine Monomers |
dc.creator.none.fl_str_mv |
Zucchi, Ileana Alicia Galante, Maria Jose Borrajo Fernandez, Julio Williams, Roberto Juan Jose |
author |
Zucchi, Ileana Alicia |
author_facet |
Zucchi, Ileana Alicia Galante, Maria Jose Borrajo Fernandez, Julio Williams, Roberto Juan Jose |
author_role |
author |
author2 |
Galante, Maria Jose Borrajo Fernandez, Julio Williams, Roberto Juan Jose |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
BLENDS PHASE SEPARATION POLYSTYRENE STEP-GROWTH POLYMERIZATION THERMODYNAMICS |
topic |
BLENDS PHASE SEPARATION POLYSTYRENE STEP-GROWTH POLYMERIZATION THERMODYNAMICS |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
A model system, consisting of a linear polymer dissolved in a bifunctional monomer/co‐monomer solvent, was selected to test the applicability of the Flory‐Huggins (FH) theory in the absence of the usual assumptions present in the analysis of modified thermosetting polymers. Solutions of two almost monodisperse polystyrenes (PS, equation image = 83 000 or 217 000), in diglycidyl ether of bisphenol A (DGEBA) and in stoichiometric DGEBA/BA (benzylamine) solutions, exhibited an upper critical solution temperature (UCST) behavior. Cloud‐point curves (CPC) were fitted with the FH model using an interaction parameter depending on both temperature and concentration, χ = (a + b/T)/(1 − cϕ2), where ϕ2 represents the volume fraction of PS. A group‐contribution method provided a reasonable explanation of the observed trends. Cloud‐point times in the course of the DGEBA/BA stepwise polymerization, carried out at 70 °C and 80 °C, were determined for solutions containing 2.5 to 15 wt.‐% PS (equation image = 83 000). Times were transformed to conversions using kinetic curves determined by Fourier Transform Infrared Spectroscopy (FT‐IR) and Size Exclusion Chromatography (SEC). The analysis of cloud‐point conversions with the FH model was performed considering the (ideal) distribution of epoxy/amine species generated as a function of conversion. An empirical fitting of cloud‐point curves was possible with the use of an interaction parameter decreasing with conversion. Possibilities of improving the thermodynamic description of a polymerization‐induced phase separation are discussed. Fil: Zucchi, Ileana Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Galante, Maria Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Borrajo Fernandez, Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina |
description |
A model system, consisting of a linear polymer dissolved in a bifunctional monomer/co‐monomer solvent, was selected to test the applicability of the Flory‐Huggins (FH) theory in the absence of the usual assumptions present in the analysis of modified thermosetting polymers. Solutions of two almost monodisperse polystyrenes (PS, equation image = 83 000 or 217 000), in diglycidyl ether of bisphenol A (DGEBA) and in stoichiometric DGEBA/BA (benzylamine) solutions, exhibited an upper critical solution temperature (UCST) behavior. Cloud‐point curves (CPC) were fitted with the FH model using an interaction parameter depending on both temperature and concentration, χ = (a + b/T)/(1 − cϕ2), where ϕ2 represents the volume fraction of PS. A group‐contribution method provided a reasonable explanation of the observed trends. Cloud‐point times in the course of the DGEBA/BA stepwise polymerization, carried out at 70 °C and 80 °C, were determined for solutions containing 2.5 to 15 wt.‐% PS (equation image = 83 000). Times were transformed to conversions using kinetic curves determined by Fourier Transform Infrared Spectroscopy (FT‐IR) and Size Exclusion Chromatography (SEC). The analysis of cloud‐point conversions with the FH model was performed considering the (ideal) distribution of epoxy/amine species generated as a function of conversion. An empirical fitting of cloud‐point curves was possible with the use of an interaction parameter decreasing with conversion. Possibilities of improving the thermodynamic description of a polymerization‐induced phase separation are discussed. |
publishDate |
2004 |
dc.date.none.fl_str_mv |
2004-03 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/94730 Zucchi, Ileana Alicia; Galante, Maria Jose; Borrajo Fernandez, Julio; Williams, Roberto Juan Jose; A Model System for the Thermodynamic Analysis of Reaction‐Induced Phase Separation: Solutions of Polystyrene in Bifunctional Epoxy/Amine Monomers; Wiley VCH Verlag; Macromolecular Chemistry And Physics; 205; 5; 3-2004; 676-683 1022-1352 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/94730 |
identifier_str_mv |
Zucchi, Ileana Alicia; Galante, Maria Jose; Borrajo Fernandez, Julio; Williams, Roberto Juan Jose; A Model System for the Thermodynamic Analysis of Reaction‐Induced Phase Separation: Solutions of Polystyrene in Bifunctional Epoxy/Amine Monomers; Wiley VCH Verlag; Macromolecular Chemistry And Physics; 205; 5; 3-2004; 676-683 1022-1352 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/macp.200300106 info:eu-repo/semantics/altIdentifier/doi/10.1002/macp.200300106 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Wiley VCH Verlag |
publisher.none.fl_str_mv |
Wiley VCH Verlag |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844613976419205120 |
score |
13.070432 |