Effect of hydrogen-to-methane concentration ratio on the phase equilibria of quaternary hydrate systems

Autores
Khan, M. Naveed; Rovetto, Laura Jorgelina; Peters, Cor J.; Sloan, E. Dendy; Sum, Amadeu K.; Koh, Carolyn A.
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Clathrate hydrates of hydrogen are of specific interest due to their potential ability to store molecular hydrogen. In particular, structure H (sH) hydrate has a higher theoretical storage capacity in comparison with the other two more common hydrate structures (sI and sII). This paper investigates the effect of hydrogen (H2) concentration on the phase equilibria of sH hydrate in a quaternary system of water, methane, hydrogen, and methylcyclohexane. Phase equilibria and cage occupancies of the quaternary system were predicted using the van der Waals and Platteeuw (vdWP) model for different hydrogen/methane ratios ranging from 0 to 7. Model predictions for the quaternary systems were found to be in good agreement with measured experimental data. It was evident from the thermodynamic equilibrium conditions of the quaternary system (MCH + H2O + CH4 + H2) that as the H2 concentration increases (H2:CH4 ratio increased from 0 to 7), higher pressures are required to produce sH hydrates at the same temperature. It was also found that the fractional cage occupancy of CH4 in the small and medium cages of sH hydrate increases with pressure.
Fil: Khan, M. Naveed. Petroleum Institute. Chemical Engineering Department; Emiratos Arabes Unidos. Colorado School of Mines. Chemical & Biological Department. Center for Hydrate Research; Estados Unidos
Fil: Rovetto, Laura Jorgelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; Argentina
Fil: Peters, Cor J.. Petroleum Institute. Chemical Engineering Department; Emiratos Arabes Unidos
Fil: Sloan, E. Dendy. Colorado School of Mines. Chemical & Biological Department. Center for Hydrate Research; Estados Unidos
Fil: Sum, Amadeu K.. Colorado School of Mines. Chemical & Biological Department. Center for Hydrate Research; Estados Unidos
Fil: Koh, Carolyn A.. Colorado School of Mines. Chemical & Biological Department. Center for Hydrate Research; Estados Unidos
Materia
Gas Hydrate
Structure H
Hydrogen
Methane
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/37788
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Effect of hydrogen-to-methane concentration ratio on the phase equilibria of quaternary hydrate systemsKhan, M. NaveedRovetto, Laura JorgelinaPeters, Cor J.Sloan, E. DendySum, Amadeu K.Koh, Carolyn A.Gas HydrateStructure HHydrogenMethanehttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Clathrate hydrates of hydrogen are of specific interest due to their potential ability to store molecular hydrogen. In particular, structure H (sH) hydrate has a higher theoretical storage capacity in comparison with the other two more common hydrate structures (sI and sII). This paper investigates the effect of hydrogen (H2) concentration on the phase equilibria of sH hydrate in a quaternary system of water, methane, hydrogen, and methylcyclohexane. Phase equilibria and cage occupancies of the quaternary system were predicted using the van der Waals and Platteeuw (vdWP) model for different hydrogen/methane ratios ranging from 0 to 7. Model predictions for the quaternary systems were found to be in good agreement with measured experimental data. It was evident from the thermodynamic equilibrium conditions of the quaternary system (MCH + H2O + CH4 + H2) that as the H2 concentration increases (H2:CH4 ratio increased from 0 to 7), higher pressures are required to produce sH hydrates at the same temperature. It was also found that the fractional cage occupancy of CH4 in the small and medium cages of sH hydrate increases with pressure.Fil: Khan, M. Naveed. Petroleum Institute. Chemical Engineering Department; Emiratos Arabes Unidos. Colorado School of Mines. Chemical & Biological Department. Center for Hydrate Research; Estados UnidosFil: Rovetto, Laura Jorgelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; ArgentinaFil: Peters, Cor J.. Petroleum Institute. Chemical Engineering Department; Emiratos Arabes UnidosFil: Sloan, E. Dendy. Colorado School of Mines. Chemical & Biological Department. Center for Hydrate Research; Estados UnidosFil: Sum, Amadeu K.. Colorado School of Mines. Chemical & Biological Department. Center for Hydrate Research; Estados UnidosFil: Koh, Carolyn A.. Colorado School of Mines. Chemical & Biological Department. Center for Hydrate Research; Estados UnidosAmerican Chemical Society2015-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/37788Khan, M. Naveed; Rovetto, Laura Jorgelina; Peters, Cor J.; Sloan, E. Dendy; Sum, Amadeu K.; et al.; Effect of hydrogen-to-methane concentration ratio on the phase equilibria of quaternary hydrate systems; American Chemical Society; Journal of Chemical and Engineering Data; 60; 2; 2-2015; 418-4230021-9568CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/je500675qinfo:eu-repo/semantics/altIdentifier/doi/10.1021/je500675qinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:45:38Zoai:ri.conicet.gov.ar:11336/37788instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:45:40.47CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effect of hydrogen-to-methane concentration ratio on the phase equilibria of quaternary hydrate systems
title Effect of hydrogen-to-methane concentration ratio on the phase equilibria of quaternary hydrate systems
spellingShingle Effect of hydrogen-to-methane concentration ratio on the phase equilibria of quaternary hydrate systems
Khan, M. Naveed
Gas Hydrate
Structure H
Hydrogen
Methane
title_short Effect of hydrogen-to-methane concentration ratio on the phase equilibria of quaternary hydrate systems
title_full Effect of hydrogen-to-methane concentration ratio on the phase equilibria of quaternary hydrate systems
title_fullStr Effect of hydrogen-to-methane concentration ratio on the phase equilibria of quaternary hydrate systems
title_full_unstemmed Effect of hydrogen-to-methane concentration ratio on the phase equilibria of quaternary hydrate systems
title_sort Effect of hydrogen-to-methane concentration ratio on the phase equilibria of quaternary hydrate systems
dc.creator.none.fl_str_mv Khan, M. Naveed
Rovetto, Laura Jorgelina
Peters, Cor J.
Sloan, E. Dendy
Sum, Amadeu K.
Koh, Carolyn A.
author Khan, M. Naveed
author_facet Khan, M. Naveed
Rovetto, Laura Jorgelina
Peters, Cor J.
Sloan, E. Dendy
Sum, Amadeu K.
Koh, Carolyn A.
author_role author
author2 Rovetto, Laura Jorgelina
Peters, Cor J.
Sloan, E. Dendy
Sum, Amadeu K.
Koh, Carolyn A.
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Gas Hydrate
Structure H
Hydrogen
Methane
topic Gas Hydrate
Structure H
Hydrogen
Methane
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Clathrate hydrates of hydrogen are of specific interest due to their potential ability to store molecular hydrogen. In particular, structure H (sH) hydrate has a higher theoretical storage capacity in comparison with the other two more common hydrate structures (sI and sII). This paper investigates the effect of hydrogen (H2) concentration on the phase equilibria of sH hydrate in a quaternary system of water, methane, hydrogen, and methylcyclohexane. Phase equilibria and cage occupancies of the quaternary system were predicted using the van der Waals and Platteeuw (vdWP) model for different hydrogen/methane ratios ranging from 0 to 7. Model predictions for the quaternary systems were found to be in good agreement with measured experimental data. It was evident from the thermodynamic equilibrium conditions of the quaternary system (MCH + H2O + CH4 + H2) that as the H2 concentration increases (H2:CH4 ratio increased from 0 to 7), higher pressures are required to produce sH hydrates at the same temperature. It was also found that the fractional cage occupancy of CH4 in the small and medium cages of sH hydrate increases with pressure.
Fil: Khan, M. Naveed. Petroleum Institute. Chemical Engineering Department; Emiratos Arabes Unidos. Colorado School of Mines. Chemical & Biological Department. Center for Hydrate Research; Estados Unidos
Fil: Rovetto, Laura Jorgelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; Argentina
Fil: Peters, Cor J.. Petroleum Institute. Chemical Engineering Department; Emiratos Arabes Unidos
Fil: Sloan, E. Dendy. Colorado School of Mines. Chemical & Biological Department. Center for Hydrate Research; Estados Unidos
Fil: Sum, Amadeu K.. Colorado School of Mines. Chemical & Biological Department. Center for Hydrate Research; Estados Unidos
Fil: Koh, Carolyn A.. Colorado School of Mines. Chemical & Biological Department. Center for Hydrate Research; Estados Unidos
description Clathrate hydrates of hydrogen are of specific interest due to their potential ability to store molecular hydrogen. In particular, structure H (sH) hydrate has a higher theoretical storage capacity in comparison with the other two more common hydrate structures (sI and sII). This paper investigates the effect of hydrogen (H2) concentration on the phase equilibria of sH hydrate in a quaternary system of water, methane, hydrogen, and methylcyclohexane. Phase equilibria and cage occupancies of the quaternary system were predicted using the van der Waals and Platteeuw (vdWP) model for different hydrogen/methane ratios ranging from 0 to 7. Model predictions for the quaternary systems were found to be in good agreement with measured experimental data. It was evident from the thermodynamic equilibrium conditions of the quaternary system (MCH + H2O + CH4 + H2) that as the H2 concentration increases (H2:CH4 ratio increased from 0 to 7), higher pressures are required to produce sH hydrates at the same temperature. It was also found that the fractional cage occupancy of CH4 in the small and medium cages of sH hydrate increases with pressure.
publishDate 2015
dc.date.none.fl_str_mv 2015-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/37788
Khan, M. Naveed; Rovetto, Laura Jorgelina; Peters, Cor J.; Sloan, E. Dendy; Sum, Amadeu K.; et al.; Effect of hydrogen-to-methane concentration ratio on the phase equilibria of quaternary hydrate systems; American Chemical Society; Journal of Chemical and Engineering Data; 60; 2; 2-2015; 418-423
0021-9568
CONICET Digital
CONICET
url http://hdl.handle.net/11336/37788
identifier_str_mv Khan, M. Naveed; Rovetto, Laura Jorgelina; Peters, Cor J.; Sloan, E. Dendy; Sum, Amadeu K.; et al.; Effect of hydrogen-to-methane concentration ratio on the phase equilibria of quaternary hydrate systems; American Chemical Society; Journal of Chemical and Engineering Data; 60; 2; 2-2015; 418-423
0021-9568
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/je500675q
info:eu-repo/semantics/altIdentifier/doi/10.1021/je500675q
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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