An alternative approach for gas hydrates: application to phase equilibria with presence of single-guest clathrate hydrates
- Autores
- Molina, Matías José; Porras Giraldo, Andrés Felipe; Rodriguez Reartes, Sabrina Belen; Zabaloy, Marcelo Santiago
- Año de publicación
- 2023
- Idioma
- inglés
- Tipo de recurso
- documento de conferencia
- Estado
- versión publicada
- Descripción
- The goal of this work was to establish whether a recent approach proposed for representing the thermodynamic properties of solid solutions (Solid Solution Approach (SSA)) (Porras Giraldo, Rodriguez-Reartes and Zabaloy, 2021) would also be applicable to the case of clathrate hydrates over wide ranges of conditions. Clathrate hydrates (CHs) are nonstoichiometric ice-like solid materials (solid solutions) made of water (host) and another component (guest), such as methane. Actually, more than one guest may be present in the CH. The formation of CHs may be exploited in applications such as the fractionation of mixtures of gases. In contrast, the precipitation of CHs may cause plugging of pipelines in the oil and gas industry. Hence, knowledge of the conditions of CH formation is useful to promote or to avoid the CH precipitation. The van der Waals-Platteeuw model is the most widely used approach for evaluating the thermodynamic properties of CHs. This model is mathematically quite complex and it seems to be applicable only to solid solutions of the CH type. On the other hand, the SSA is mathematically much simpler, and has already been applied to solid solutions of varying nature (Porras Giraldo, Rodriguez-Reartes and Zabaloy, 2021), e.g., to those made of waxes.
Fil: Molina, Matías José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
Fil: Porras Giraldo, Andrés Felipe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
Fil: Rodriguez Reartes, Sabrina Belen. Departament D'enginyeria Química; España. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Zabaloy, Marcelo Santiago. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
11th World Congress of Chemical Engineering
Ciudad Autónoma de Buenos Aires
Argentina
Asociación Argentina de Ingenieros Químicos - Materia
-
SOLID SOLUTION
CLATHRATE HYDRATES
SOLID-FLUID EQUILIBRIUM
EQUATION OF SATE - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
.jpg)
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/244307
Ver los metadatos del registro completo
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An alternative approach for gas hydrates: application to phase equilibria with presence of single-guest clathrate hydratesMolina, Matías JoséPorras Giraldo, Andrés FelipeRodriguez Reartes, Sabrina BelenZabaloy, Marcelo SantiagoSOLID SOLUTIONCLATHRATE HYDRATESSOLID-FLUID EQUILIBRIUMEQUATION OF SATEhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The goal of this work was to establish whether a recent approach proposed for representing the thermodynamic properties of solid solutions (Solid Solution Approach (SSA)) (Porras Giraldo, Rodriguez-Reartes and Zabaloy, 2021) would also be applicable to the case of clathrate hydrates over wide ranges of conditions. Clathrate hydrates (CHs) are nonstoichiometric ice-like solid materials (solid solutions) made of water (host) and another component (guest), such as methane. Actually, more than one guest may be present in the CH. The formation of CHs may be exploited in applications such as the fractionation of mixtures of gases. In contrast, the precipitation of CHs may cause plugging of pipelines in the oil and gas industry. Hence, knowledge of the conditions of CH formation is useful to promote or to avoid the CH precipitation. The van der Waals-Platteeuw model is the most widely used approach for evaluating the thermodynamic properties of CHs. This model is mathematically quite complex and it seems to be applicable only to solid solutions of the CH type. On the other hand, the SSA is mathematically much simpler, and has already been applied to solid solutions of varying nature (Porras Giraldo, Rodriguez-Reartes and Zabaloy, 2021), e.g., to those made of waxes.Fil: Molina, Matías José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; ArgentinaFil: Porras Giraldo, Andrés Felipe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; ArgentinaFil: Rodriguez Reartes, Sabrina Belen. Departament D'enginyeria Química; España. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Zabaloy, Marcelo Santiago. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina11th World Congress of Chemical EngineeringCiudad Autónoma de Buenos AiresArgentinaAsociación Argentina de Ingenieros QuímicosAsociación Argentina de Ingenieros Químicos2023info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/conferenceObjectCongresoJournalhttp://purl.org/coar/resource_type/c_5794info:ar-repo/semantics/documentoDeConferenciaapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/244307An alternative approach for gas hydrates: application to phase equilibria with presence of single-guest clathrate hydrates; 11th World Congress of Chemical Engineering; Ciudad Autónoma de Buenos Aires; Argentina; 2023; 1-62953-5565CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.wcce11.org/wc/template/Proceedings-Abstracts_WCCE11.pdf?Internacionalinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:44:54Zoai:ri.conicet.gov.ar:11336/244307instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:44:54.809CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
| dc.title.none.fl_str_mv |
An alternative approach for gas hydrates: application to phase equilibria with presence of single-guest clathrate hydrates |
| title |
An alternative approach for gas hydrates: application to phase equilibria with presence of single-guest clathrate hydrates |
| spellingShingle |
An alternative approach for gas hydrates: application to phase equilibria with presence of single-guest clathrate hydrates Molina, Matías José SOLID SOLUTION CLATHRATE HYDRATES SOLID-FLUID EQUILIBRIUM EQUATION OF SATE |
| title_short |
An alternative approach for gas hydrates: application to phase equilibria with presence of single-guest clathrate hydrates |
| title_full |
An alternative approach for gas hydrates: application to phase equilibria with presence of single-guest clathrate hydrates |
| title_fullStr |
An alternative approach for gas hydrates: application to phase equilibria with presence of single-guest clathrate hydrates |
| title_full_unstemmed |
An alternative approach for gas hydrates: application to phase equilibria with presence of single-guest clathrate hydrates |
| title_sort |
An alternative approach for gas hydrates: application to phase equilibria with presence of single-guest clathrate hydrates |
| dc.creator.none.fl_str_mv |
Molina, Matías José Porras Giraldo, Andrés Felipe Rodriguez Reartes, Sabrina Belen Zabaloy, Marcelo Santiago |
| author |
Molina, Matías José |
| author_facet |
Molina, Matías José Porras Giraldo, Andrés Felipe Rodriguez Reartes, Sabrina Belen Zabaloy, Marcelo Santiago |
| author_role |
author |
| author2 |
Porras Giraldo, Andrés Felipe Rodriguez Reartes, Sabrina Belen Zabaloy, Marcelo Santiago |
| author2_role |
author author author |
| dc.subject.none.fl_str_mv |
SOLID SOLUTION CLATHRATE HYDRATES SOLID-FLUID EQUILIBRIUM EQUATION OF SATE |
| topic |
SOLID SOLUTION CLATHRATE HYDRATES SOLID-FLUID EQUILIBRIUM EQUATION OF SATE |
| purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
| dc.description.none.fl_txt_mv |
The goal of this work was to establish whether a recent approach proposed for representing the thermodynamic properties of solid solutions (Solid Solution Approach (SSA)) (Porras Giraldo, Rodriguez-Reartes and Zabaloy, 2021) would also be applicable to the case of clathrate hydrates over wide ranges of conditions. Clathrate hydrates (CHs) are nonstoichiometric ice-like solid materials (solid solutions) made of water (host) and another component (guest), such as methane. Actually, more than one guest may be present in the CH. The formation of CHs may be exploited in applications such as the fractionation of mixtures of gases. In contrast, the precipitation of CHs may cause plugging of pipelines in the oil and gas industry. Hence, knowledge of the conditions of CH formation is useful to promote or to avoid the CH precipitation. The van der Waals-Platteeuw model is the most widely used approach for evaluating the thermodynamic properties of CHs. This model is mathematically quite complex and it seems to be applicable only to solid solutions of the CH type. On the other hand, the SSA is mathematically much simpler, and has already been applied to solid solutions of varying nature (Porras Giraldo, Rodriguez-Reartes and Zabaloy, 2021), e.g., to those made of waxes. Fil: Molina, Matías José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina Fil: Porras Giraldo, Andrés Felipe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina Fil: Rodriguez Reartes, Sabrina Belen. Departament D'enginyeria Química; España. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina Fil: Zabaloy, Marcelo Santiago. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina 11th World Congress of Chemical Engineering Ciudad Autónoma de Buenos Aires Argentina Asociación Argentina de Ingenieros Químicos |
| description |
The goal of this work was to establish whether a recent approach proposed for representing the thermodynamic properties of solid solutions (Solid Solution Approach (SSA)) (Porras Giraldo, Rodriguez-Reartes and Zabaloy, 2021) would also be applicable to the case of clathrate hydrates over wide ranges of conditions. Clathrate hydrates (CHs) are nonstoichiometric ice-like solid materials (solid solutions) made of water (host) and another component (guest), such as methane. Actually, more than one guest may be present in the CH. The formation of CHs may be exploited in applications such as the fractionation of mixtures of gases. In contrast, the precipitation of CHs may cause plugging of pipelines in the oil and gas industry. Hence, knowledge of the conditions of CH formation is useful to promote or to avoid the CH precipitation. The van der Waals-Platteeuw model is the most widely used approach for evaluating the thermodynamic properties of CHs. This model is mathematically quite complex and it seems to be applicable only to solid solutions of the CH type. On the other hand, the SSA is mathematically much simpler, and has already been applied to solid solutions of varying nature (Porras Giraldo, Rodriguez-Reartes and Zabaloy, 2021), e.g., to those made of waxes. |
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2023 |
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2023 |
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info:eu-repo/semantics/publishedVersion info:eu-repo/semantics/conferenceObject Congreso Journal http://purl.org/coar/resource_type/c_5794 info:ar-repo/semantics/documentoDeConferencia |
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http://hdl.handle.net/11336/244307 An alternative approach for gas hydrates: application to phase equilibria with presence of single-guest clathrate hydrates; 11th World Congress of Chemical Engineering; Ciudad Autónoma de Buenos Aires; Argentina; 2023; 1-6 2953-5565 CONICET Digital CONICET |
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An alternative approach for gas hydrates: application to phase equilibria with presence of single-guest clathrate hydrates; 11th World Congress of Chemical Engineering; Ciudad Autónoma de Buenos Aires; Argentina; 2023; 1-6 2953-5565 CONICET Digital CONICET |
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eng |
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