Carbon steel passivity examined in solutions with a low degree of carbonation: The effect of chloride and nitrite ions
- Autores
- Valcarce, María Beatriz; Vazquez, Marcela Vivian
- Año de publicación
- 2009
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The effect of nitrite ions as inhibitors against steel corrosion in carbonated and chloride-contaminated concrete pore simulating solutions (pH 9) is investigated. Various inhibitor dosages and two chloride contents are tested. The inhibition efficiency is evaluated measuring the corrosion potential, cyclic voltammograms, anodic polarization curves, pitting and repassivation potentials, polarization resistance and performing electrochemical impedance spectra, together with weight-loss measurements. Independently of the chloride content, when [NO2−] = 0.2 mol l−1, the inhibition efficiency reaches 99% and if pitting occurs, surface repassivation is possible. At high chloride contents, if inadequate dosages of inhibitor are used, the risk of pitting attack is high because Epit is close to the OCP. The [NO2−]/[Cl−] ratio is not an appropriated parameter to evaluate the inhibitor efficiency for varying chloride concentrations in a carbonated concrete. An optimal nitrite ions concentration ([NO2−] = 0.2 mol l−1) can be established as the most suitable parameter to guarantee the inhibitor efficiency in the different electrolytes studied.
Fil: Valcarce, María Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Vazquez, Marcela Vivian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina - Materia
-
Surfaces
Oxides
Electrochemical Techniques
Corrosion - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/35010
Ver los metadatos del registro completo
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Carbon steel passivity examined in solutions with a low degree of carbonation: The effect of chloride and nitrite ionsValcarce, María BeatrizVazquez, Marcela VivianSurfacesOxidesElectrochemical TechniquesCorrosionhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The effect of nitrite ions as inhibitors against steel corrosion in carbonated and chloride-contaminated concrete pore simulating solutions (pH 9) is investigated. Various inhibitor dosages and two chloride contents are tested. The inhibition efficiency is evaluated measuring the corrosion potential, cyclic voltammograms, anodic polarization curves, pitting and repassivation potentials, polarization resistance and performing electrochemical impedance spectra, together with weight-loss measurements. Independently of the chloride content, when [NO2−] = 0.2 mol l−1, the inhibition efficiency reaches 99% and if pitting occurs, surface repassivation is possible. At high chloride contents, if inadequate dosages of inhibitor are used, the risk of pitting attack is high because Epit is close to the OCP. The [NO2−]/[Cl−] ratio is not an appropriated parameter to evaluate the inhibitor efficiency for varying chloride concentrations in a carbonated concrete. An optimal nitrite ions concentration ([NO2−] = 0.2 mol l−1) can be established as the most suitable parameter to guarantee the inhibitor efficiency in the different electrolytes studied.Fil: Valcarce, María Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Vazquez, Marcela Vivian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaElsevier Science Sa2009-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/35010Valcarce, María Beatriz; Vazquez, Marcela Vivian; Carbon steel passivity examined in solutions with a low degree of carbonation: The effect of chloride and nitrite ions; Elsevier Science Sa; Materials Chemistry and Physics; 115; 1; 3-2009; 313-3210254-0584CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.matchemphys.2008.12.007info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0254058408009863info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:39:12Zoai:ri.conicet.gov.ar:11336/35010instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:39:12.916CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Carbon steel passivity examined in solutions with a low degree of carbonation: The effect of chloride and nitrite ions |
title |
Carbon steel passivity examined in solutions with a low degree of carbonation: The effect of chloride and nitrite ions |
spellingShingle |
Carbon steel passivity examined in solutions with a low degree of carbonation: The effect of chloride and nitrite ions Valcarce, María Beatriz Surfaces Oxides Electrochemical Techniques Corrosion |
title_short |
Carbon steel passivity examined in solutions with a low degree of carbonation: The effect of chloride and nitrite ions |
title_full |
Carbon steel passivity examined in solutions with a low degree of carbonation: The effect of chloride and nitrite ions |
title_fullStr |
Carbon steel passivity examined in solutions with a low degree of carbonation: The effect of chloride and nitrite ions |
title_full_unstemmed |
Carbon steel passivity examined in solutions with a low degree of carbonation: The effect of chloride and nitrite ions |
title_sort |
Carbon steel passivity examined in solutions with a low degree of carbonation: The effect of chloride and nitrite ions |
dc.creator.none.fl_str_mv |
Valcarce, María Beatriz Vazquez, Marcela Vivian |
author |
Valcarce, María Beatriz |
author_facet |
Valcarce, María Beatriz Vazquez, Marcela Vivian |
author_role |
author |
author2 |
Vazquez, Marcela Vivian |
author2_role |
author |
dc.subject.none.fl_str_mv |
Surfaces Oxides Electrochemical Techniques Corrosion |
topic |
Surfaces Oxides Electrochemical Techniques Corrosion |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The effect of nitrite ions as inhibitors against steel corrosion in carbonated and chloride-contaminated concrete pore simulating solutions (pH 9) is investigated. Various inhibitor dosages and two chloride contents are tested. The inhibition efficiency is evaluated measuring the corrosion potential, cyclic voltammograms, anodic polarization curves, pitting and repassivation potentials, polarization resistance and performing electrochemical impedance spectra, together with weight-loss measurements. Independently of the chloride content, when [NO2−] = 0.2 mol l−1, the inhibition efficiency reaches 99% and if pitting occurs, surface repassivation is possible. At high chloride contents, if inadequate dosages of inhibitor are used, the risk of pitting attack is high because Epit is close to the OCP. The [NO2−]/[Cl−] ratio is not an appropriated parameter to evaluate the inhibitor efficiency for varying chloride concentrations in a carbonated concrete. An optimal nitrite ions concentration ([NO2−] = 0.2 mol l−1) can be established as the most suitable parameter to guarantee the inhibitor efficiency in the different electrolytes studied. Fil: Valcarce, María Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina Fil: Vazquez, Marcela Vivian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina |
description |
The effect of nitrite ions as inhibitors against steel corrosion in carbonated and chloride-contaminated concrete pore simulating solutions (pH 9) is investigated. Various inhibitor dosages and two chloride contents are tested. The inhibition efficiency is evaluated measuring the corrosion potential, cyclic voltammograms, anodic polarization curves, pitting and repassivation potentials, polarization resistance and performing electrochemical impedance spectra, together with weight-loss measurements. Independently of the chloride content, when [NO2−] = 0.2 mol l−1, the inhibition efficiency reaches 99% and if pitting occurs, surface repassivation is possible. At high chloride contents, if inadequate dosages of inhibitor are used, the risk of pitting attack is high because Epit is close to the OCP. The [NO2−]/[Cl−] ratio is not an appropriated parameter to evaluate the inhibitor efficiency for varying chloride concentrations in a carbonated concrete. An optimal nitrite ions concentration ([NO2−] = 0.2 mol l−1) can be established as the most suitable parameter to guarantee the inhibitor efficiency in the different electrolytes studied. |
publishDate |
2009 |
dc.date.none.fl_str_mv |
2009-03 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/35010 Valcarce, María Beatriz; Vazquez, Marcela Vivian; Carbon steel passivity examined in solutions with a low degree of carbonation: The effect of chloride and nitrite ions; Elsevier Science Sa; Materials Chemistry and Physics; 115; 1; 3-2009; 313-321 0254-0584 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/35010 |
identifier_str_mv |
Valcarce, María Beatriz; Vazquez, Marcela Vivian; Carbon steel passivity examined in solutions with a low degree of carbonation: The effect of chloride and nitrite ions; Elsevier Science Sa; Materials Chemistry and Physics; 115; 1; 3-2009; 313-321 0254-0584 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.matchemphys.2008.12.007 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0254058408009863 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science Sa |
publisher.none.fl_str_mv |
Elsevier Science Sa |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613239939268608 |
score |
13.070432 |