Electrodeposition of bilayered polypyrrole on 316 L stainless steel for corrosion prevention

Autores
González, Belén; Saidman, Silvana Beatriz
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The electropolymerization of pyrrole in aqueous solutions of salicylate leads to the formation of hollow rectangular-sectioned microtubes. With the aim to develop a coating with this morphology but with better anticorrosive properties we synthesized a bilayer system by depositing a polypyrrole underlayer electropolymerized in the presence of molybdate and nitrate and a polypyrrole film formed by the microtubes as a top layer. The corrosion performance of the coatings was monitored by following the open circuit potentials, polarization curves and electrochemical impedance spectroscopy in acid and neutral chloride solutions. The bilayers have the capacity to protect the steel against uniform as well as against pitting corrosion during long exposure times. The system with the inner layer formed in alkaline solution was the most protective coating in this study. The results are discussed in terms of the galvanic interaction between the polymer and the substrate and the role played by the dopant anions.
Fil: González, Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina
Fil: Saidman, Silvana Beatriz. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina
Materia
Coatings
Corrosion
Electrochemical Techniques
Polymers
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/39615
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Electrodeposition of bilayered polypyrrole on 316 L stainless steel for corrosion preventionGonzález, BelénSaidman, Silvana BeatrizCoatingsCorrosionElectrochemical TechniquesPolymershttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The electropolymerization of pyrrole in aqueous solutions of salicylate leads to the formation of hollow rectangular-sectioned microtubes. With the aim to develop a coating with this morphology but with better anticorrosive properties we synthesized a bilayer system by depositing a polypyrrole underlayer electropolymerized in the presence of molybdate and nitrate and a polypyrrole film formed by the microtubes as a top layer. The corrosion performance of the coatings was monitored by following the open circuit potentials, polarization curves and electrochemical impedance spectroscopy in acid and neutral chloride solutions. The bilayers have the capacity to protect the steel against uniform as well as against pitting corrosion during long exposure times. The system with the inner layer formed in alkaline solution was the most protective coating in this study. The results are discussed in terms of the galvanic interaction between the polymer and the substrate and the role played by the dopant anions.Fil: González, Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; ArgentinaFil: Saidman, Silvana Beatriz. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; ArgentinaElsevier Science Sa2015-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/39615González, Belén; Saidman, Silvana Beatriz; Electrodeposition of bilayered polypyrrole on 316 L stainless steel for corrosion prevention; Elsevier Science Sa; Progress In Organic Coatings; 78; 1-2015; 21-270300-9440CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0300944014003415info:eu-repo/semantics/altIdentifier/doi/10.1016/j.porgcoat.2014.10.012info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:03:11Zoai:ri.conicet.gov.ar:11336/39615instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:03:11.926CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Electrodeposition of bilayered polypyrrole on 316 L stainless steel for corrosion prevention
title Electrodeposition of bilayered polypyrrole on 316 L stainless steel for corrosion prevention
spellingShingle Electrodeposition of bilayered polypyrrole on 316 L stainless steel for corrosion prevention
González, Belén
Coatings
Corrosion
Electrochemical Techniques
Polymers
title_short Electrodeposition of bilayered polypyrrole on 316 L stainless steel for corrosion prevention
title_full Electrodeposition of bilayered polypyrrole on 316 L stainless steel for corrosion prevention
title_fullStr Electrodeposition of bilayered polypyrrole on 316 L stainless steel for corrosion prevention
title_full_unstemmed Electrodeposition of bilayered polypyrrole on 316 L stainless steel for corrosion prevention
title_sort Electrodeposition of bilayered polypyrrole on 316 L stainless steel for corrosion prevention
dc.creator.none.fl_str_mv González, Belén
Saidman, Silvana Beatriz
author González, Belén
author_facet González, Belén
Saidman, Silvana Beatriz
author_role author
author2 Saidman, Silvana Beatriz
author2_role author
dc.subject.none.fl_str_mv Coatings
Corrosion
Electrochemical Techniques
Polymers
topic Coatings
Corrosion
Electrochemical Techniques
Polymers
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The electropolymerization of pyrrole in aqueous solutions of salicylate leads to the formation of hollow rectangular-sectioned microtubes. With the aim to develop a coating with this morphology but with better anticorrosive properties we synthesized a bilayer system by depositing a polypyrrole underlayer electropolymerized in the presence of molybdate and nitrate and a polypyrrole film formed by the microtubes as a top layer. The corrosion performance of the coatings was monitored by following the open circuit potentials, polarization curves and electrochemical impedance spectroscopy in acid and neutral chloride solutions. The bilayers have the capacity to protect the steel against uniform as well as against pitting corrosion during long exposure times. The system with the inner layer formed in alkaline solution was the most protective coating in this study. The results are discussed in terms of the galvanic interaction between the polymer and the substrate and the role played by the dopant anions.
Fil: González, Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina
Fil: Saidman, Silvana Beatriz. Universidad Nacional del Sur. Departamento de Ingeniería Química. Instituto de Ingeniería Electroquímica y Corrosión; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina
description The electropolymerization of pyrrole in aqueous solutions of salicylate leads to the formation of hollow rectangular-sectioned microtubes. With the aim to develop a coating with this morphology but with better anticorrosive properties we synthesized a bilayer system by depositing a polypyrrole underlayer electropolymerized in the presence of molybdate and nitrate and a polypyrrole film formed by the microtubes as a top layer. The corrosion performance of the coatings was monitored by following the open circuit potentials, polarization curves and electrochemical impedance spectroscopy in acid and neutral chloride solutions. The bilayers have the capacity to protect the steel against uniform as well as against pitting corrosion during long exposure times. The system with the inner layer formed in alkaline solution was the most protective coating in this study. The results are discussed in terms of the galvanic interaction between the polymer and the substrate and the role played by the dopant anions.
publishDate 2015
dc.date.none.fl_str_mv 2015-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/39615
González, Belén; Saidman, Silvana Beatriz; Electrodeposition of bilayered polypyrrole on 316 L stainless steel for corrosion prevention; Elsevier Science Sa; Progress In Organic Coatings; 78; 1-2015; 21-27
0300-9440
CONICET Digital
CONICET
url http://hdl.handle.net/11336/39615
identifier_str_mv González, Belén; Saidman, Silvana Beatriz; Electrodeposition of bilayered polypyrrole on 316 L stainless steel for corrosion prevention; Elsevier Science Sa; Progress In Organic Coatings; 78; 1-2015; 21-27
0300-9440
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0300944014003415
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.porgcoat.2014.10.012
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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