Plasma-based techniques applied to the determination of 17 elements in partitioned top soils
- Autores
- Morales del Mastro, Anabella Mabel; Londonio, Juan Agustín; Jiménez Rebagliati, Raúl Alberto Jorge; Pereyra, Marcelo Tomas; Dawidowski, Laura Elena; Gómez, Darío; Smichowski, Patricia Nora
- Año de publicación
- 2015
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- An investigation was carried out to characterize top soils collected in a prototypical urban area impacted by industrial and agricultural activities. Soils of the studied zone receive also the contribution of traffic from the urban area, marine aerosols from the Atlantic Ocean and dust from the Patagonian steppe. Top soil samples were sampled and then sieved in two fractions (F1 < 37 μm, and 37 < F2 < 50 μm) for subsequent digestion using an acid mixture containing HCl, HNO3 and HF (6:2:1). Elemental determination of Al, As, Ba, Ca, Cd, Cr, Cu, Fe, Mg, Mn, Mo, Ni, Pb, Sb, Ti, V and Zn was carried out by inductively coupled plasma optical emission spectrometry (ICP OES) and/or inductively coupled plasma-mass spectrometry (ICP-MS). Accuracy tests for the entire analytical procedure were performed by means of the certified reference material NIST SRM 2711 Montana soil. Limit of detection reached varied from 0.08 μg g− 1 (Cd) to 2.4 μg g− 1 (Ba). Elemental concentrations ranged from 0.10 ± 0.01 μg g− 1 (Mo) to 14.6 ± 0.6% (Ca). Aluminum, Ca, Fe, Mg and Ti (geological elements) were found at concentrations in the percentage order. The ratios of elemental concentrations Mo/Ca, Ni/Ca and Ti/Ca were identified as chemical markers suitable for distinguishing the different soil samples by exposing the relative differences in the 4-element chemical profile. The concentrations of metals and metalloids in size-fractionated top soils reported in this study will be an important tool for future studies aimed to characterize soil resuspension and its contribution to airborne particulate matter.
Fil: Morales del Mastro, Anabella Mabel. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Londonio, Juan Agustín. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; Argentina
Fil: Jiménez Rebagliati, Raúl Alberto Jorge. Comisión Nacional de Energía Atómica; Argentina
Fil: Pereyra, Marcelo Tomas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Dawidowski, Laura Elena. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; Argentina
Fil: Gómez, Darío. Comisión Nacional de Energía Atómica; Argentina
Fil: Smichowski, Patricia Nora. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina - Materia
-
Soils
Physical Fractionation
Metals And Metalloids
Chemical Markers - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
.jpg)
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/40537
Ver los metadatos del registro completo
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Plasma-based techniques applied to the determination of 17 elements in partitioned top soilsMorales del Mastro, Anabella MabelLondonio, Juan AgustínJiménez Rebagliati, Raúl Alberto JorgePereyra, Marcelo TomasDawidowski, Laura ElenaGómez, DaríoSmichowski, Patricia NoraSoilsPhysical FractionationMetals And MetalloidsChemical Markershttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1An investigation was carried out to characterize top soils collected in a prototypical urban area impacted by industrial and agricultural activities. Soils of the studied zone receive also the contribution of traffic from the urban area, marine aerosols from the Atlantic Ocean and dust from the Patagonian steppe. Top soil samples were sampled and then sieved in two fractions (F1 < 37 μm, and 37 < F2 < 50 μm) for subsequent digestion using an acid mixture containing HCl, HNO3 and HF (6:2:1). Elemental determination of Al, As, Ba, Ca, Cd, Cr, Cu, Fe, Mg, Mn, Mo, Ni, Pb, Sb, Ti, V and Zn was carried out by inductively coupled plasma optical emission spectrometry (ICP OES) and/or inductively coupled plasma-mass spectrometry (ICP-MS). Accuracy tests for the entire analytical procedure were performed by means of the certified reference material NIST SRM 2711 Montana soil. Limit of detection reached varied from 0.08 μg g− 1 (Cd) to 2.4 μg g− 1 (Ba). Elemental concentrations ranged from 0.10 ± 0.01 μg g− 1 (Mo) to 14.6 ± 0.6% (Ca). Aluminum, Ca, Fe, Mg and Ti (geological elements) were found at concentrations in the percentage order. The ratios of elemental concentrations Mo/Ca, Ni/Ca and Ti/Ca were identified as chemical markers suitable for distinguishing the different soil samples by exposing the relative differences in the 4-element chemical profile. The concentrations of metals and metalloids in size-fractionated top soils reported in this study will be an important tool for future studies aimed to characterize soil resuspension and its contribution to airborne particulate matter.Fil: Morales del Mastro, Anabella Mabel. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Londonio, Juan Agustín. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; ArgentinaFil: Jiménez Rebagliati, Raúl Alberto Jorge. Comisión Nacional de Energía Atómica; ArgentinaFil: Pereyra, Marcelo Tomas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Dawidowski, Laura Elena. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; ArgentinaFil: Gómez, Darío. Comisión Nacional de Energía Atómica; ArgentinaFil: Smichowski, Patricia Nora. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaElsevier Science2015-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/40537Morales del Mastro, Anabella Mabel; Londonio, Juan Agustín; Jiménez Rebagliati, Raúl Alberto Jorge; Pereyra, Marcelo Tomas; Dawidowski, Laura Elena; et al.; Plasma-based techniques applied to the determination of 17 elements in partitioned top soils; Elsevier Science; Microchemical Journal; 123; 11-2015; 224-2290026-265XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2015.07.002info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0026265X15001393info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:35:47Zoai:ri.conicet.gov.ar:11336/40537instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:35:48.202CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
| dc.title.none.fl_str_mv |
Plasma-based techniques applied to the determination of 17 elements in partitioned top soils |
| title |
Plasma-based techniques applied to the determination of 17 elements in partitioned top soils |
| spellingShingle |
Plasma-based techniques applied to the determination of 17 elements in partitioned top soils Morales del Mastro, Anabella Mabel Soils Physical Fractionation Metals And Metalloids Chemical Markers |
| title_short |
Plasma-based techniques applied to the determination of 17 elements in partitioned top soils |
| title_full |
Plasma-based techniques applied to the determination of 17 elements in partitioned top soils |
| title_fullStr |
Plasma-based techniques applied to the determination of 17 elements in partitioned top soils |
| title_full_unstemmed |
Plasma-based techniques applied to the determination of 17 elements in partitioned top soils |
| title_sort |
Plasma-based techniques applied to the determination of 17 elements in partitioned top soils |
| dc.creator.none.fl_str_mv |
Morales del Mastro, Anabella Mabel Londonio, Juan Agustín Jiménez Rebagliati, Raúl Alberto Jorge Pereyra, Marcelo Tomas Dawidowski, Laura Elena Gómez, Darío Smichowski, Patricia Nora |
| author |
Morales del Mastro, Anabella Mabel |
| author_facet |
Morales del Mastro, Anabella Mabel Londonio, Juan Agustín Jiménez Rebagliati, Raúl Alberto Jorge Pereyra, Marcelo Tomas Dawidowski, Laura Elena Gómez, Darío Smichowski, Patricia Nora |
| author_role |
author |
| author2 |
Londonio, Juan Agustín Jiménez Rebagliati, Raúl Alberto Jorge Pereyra, Marcelo Tomas Dawidowski, Laura Elena Gómez, Darío Smichowski, Patricia Nora |
| author2_role |
author author author author author author |
| dc.subject.none.fl_str_mv |
Soils Physical Fractionation Metals And Metalloids Chemical Markers |
| topic |
Soils Physical Fractionation Metals And Metalloids Chemical Markers |
| purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| dc.description.none.fl_txt_mv |
An investigation was carried out to characterize top soils collected in a prototypical urban area impacted by industrial and agricultural activities. Soils of the studied zone receive also the contribution of traffic from the urban area, marine aerosols from the Atlantic Ocean and dust from the Patagonian steppe. Top soil samples were sampled and then sieved in two fractions (F1 < 37 μm, and 37 < F2 < 50 μm) for subsequent digestion using an acid mixture containing HCl, HNO3 and HF (6:2:1). Elemental determination of Al, As, Ba, Ca, Cd, Cr, Cu, Fe, Mg, Mn, Mo, Ni, Pb, Sb, Ti, V and Zn was carried out by inductively coupled plasma optical emission spectrometry (ICP OES) and/or inductively coupled plasma-mass spectrometry (ICP-MS). Accuracy tests for the entire analytical procedure were performed by means of the certified reference material NIST SRM 2711 Montana soil. Limit of detection reached varied from 0.08 μg g− 1 (Cd) to 2.4 μg g− 1 (Ba). Elemental concentrations ranged from 0.10 ± 0.01 μg g− 1 (Mo) to 14.6 ± 0.6% (Ca). Aluminum, Ca, Fe, Mg and Ti (geological elements) were found at concentrations in the percentage order. The ratios of elemental concentrations Mo/Ca, Ni/Ca and Ti/Ca were identified as chemical markers suitable for distinguishing the different soil samples by exposing the relative differences in the 4-element chemical profile. The concentrations of metals and metalloids in size-fractionated top soils reported in this study will be an important tool for future studies aimed to characterize soil resuspension and its contribution to airborne particulate matter. Fil: Morales del Mastro, Anabella Mabel. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Londonio, Juan Agustín. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; Argentina Fil: Jiménez Rebagliati, Raúl Alberto Jorge. Comisión Nacional de Energía Atómica; Argentina Fil: Pereyra, Marcelo Tomas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina Fil: Dawidowski, Laura Elena. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; Argentina Fil: Gómez, Darío. Comisión Nacional de Energía Atómica; Argentina Fil: Smichowski, Patricia Nora. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina |
| description |
An investigation was carried out to characterize top soils collected in a prototypical urban area impacted by industrial and agricultural activities. Soils of the studied zone receive also the contribution of traffic from the urban area, marine aerosols from the Atlantic Ocean and dust from the Patagonian steppe. Top soil samples were sampled and then sieved in two fractions (F1 < 37 μm, and 37 < F2 < 50 μm) for subsequent digestion using an acid mixture containing HCl, HNO3 and HF (6:2:1). Elemental determination of Al, As, Ba, Ca, Cd, Cr, Cu, Fe, Mg, Mn, Mo, Ni, Pb, Sb, Ti, V and Zn was carried out by inductively coupled plasma optical emission spectrometry (ICP OES) and/or inductively coupled plasma-mass spectrometry (ICP-MS). Accuracy tests for the entire analytical procedure were performed by means of the certified reference material NIST SRM 2711 Montana soil. Limit of detection reached varied from 0.08 μg g− 1 (Cd) to 2.4 μg g− 1 (Ba). Elemental concentrations ranged from 0.10 ± 0.01 μg g− 1 (Mo) to 14.6 ± 0.6% (Ca). Aluminum, Ca, Fe, Mg and Ti (geological elements) were found at concentrations in the percentage order. The ratios of elemental concentrations Mo/Ca, Ni/Ca and Ti/Ca were identified as chemical markers suitable for distinguishing the different soil samples by exposing the relative differences in the 4-element chemical profile. The concentrations of metals and metalloids in size-fractionated top soils reported in this study will be an important tool for future studies aimed to characterize soil resuspension and its contribution to airborne particulate matter. |
| publishDate |
2015 |
| dc.date.none.fl_str_mv |
2015-11 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
| format |
article |
| status_str |
publishedVersion |
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http://hdl.handle.net/11336/40537 Morales del Mastro, Anabella Mabel; Londonio, Juan Agustín; Jiménez Rebagliati, Raúl Alberto Jorge; Pereyra, Marcelo Tomas; Dawidowski, Laura Elena; et al.; Plasma-based techniques applied to the determination of 17 elements in partitioned top soils; Elsevier Science; Microchemical Journal; 123; 11-2015; 224-229 0026-265X CONICET Digital CONICET |
| url |
http://hdl.handle.net/11336/40537 |
| identifier_str_mv |
Morales del Mastro, Anabella Mabel; Londonio, Juan Agustín; Jiménez Rebagliati, Raúl Alberto Jorge; Pereyra, Marcelo Tomas; Dawidowski, Laura Elena; et al.; Plasma-based techniques applied to the determination of 17 elements in partitioned top soils; Elsevier Science; Microchemical Journal; 123; 11-2015; 224-229 0026-265X CONICET Digital CONICET |
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eng |
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eng |
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info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2015.07.002 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0026265X15001393 |
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Elsevier Science |
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Elsevier Science |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
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dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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