Plasma-based techniques applied to the determination of 17 elements in partitioned top soils

Autores
Morales del Mastro, Anabella Mabel; Londonio, Juan Agustín; Jiménez Rebagliati, Raúl Alberto Jorge; Pereyra, Marcelo Tomas; Dawidowski, Laura Elena; Gómez, Darío; Smichowski, Patricia Nora
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
An investigation was carried out to characterize top soils collected in a prototypical urban area impacted by industrial and agricultural activities. Soils of the studied zone receive also the contribution of traffic from the urban area, marine aerosols from the Atlantic Ocean and dust from the Patagonian steppe. Top soil samples were sampled and then sieved in two fractions (F1 < 37 μm, and 37 < F2 < 50 μm) for subsequent digestion using an acid mixture containing HCl, HNO3 and HF (6:2:1). Elemental determination of Al, As, Ba, Ca, Cd, Cr, Cu, Fe, Mg, Mn, Mo, Ni, Pb, Sb, Ti, V and Zn was carried out by inductively coupled plasma optical emission spectrometry (ICP OES) and/or inductively coupled plasma-mass spectrometry (ICP-MS). Accuracy tests for the entire analytical procedure were performed by means of the certified reference material NIST SRM 2711 Montana soil. Limit of detection reached varied from 0.08 μg g− 1 (Cd) to 2.4 μg g− 1 (Ba). Elemental concentrations ranged from 0.10 ± 0.01 μg g− 1 (Mo) to 14.6 ± 0.6% (Ca). Aluminum, Ca, Fe, Mg and Ti (geological elements) were found at concentrations in the percentage order. The ratios of elemental concentrations Mo/Ca, Ni/Ca and Ti/Ca were identified as chemical markers suitable for distinguishing the different soil samples by exposing the relative differences in the 4-element chemical profile. The concentrations of metals and metalloids in size-fractionated top soils reported in this study will be an important tool for future studies aimed to characterize soil resuspension and its contribution to airborne particulate matter.
Fil: Morales del Mastro, Anabella Mabel. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Londonio, Juan Agustín. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; Argentina
Fil: Jiménez Rebagliati, Raúl Alberto Jorge. Comisión Nacional de Energía Atómica; Argentina
Fil: Pereyra, Marcelo Tomas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Dawidowski, Laura Elena. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; Argentina
Fil: Gómez, Darío. Comisión Nacional de Energía Atómica; Argentina
Fil: Smichowski, Patricia Nora. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
Soils
Physical Fractionation
Metals And Metalloids
Chemical Markers
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/40537
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/40537
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Plasma-based techniques applied to the determination of 17 elements in partitioned top soilsMorales del Mastro, Anabella MabelLondonio, Juan AgustínJiménez Rebagliati, Raúl Alberto JorgePereyra, Marcelo TomasDawidowski, Laura ElenaGómez, DaríoSmichowski, Patricia NoraSoilsPhysical FractionationMetals And MetalloidsChemical Markershttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1An investigation was carried out to characterize top soils collected in a prototypical urban area impacted by industrial and agricultural activities. Soils of the studied zone receive also the contribution of traffic from the urban area, marine aerosols from the Atlantic Ocean and dust from the Patagonian steppe. Top soil samples were sampled and then sieved in two fractions (F1 < 37 μm, and 37 < F2 < 50 μm) for subsequent digestion using an acid mixture containing HCl, HNO3 and HF (6:2:1). Elemental determination of Al, As, Ba, Ca, Cd, Cr, Cu, Fe, Mg, Mn, Mo, Ni, Pb, Sb, Ti, V and Zn was carried out by inductively coupled plasma optical emission spectrometry (ICP OES) and/or inductively coupled plasma-mass spectrometry (ICP-MS). Accuracy tests for the entire analytical procedure were performed by means of the certified reference material NIST SRM 2711 Montana soil. Limit of detection reached varied from 0.08 μg g− 1 (Cd) to 2.4 μg g− 1 (Ba). Elemental concentrations ranged from 0.10 ± 0.01 μg g− 1 (Mo) to 14.6 ± 0.6% (Ca). Aluminum, Ca, Fe, Mg and Ti (geological elements) were found at concentrations in the percentage order. The ratios of elemental concentrations Mo/Ca, Ni/Ca and Ti/Ca were identified as chemical markers suitable for distinguishing the different soil samples by exposing the relative differences in the 4-element chemical profile. The concentrations of metals and metalloids in size-fractionated top soils reported in this study will be an important tool for future studies aimed to characterize soil resuspension and its contribution to airborne particulate matter.Fil: Morales del Mastro, Anabella Mabel. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Londonio, Juan Agustín. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; ArgentinaFil: Jiménez Rebagliati, Raúl Alberto Jorge. Comisión Nacional de Energía Atómica; ArgentinaFil: Pereyra, Marcelo Tomas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Dawidowski, Laura Elena. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; ArgentinaFil: Gómez, Darío. Comisión Nacional de Energía Atómica; ArgentinaFil: Smichowski, Patricia Nora. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaElsevier Science2015-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/40537Morales del Mastro, Anabella Mabel; Londonio, Juan Agustín; Jiménez Rebagliati, Raúl Alberto Jorge; Pereyra, Marcelo Tomas; Dawidowski, Laura Elena; et al.; Plasma-based techniques applied to the determination of 17 elements in partitioned top soils; Elsevier Science; Microchemical Journal; 123; 11-2015; 224-2290026-265XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2015.07.002info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0026265X15001393info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:33:24Zoai:ri.conicet.gov.ar:11336/40537instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:33:24.802CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Plasma-based techniques applied to the determination of 17 elements in partitioned top soils
title Plasma-based techniques applied to the determination of 17 elements in partitioned top soils
spellingShingle Plasma-based techniques applied to the determination of 17 elements in partitioned top soils
Morales del Mastro, Anabella Mabel
Soils
Physical Fractionation
Metals And Metalloids
Chemical Markers
title_short Plasma-based techniques applied to the determination of 17 elements in partitioned top soils
title_full Plasma-based techniques applied to the determination of 17 elements in partitioned top soils
title_fullStr Plasma-based techniques applied to the determination of 17 elements in partitioned top soils
title_full_unstemmed Plasma-based techniques applied to the determination of 17 elements in partitioned top soils
title_sort Plasma-based techniques applied to the determination of 17 elements in partitioned top soils
dc.creator.none.fl_str_mv Morales del Mastro, Anabella Mabel
Londonio, Juan Agustín
Jiménez Rebagliati, Raúl Alberto Jorge
Pereyra, Marcelo Tomas
Dawidowski, Laura Elena
Gómez, Darío
Smichowski, Patricia Nora
author Morales del Mastro, Anabella Mabel
author_facet Morales del Mastro, Anabella Mabel
Londonio, Juan Agustín
Jiménez Rebagliati, Raúl Alberto Jorge
Pereyra, Marcelo Tomas
Dawidowski, Laura Elena
Gómez, Darío
Smichowski, Patricia Nora
author_role author
author2 Londonio, Juan Agustín
Jiménez Rebagliati, Raúl Alberto Jorge
Pereyra, Marcelo Tomas
Dawidowski, Laura Elena
Gómez, Darío
Smichowski, Patricia Nora
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Soils
Physical Fractionation
Metals And Metalloids
Chemical Markers
topic Soils
Physical Fractionation
Metals And Metalloids
Chemical Markers
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv An investigation was carried out to characterize top soils collected in a prototypical urban area impacted by industrial and agricultural activities. Soils of the studied zone receive also the contribution of traffic from the urban area, marine aerosols from the Atlantic Ocean and dust from the Patagonian steppe. Top soil samples were sampled and then sieved in two fractions (F1 < 37 μm, and 37 < F2 < 50 μm) for subsequent digestion using an acid mixture containing HCl, HNO3 and HF (6:2:1). Elemental determination of Al, As, Ba, Ca, Cd, Cr, Cu, Fe, Mg, Mn, Mo, Ni, Pb, Sb, Ti, V and Zn was carried out by inductively coupled plasma optical emission spectrometry (ICP OES) and/or inductively coupled plasma-mass spectrometry (ICP-MS). Accuracy tests for the entire analytical procedure were performed by means of the certified reference material NIST SRM 2711 Montana soil. Limit of detection reached varied from 0.08 μg g− 1 (Cd) to 2.4 μg g− 1 (Ba). Elemental concentrations ranged from 0.10 ± 0.01 μg g− 1 (Mo) to 14.6 ± 0.6% (Ca). Aluminum, Ca, Fe, Mg and Ti (geological elements) were found at concentrations in the percentage order. The ratios of elemental concentrations Mo/Ca, Ni/Ca and Ti/Ca were identified as chemical markers suitable for distinguishing the different soil samples by exposing the relative differences in the 4-element chemical profile. The concentrations of metals and metalloids in size-fractionated top soils reported in this study will be an important tool for future studies aimed to characterize soil resuspension and its contribution to airborne particulate matter.
Fil: Morales del Mastro, Anabella Mabel. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Londonio, Juan Agustín. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; Argentina
Fil: Jiménez Rebagliati, Raúl Alberto Jorge. Comisión Nacional de Energía Atómica; Argentina
Fil: Pereyra, Marcelo Tomas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Dawidowski, Laura Elena. Comisión Nacional de Energía Atómica; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental; Argentina
Fil: Gómez, Darío. Comisión Nacional de Energía Atómica; Argentina
Fil: Smichowski, Patricia Nora. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description An investigation was carried out to characterize top soils collected in a prototypical urban area impacted by industrial and agricultural activities. Soils of the studied zone receive also the contribution of traffic from the urban area, marine aerosols from the Atlantic Ocean and dust from the Patagonian steppe. Top soil samples were sampled and then sieved in two fractions (F1 < 37 μm, and 37 < F2 < 50 μm) for subsequent digestion using an acid mixture containing HCl, HNO3 and HF (6:2:1). Elemental determination of Al, As, Ba, Ca, Cd, Cr, Cu, Fe, Mg, Mn, Mo, Ni, Pb, Sb, Ti, V and Zn was carried out by inductively coupled plasma optical emission spectrometry (ICP OES) and/or inductively coupled plasma-mass spectrometry (ICP-MS). Accuracy tests for the entire analytical procedure were performed by means of the certified reference material NIST SRM 2711 Montana soil. Limit of detection reached varied from 0.08 μg g− 1 (Cd) to 2.4 μg g− 1 (Ba). Elemental concentrations ranged from 0.10 ± 0.01 μg g− 1 (Mo) to 14.6 ± 0.6% (Ca). Aluminum, Ca, Fe, Mg and Ti (geological elements) were found at concentrations in the percentage order. The ratios of elemental concentrations Mo/Ca, Ni/Ca and Ti/Ca were identified as chemical markers suitable for distinguishing the different soil samples by exposing the relative differences in the 4-element chemical profile. The concentrations of metals and metalloids in size-fractionated top soils reported in this study will be an important tool for future studies aimed to characterize soil resuspension and its contribution to airborne particulate matter.
publishDate 2015
dc.date.none.fl_str_mv 2015-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/40537
Morales del Mastro, Anabella Mabel; Londonio, Juan Agustín; Jiménez Rebagliati, Raúl Alberto Jorge; Pereyra, Marcelo Tomas; Dawidowski, Laura Elena; et al.; Plasma-based techniques applied to the determination of 17 elements in partitioned top soils; Elsevier Science; Microchemical Journal; 123; 11-2015; 224-229
0026-265X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/40537
identifier_str_mv Morales del Mastro, Anabella Mabel; Londonio, Juan Agustín; Jiménez Rebagliati, Raúl Alberto Jorge; Pereyra, Marcelo Tomas; Dawidowski, Laura Elena; et al.; Plasma-based techniques applied to the determination of 17 elements in partitioned top soils; Elsevier Science; Microchemical Journal; 123; 11-2015; 224-229
0026-265X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2015.07.002
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0026265X15001393
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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