3Y-TZP dip-coated with Zn-containing calcium silicate layers: development and characterization

Autores
Bruni, Yesica Lorena; Albano, Maria Patricia
Año de publicación
2021
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Coating layers based on Ca3Si3O9, Ca2ZnSi2O7, and ZnSiO4 on 3Y-TZP ceramics were obtained by the dip coating process, using SiO2-CaO-P2O5-ZnO glass suspensions with Zn contents in the range of 0-20 mol%. The influence of the Zn content in the dip coating slips, the slip solid loading, and the 3Y-TZP surface porosity on the layer formation rate was studied. The Zn content of the dip coating slips as well as the slip solid loading greatly affected the slip viscosity, and consequently the liquid entrainment mechanism at the initial stage. The low dissolution rate of 20 mol% Zn-containing slips decreased the dip coating slip viscosity, whereas the lower stability of 10 mol% Zn-containing slips increased the slip viscosity. A significant increase in the initial layer thickness was produced either by using 10 mol% Zn-containing slips or by increasing the slip solid loading. The casting rate for longer immersion times was markedly accelerated by increasing the 3Y-TZP surface porosity. Sintered layers based on ZnSiO4 having the lowest thickness values were produced using the glass containing 20 mol% Zn. On the other hand, the 0 and 10 mol% Zn-containing glass produced thicker sintered layers mainly composed of Ca3Si3O9 and Ca2ZnSi2O7, respectively.
Fil: Bruni, Yesica Lorena. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas; Argentina
Fil: Albano, Maria Patricia. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas; Argentina
Materia
3Y-TZP COATED WITH ZN-CONTAINING CALCIUM SILICATE
BIOMATERIALS
DIP COATING PROCESS
LAYER GROWTH RATE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/181288
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/181288
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling 3Y-TZP dip-coated with Zn-containing calcium silicate layers: development and characterizationBruni, Yesica LorenaAlbano, Maria Patricia3Y-TZP COATED WITH ZN-CONTAINING CALCIUM SILICATEBIOMATERIALSDIP COATING PROCESSLAYER GROWTH RATEhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Coating layers based on Ca3Si3O9, Ca2ZnSi2O7, and ZnSiO4 on 3Y-TZP ceramics were obtained by the dip coating process, using SiO2-CaO-P2O5-ZnO glass suspensions with Zn contents in the range of 0-20 mol%. The influence of the Zn content in the dip coating slips, the slip solid loading, and the 3Y-TZP surface porosity on the layer formation rate was studied. The Zn content of the dip coating slips as well as the slip solid loading greatly affected the slip viscosity, and consequently the liquid entrainment mechanism at the initial stage. The low dissolution rate of 20 mol% Zn-containing slips decreased the dip coating slip viscosity, whereas the lower stability of 10 mol% Zn-containing slips increased the slip viscosity. A significant increase in the initial layer thickness was produced either by using 10 mol% Zn-containing slips or by increasing the slip solid loading. The casting rate for longer immersion times was markedly accelerated by increasing the 3Y-TZP surface porosity. Sintered layers based on ZnSiO4 having the lowest thickness values were produced using the glass containing 20 mol% Zn. On the other hand, the 0 and 10 mol% Zn-containing glass produced thicker sintered layers mainly composed of Ca3Si3O9 and Ca2ZnSi2O7, respectively.Fil: Bruni, Yesica Lorena. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas; ArgentinaFil: Albano, Maria Patricia. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas; ArgentinaAssociação Brasileira de Cerâmica2021-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/181288Bruni, Yesica Lorena; Albano, Maria Patricia; 3Y-TZP dip-coated with Zn-containing calcium silicate layers: development and characterization; Associação Brasileira de Cerâmica; Ceramica; 67; 384; 10-2021; 463-4700366-69131678-4553CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.scielo.br/j/ce/a/KNQVygx4DCJ5bYPHmpzd9Vm/?lang=eninfo:eu-repo/semantics/altIdentifier/doi/10.1590/0366-69132021673843170info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:06:53Zoai:ri.conicet.gov.ar:11336/181288instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:06:53.912CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv 3Y-TZP dip-coated with Zn-containing calcium silicate layers: development and characterization
title 3Y-TZP dip-coated with Zn-containing calcium silicate layers: development and characterization
spellingShingle 3Y-TZP dip-coated with Zn-containing calcium silicate layers: development and characterization
Bruni, Yesica Lorena
3Y-TZP COATED WITH ZN-CONTAINING CALCIUM SILICATE
BIOMATERIALS
DIP COATING PROCESS
LAYER GROWTH RATE
title_short 3Y-TZP dip-coated with Zn-containing calcium silicate layers: development and characterization
title_full 3Y-TZP dip-coated with Zn-containing calcium silicate layers: development and characterization
title_fullStr 3Y-TZP dip-coated with Zn-containing calcium silicate layers: development and characterization
title_full_unstemmed 3Y-TZP dip-coated with Zn-containing calcium silicate layers: development and characterization
title_sort 3Y-TZP dip-coated with Zn-containing calcium silicate layers: development and characterization
dc.creator.none.fl_str_mv Bruni, Yesica Lorena
Albano, Maria Patricia
author Bruni, Yesica Lorena
author_facet Bruni, Yesica Lorena
Albano, Maria Patricia
author_role author
author2 Albano, Maria Patricia
author2_role author
dc.subject.none.fl_str_mv 3Y-TZP COATED WITH ZN-CONTAINING CALCIUM SILICATE
BIOMATERIALS
DIP COATING PROCESS
LAYER GROWTH RATE
topic 3Y-TZP COATED WITH ZN-CONTAINING CALCIUM SILICATE
BIOMATERIALS
DIP COATING PROCESS
LAYER GROWTH RATE
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Coating layers based on Ca3Si3O9, Ca2ZnSi2O7, and ZnSiO4 on 3Y-TZP ceramics were obtained by the dip coating process, using SiO2-CaO-P2O5-ZnO glass suspensions with Zn contents in the range of 0-20 mol%. The influence of the Zn content in the dip coating slips, the slip solid loading, and the 3Y-TZP surface porosity on the layer formation rate was studied. The Zn content of the dip coating slips as well as the slip solid loading greatly affected the slip viscosity, and consequently the liquid entrainment mechanism at the initial stage. The low dissolution rate of 20 mol% Zn-containing slips decreased the dip coating slip viscosity, whereas the lower stability of 10 mol% Zn-containing slips increased the slip viscosity. A significant increase in the initial layer thickness was produced either by using 10 mol% Zn-containing slips or by increasing the slip solid loading. The casting rate for longer immersion times was markedly accelerated by increasing the 3Y-TZP surface porosity. Sintered layers based on ZnSiO4 having the lowest thickness values were produced using the glass containing 20 mol% Zn. On the other hand, the 0 and 10 mol% Zn-containing glass produced thicker sintered layers mainly composed of Ca3Si3O9 and Ca2ZnSi2O7, respectively.
Fil: Bruni, Yesica Lorena. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas; Argentina
Fil: Albano, Maria Patricia. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas; Argentina
description Coating layers based on Ca3Si3O9, Ca2ZnSi2O7, and ZnSiO4 on 3Y-TZP ceramics were obtained by the dip coating process, using SiO2-CaO-P2O5-ZnO glass suspensions with Zn contents in the range of 0-20 mol%. The influence of the Zn content in the dip coating slips, the slip solid loading, and the 3Y-TZP surface porosity on the layer formation rate was studied. The Zn content of the dip coating slips as well as the slip solid loading greatly affected the slip viscosity, and consequently the liquid entrainment mechanism at the initial stage. The low dissolution rate of 20 mol% Zn-containing slips decreased the dip coating slip viscosity, whereas the lower stability of 10 mol% Zn-containing slips increased the slip viscosity. A significant increase in the initial layer thickness was produced either by using 10 mol% Zn-containing slips or by increasing the slip solid loading. The casting rate for longer immersion times was markedly accelerated by increasing the 3Y-TZP surface porosity. Sintered layers based on ZnSiO4 having the lowest thickness values were produced using the glass containing 20 mol% Zn. On the other hand, the 0 and 10 mol% Zn-containing glass produced thicker sintered layers mainly composed of Ca3Si3O9 and Ca2ZnSi2O7, respectively.
publishDate 2021
dc.date.none.fl_str_mv 2021-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/181288
Bruni, Yesica Lorena; Albano, Maria Patricia; 3Y-TZP dip-coated with Zn-containing calcium silicate layers: development and characterization; Associação Brasileira de Cerâmica; Ceramica; 67; 384; 10-2021; 463-470
0366-6913
1678-4553
CONICET Digital
CONICET
url http://hdl.handle.net/11336/181288
identifier_str_mv Bruni, Yesica Lorena; Albano, Maria Patricia; 3Y-TZP dip-coated with Zn-containing calcium silicate layers: development and characterization; Associação Brasileira de Cerâmica; Ceramica; 67; 384; 10-2021; 463-470
0366-6913
1678-4553
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.scielo.br/j/ce/a/KNQVygx4DCJ5bYPHmpzd9Vm/?lang=en
info:eu-repo/semantics/altIdentifier/doi/10.1590/0366-69132021673843170
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Associação Brasileira de Cerâmica
publisher.none.fl_str_mv Associação Brasileira de Cerâmica
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613922910371840
score 13.070432

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