Fractionation of fatty acid esters and acylglycerides with pressurized CO2

Autores
Cotabarren, Natalia Soledad; Hegel, Pablo Ezequiel; Pereda, Selva
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Fatty mono- and di-glycerides are products highly used in the food, cleaning and cosmetic industries because of their emulsifying properties. These products can be obtained through different synthesis routes, namely, glycerolysis of vegetable oils, direct esterification of fatty acids with glycerol or partial transesterification of vegetable oils with alcohols. The last two chemical pathways produce fatty acid esters besides mono/diglycerides, which are difficult to split and purify at industrial scale because of its low vapor pressure, low relative volatility, and high viscosity. In this work, we evaluate the fractionation of fatty acid esters and acylglycerides by supercritical CO2 technology. High pressure experimental extractions were carried out at different operating conditions to validate the technology and a rigorous thermodynamic model was used to evaluate the fractionation process.
Fil: Cotabarren, Natalia Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Hegel, Pablo Ezequiel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Pereda, Selva. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. University of KwaZulu-Natal. Howard College Campus. School of Engineering. Thermodynamics Research Unit; Sudáfrica
Materia
MONOGLYCERIDES
DIGLYCERIDES
FATTY ACID ESTERS
SUPERCRITICAL
CARBON DIOXIDE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/108253
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Fractionation of fatty acid esters and acylglycerides with pressurized CO2Cotabarren, Natalia SoledadHegel, Pablo EzequielPereda, SelvaMONOGLYCERIDESDIGLYCERIDESFATTY ACID ESTERSSUPERCRITICALCARBON DIOXIDEhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Fatty mono- and di-glycerides are products highly used in the food, cleaning and cosmetic industries because of their emulsifying properties. These products can be obtained through different synthesis routes, namely, glycerolysis of vegetable oils, direct esterification of fatty acids with glycerol or partial transesterification of vegetable oils with alcohols. The last two chemical pathways produce fatty acid esters besides mono/diglycerides, which are difficult to split and purify at industrial scale because of its low vapor pressure, low relative volatility, and high viscosity. In this work, we evaluate the fractionation of fatty acid esters and acylglycerides by supercritical CO2 technology. High pressure experimental extractions were carried out at different operating conditions to validate the technology and a rigorous thermodynamic model was used to evaluate the fractionation process.Fil: Cotabarren, Natalia Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Hegel, Pablo Ezequiel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Pereda, Selva. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. University of KwaZulu-Natal. Howard College Campus. School of Engineering. Thermodynamics Research Unit; SudáfricaPlanta Piloto de Ingeniería Química2019-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/108253Cotabarren, Natalia Soledad; Hegel, Pablo Ezequiel; Pereda, Selva; Fractionation of fatty acid esters and acylglycerides with pressurized CO2; Planta Piloto de Ingeniería Química; Latin American Applied Research; 49; 2; 8-2019; 117-1230327-07931851-8796CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://laar.plapiqui.edu.ar/OJS/index.php/laar/article/view/39info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:23:20Zoai:ri.conicet.gov.ar:11336/108253instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:23:21.214CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Fractionation of fatty acid esters and acylglycerides with pressurized CO2
title Fractionation of fatty acid esters and acylglycerides with pressurized CO2
spellingShingle Fractionation of fatty acid esters and acylglycerides with pressurized CO2
Cotabarren, Natalia Soledad
MONOGLYCERIDES
DIGLYCERIDES
FATTY ACID ESTERS
SUPERCRITICAL
CARBON DIOXIDE
title_short Fractionation of fatty acid esters and acylglycerides with pressurized CO2
title_full Fractionation of fatty acid esters and acylglycerides with pressurized CO2
title_fullStr Fractionation of fatty acid esters and acylglycerides with pressurized CO2
title_full_unstemmed Fractionation of fatty acid esters and acylglycerides with pressurized CO2
title_sort Fractionation of fatty acid esters and acylglycerides with pressurized CO2
dc.creator.none.fl_str_mv Cotabarren, Natalia Soledad
Hegel, Pablo Ezequiel
Pereda, Selva
author Cotabarren, Natalia Soledad
author_facet Cotabarren, Natalia Soledad
Hegel, Pablo Ezequiel
Pereda, Selva
author_role author
author2 Hegel, Pablo Ezequiel
Pereda, Selva
author2_role author
author
dc.subject.none.fl_str_mv MONOGLYCERIDES
DIGLYCERIDES
FATTY ACID ESTERS
SUPERCRITICAL
CARBON DIOXIDE
topic MONOGLYCERIDES
DIGLYCERIDES
FATTY ACID ESTERS
SUPERCRITICAL
CARBON DIOXIDE
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Fatty mono- and di-glycerides are products highly used in the food, cleaning and cosmetic industries because of their emulsifying properties. These products can be obtained through different synthesis routes, namely, glycerolysis of vegetable oils, direct esterification of fatty acids with glycerol or partial transesterification of vegetable oils with alcohols. The last two chemical pathways produce fatty acid esters besides mono/diglycerides, which are difficult to split and purify at industrial scale because of its low vapor pressure, low relative volatility, and high viscosity. In this work, we evaluate the fractionation of fatty acid esters and acylglycerides by supercritical CO2 technology. High pressure experimental extractions were carried out at different operating conditions to validate the technology and a rigorous thermodynamic model was used to evaluate the fractionation process.
Fil: Cotabarren, Natalia Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Hegel, Pablo Ezequiel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Pereda, Selva. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. University of KwaZulu-Natal. Howard College Campus. School of Engineering. Thermodynamics Research Unit; Sudáfrica
description Fatty mono- and di-glycerides are products highly used in the food, cleaning and cosmetic industries because of their emulsifying properties. These products can be obtained through different synthesis routes, namely, glycerolysis of vegetable oils, direct esterification of fatty acids with glycerol or partial transesterification of vegetable oils with alcohols. The last two chemical pathways produce fatty acid esters besides mono/diglycerides, which are difficult to split and purify at industrial scale because of its low vapor pressure, low relative volatility, and high viscosity. In this work, we evaluate the fractionation of fatty acid esters and acylglycerides by supercritical CO2 technology. High pressure experimental extractions were carried out at different operating conditions to validate the technology and a rigorous thermodynamic model was used to evaluate the fractionation process.
publishDate 2019
dc.date.none.fl_str_mv 2019-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/108253
Cotabarren, Natalia Soledad; Hegel, Pablo Ezequiel; Pereda, Selva; Fractionation of fatty acid esters and acylglycerides with pressurized CO2; Planta Piloto de Ingeniería Química; Latin American Applied Research; 49; 2; 8-2019; 117-123
0327-0793
1851-8796
CONICET Digital
CONICET
url http://hdl.handle.net/11336/108253
identifier_str_mv Cotabarren, Natalia Soledad; Hegel, Pablo Ezequiel; Pereda, Selva; Fractionation of fatty acid esters and acylglycerides with pressurized CO2; Planta Piloto de Ingeniería Química; Latin American Applied Research; 49; 2; 8-2019; 117-123
0327-0793
1851-8796
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://laar.plapiqui.edu.ar/OJS/index.php/laar/article/view/39
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Planta Piloto de Ingeniería Química
publisher.none.fl_str_mv Planta Piloto de Ingeniería Química
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614227781746688
score 13.070432

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