Mechanisms of fluoride release in sediments of Argentina's central region

Autores
Borgnino Bianchi, Laura Carolina; Garcia, Maria Gabriela; Bia, Gonzalo Luis; Stupar, Y. V.; Le Coustumer, Ph.; Depetris Gallino, Pedro Jose
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We analyze the sources and mechanisms that control the release of fluoride from sediments collected from two types of aquatic reservoirs in the central region of Argentina: 1) mountainous rivers draining crystalline rocks from the Sierras Pampeanas ranges, and 2) shallow aquifers in loessic sediments. The assessment was performed on the basis of experimental work and the study of chemical and mineralogical characteristics of sediments in contact with F-rich waters of the studied region. The chemical and mineralogical compositions of sediments were analyzed by ICP/OES, DRX, and SEM-EDS. Batch experiments were conducted to evaluate the kinetics of fluoride release under variable pH and ionic composition of the solution. The enhanced release of fluoride at more acidic pH, the inhibition of release in Ca-rich solutions and the positive significant linear trends between Ca2+ and fluoride concentrations suggest that the dissolution of a Ca/F-bearing phase (like fluorapatite) strongly controls the dynamics of fluoride in the early stages of water–sediment interaction, particularly under acidic conditions. Calculations revealed that the dissolution of an amount of FAp equivalent to that estimated in the studied sediments may widely account for the values measured in the leaching experiments at pH 6, whatever the dominant cation in the solution. Under such conditions, dissolution of FAp (present as coatings onto glass surfaces or as detritic grains) is likely the major primary source of fluorine in the studied sediments. Contribution from biotite may be also considered as a source in fluvial sediments. When adequate surfaces are present the released anions may partially be scavenged from the solution by adsorption at acidic pH. Increasing alkalinity in the aquatic reservoirs may then release the adsorbed fluoride through desorption or through competition with other anionic species. Comparing both mechanisms, dissolution predominates at lower pH while desorption is the main contribution under alkaline conditions.
Fil: Borgnino Bianchi, Laura Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Garcia, Maria Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Fil: Bia, Gonzalo Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Fil: Stupar, Y. V.. Universite de Bordeaux; Francia
Fil: Le Coustumer, Ph.. Universite de Bordeaux; Francia
Fil: Depetris Gallino, Pedro Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Materia
Fluorapatite
Dissolution
Desorption
Volcani Shards
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/25702
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Mechanisms of fluoride release in sediments of Argentina's central regionBorgnino Bianchi, Laura CarolinaGarcia, Maria GabrielaBia, Gonzalo LuisStupar, Y. V.Le Coustumer, Ph.Depetris Gallino, Pedro JoseFluorapatiteDissolutionDesorptionVolcani Shardshttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1We analyze the sources and mechanisms that control the release of fluoride from sediments collected from two types of aquatic reservoirs in the central region of Argentina: 1) mountainous rivers draining crystalline rocks from the Sierras Pampeanas ranges, and 2) shallow aquifers in loessic sediments. The assessment was performed on the basis of experimental work and the study of chemical and mineralogical characteristics of sediments in contact with F-rich waters of the studied region. The chemical and mineralogical compositions of sediments were analyzed by ICP/OES, DRX, and SEM-EDS. Batch experiments were conducted to evaluate the kinetics of fluoride release under variable pH and ionic composition of the solution. The enhanced release of fluoride at more acidic pH, the inhibition of release in Ca-rich solutions and the positive significant linear trends between Ca2+ and fluoride concentrations suggest that the dissolution of a Ca/F-bearing phase (like fluorapatite) strongly controls the dynamics of fluoride in the early stages of water–sediment interaction, particularly under acidic conditions. Calculations revealed that the dissolution of an amount of FAp equivalent to that estimated in the studied sediments may widely account for the values measured in the leaching experiments at pH 6, whatever the dominant cation in the solution. Under such conditions, dissolution of FAp (present as coatings onto glass surfaces or as detritic grains) is likely the major primary source of fluorine in the studied sediments. Contribution from biotite may be also considered as a source in fluvial sediments. When adequate surfaces are present the released anions may partially be scavenged from the solution by adsorption at acidic pH. Increasing alkalinity in the aquatic reservoirs may then release the adsorbed fluoride through desorption or through competition with other anionic species. Comparing both mechanisms, dissolution predominates at lower pH while desorption is the main contribution under alkaline conditions.Fil: Borgnino Bianchi, Laura Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Garcia, Maria Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaFil: Bia, Gonzalo Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaFil: Stupar, Y. V.. Universite de Bordeaux; FranciaFil: Le Coustumer, Ph.. Universite de Bordeaux; FranciaFil: Depetris Gallino, Pedro Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaElsevier Science2012-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/25702Borgnino Bianchi, Laura Carolina; Garcia, Maria Gabriela; Bia, Gonzalo Luis; Stupar, Y. V.; Le Coustumer, Ph.; et al.; Mechanisms of fluoride release in sediments of Argentina's central region; Elsevier Science; Science of the Total Environment; 443; 11-2012; 245-2550048-9697CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.scitotenv.2012.10.093info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0048969712013939info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:58:15Zoai:ri.conicet.gov.ar:11336/25702instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:58:16.073CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Mechanisms of fluoride release in sediments of Argentina's central region
title Mechanisms of fluoride release in sediments of Argentina's central region
spellingShingle Mechanisms of fluoride release in sediments of Argentina's central region
Borgnino Bianchi, Laura Carolina
Fluorapatite
Dissolution
Desorption
Volcani Shards
title_short Mechanisms of fluoride release in sediments of Argentina's central region
title_full Mechanisms of fluoride release in sediments of Argentina's central region
title_fullStr Mechanisms of fluoride release in sediments of Argentina's central region
title_full_unstemmed Mechanisms of fluoride release in sediments of Argentina's central region
title_sort Mechanisms of fluoride release in sediments of Argentina's central region
dc.creator.none.fl_str_mv Borgnino Bianchi, Laura Carolina
Garcia, Maria Gabriela
Bia, Gonzalo Luis
Stupar, Y. V.
Le Coustumer, Ph.
Depetris Gallino, Pedro Jose
author Borgnino Bianchi, Laura Carolina
author_facet Borgnino Bianchi, Laura Carolina
Garcia, Maria Gabriela
Bia, Gonzalo Luis
Stupar, Y. V.
Le Coustumer, Ph.
Depetris Gallino, Pedro Jose
author_role author
author2 Garcia, Maria Gabriela
Bia, Gonzalo Luis
Stupar, Y. V.
Le Coustumer, Ph.
Depetris Gallino, Pedro Jose
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Fluorapatite
Dissolution
Desorption
Volcani Shards
topic Fluorapatite
Dissolution
Desorption
Volcani Shards
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv We analyze the sources and mechanisms that control the release of fluoride from sediments collected from two types of aquatic reservoirs in the central region of Argentina: 1) mountainous rivers draining crystalline rocks from the Sierras Pampeanas ranges, and 2) shallow aquifers in loessic sediments. The assessment was performed on the basis of experimental work and the study of chemical and mineralogical characteristics of sediments in contact with F-rich waters of the studied region. The chemical and mineralogical compositions of sediments were analyzed by ICP/OES, DRX, and SEM-EDS. Batch experiments were conducted to evaluate the kinetics of fluoride release under variable pH and ionic composition of the solution. The enhanced release of fluoride at more acidic pH, the inhibition of release in Ca-rich solutions and the positive significant linear trends between Ca2+ and fluoride concentrations suggest that the dissolution of a Ca/F-bearing phase (like fluorapatite) strongly controls the dynamics of fluoride in the early stages of water–sediment interaction, particularly under acidic conditions. Calculations revealed that the dissolution of an amount of FAp equivalent to that estimated in the studied sediments may widely account for the values measured in the leaching experiments at pH 6, whatever the dominant cation in the solution. Under such conditions, dissolution of FAp (present as coatings onto glass surfaces or as detritic grains) is likely the major primary source of fluorine in the studied sediments. Contribution from biotite may be also considered as a source in fluvial sediments. When adequate surfaces are present the released anions may partially be scavenged from the solution by adsorption at acidic pH. Increasing alkalinity in the aquatic reservoirs may then release the adsorbed fluoride through desorption or through competition with other anionic species. Comparing both mechanisms, dissolution predominates at lower pH while desorption is the main contribution under alkaline conditions.
Fil: Borgnino Bianchi, Laura Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Garcia, Maria Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Fil: Bia, Gonzalo Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Fil: Stupar, Y. V.. Universite de Bordeaux; Francia
Fil: Le Coustumer, Ph.. Universite de Bordeaux; Francia
Fil: Depetris Gallino, Pedro Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
description We analyze the sources and mechanisms that control the release of fluoride from sediments collected from two types of aquatic reservoirs in the central region of Argentina: 1) mountainous rivers draining crystalline rocks from the Sierras Pampeanas ranges, and 2) shallow aquifers in loessic sediments. The assessment was performed on the basis of experimental work and the study of chemical and mineralogical characteristics of sediments in contact with F-rich waters of the studied region. The chemical and mineralogical compositions of sediments were analyzed by ICP/OES, DRX, and SEM-EDS. Batch experiments were conducted to evaluate the kinetics of fluoride release under variable pH and ionic composition of the solution. The enhanced release of fluoride at more acidic pH, the inhibition of release in Ca-rich solutions and the positive significant linear trends between Ca2+ and fluoride concentrations suggest that the dissolution of a Ca/F-bearing phase (like fluorapatite) strongly controls the dynamics of fluoride in the early stages of water–sediment interaction, particularly under acidic conditions. Calculations revealed that the dissolution of an amount of FAp equivalent to that estimated in the studied sediments may widely account for the values measured in the leaching experiments at pH 6, whatever the dominant cation in the solution. Under such conditions, dissolution of FAp (present as coatings onto glass surfaces or as detritic grains) is likely the major primary source of fluorine in the studied sediments. Contribution from biotite may be also considered as a source in fluvial sediments. When adequate surfaces are present the released anions may partially be scavenged from the solution by adsorption at acidic pH. Increasing alkalinity in the aquatic reservoirs may then release the adsorbed fluoride through desorption or through competition with other anionic species. Comparing both mechanisms, dissolution predominates at lower pH while desorption is the main contribution under alkaline conditions.
publishDate 2012
dc.date.none.fl_str_mv 2012-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/25702
Borgnino Bianchi, Laura Carolina; Garcia, Maria Gabriela; Bia, Gonzalo Luis; Stupar, Y. V.; Le Coustumer, Ph.; et al.; Mechanisms of fluoride release in sediments of Argentina's central region; Elsevier Science; Science of the Total Environment; 443; 11-2012; 245-255
0048-9697
CONICET Digital
CONICET
url http://hdl.handle.net/11336/25702
identifier_str_mv Borgnino Bianchi, Laura Carolina; Garcia, Maria Gabriela; Bia, Gonzalo Luis; Stupar, Y. V.; Le Coustumer, Ph.; et al.; Mechanisms of fluoride release in sediments of Argentina's central region; Elsevier Science; Science of the Total Environment; 443; 11-2012; 245-255
0048-9697
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.scitotenv.2012.10.093
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0048969712013939
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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