Unusual Magnetic Behaviors and Electronic Configurations Driven by Diverse Co(II) or Mn(II) MOF Architectures

Autores
Bernini, Maria Celeste; Romero de Paz, Julio; Snejko, Natalia; Sáez Puche, Regino; Gutierrez Puebla, Enrique; Monge, Maria Angeles
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Five novel metal organic frameworks were obtained by hydrosolvothermal reactions using the hexafluorisopropylidenebis(benzoic) acid (H2hfipbb) as linker and Co(II) or Mn(II) ions as connectors. [Co2(Hhfipbb)- (TEA)], compound 1 (TEA = triethanolamine trianion) with a threedimensional (3D) framework, and a tpu net; [Co1.5(hfipbb)2]·HN(CH2CH3)3 and [Co3(hfipbb)2]·2{HN(CH2CH3)3}, compounds 2 and 2-a, respectively, both with two-dimensional structure, sql topologies, and different layer packings. Compounds 3 and 4, having the general formula [M2(hfipbb)2]·C7H8, where M = Co (3) or Mn (4), have 3D frameworks with an sqc topology. A deep analysis of the magnetic measurements reveals different striking magnetic behaviors resulting from diverse secondary building unit and framework architectures. Compound 1 presents canted antiferromagnetic chains, compound 2 contains ferromagnetic linear trimeric clusters, and compound 3 exhibits ferromagnetic chains. For the three compounds, a 3D canted antiferromagnetic structure takes place at ∼8 K by means of weak magnetic interactions between the mentioned magnetic units. Such long-range magnetic order is precluded with the application of a high enough magnetic field. Compound 4 evidenced intrachain antiferromagnetic interactions.
Fil: Bernini, Maria Celeste. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones En Tecnología Química; Argentina. Instituto de Ciencia de Materiales de Madrid; España
Fil: Romero de Paz, Julio. Universidad Complutense de Madrid; España
Fil: Snejko, Natalia. Instituto de Ciencia de Materiales de Madrid; España
Fil: Sáez Puche, Regino. Universidad Complutense de Madrid; España
Fil: Gutierrez Puebla, Enrique. Instituto de Ciencia de Materiales de Madrid; España
Fil: Monge, Maria Angeles . Instituto de Ciencia de Materiales de Madrid; España
Materia
Mofs
Magnetism
Topology
Hexafluoroisopropylidenebis(Benzoic) Acid
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5889
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/5889
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Unusual Magnetic Behaviors and Electronic Configurations Driven by Diverse Co(II) or Mn(II) MOF ArchitecturesBernini, Maria CelesteRomero de Paz, JulioSnejko, NataliaSáez Puche, ReginoGutierrez Puebla, EnriqueMonge, Maria Angeles MofsMagnetismTopologyHexafluoroisopropylidenebis(Benzoic) Acidhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Five novel metal organic frameworks were obtained by hydrosolvothermal reactions using the hexafluorisopropylidenebis(benzoic) acid (H2hfipbb) as linker and Co(II) or Mn(II) ions as connectors. [Co2(Hhfipbb)- (TEA)], compound 1 (TEA = triethanolamine trianion) with a threedimensional (3D) framework, and a tpu net; [Co1.5(hfipbb)2]·HN(CH2CH3)3 and [Co3(hfipbb)2]·2{HN(CH2CH3)3}, compounds 2 and 2-a, respectively, both with two-dimensional structure, sql topologies, and different layer packings. Compounds 3 and 4, having the general formula [M2(hfipbb)2]·C7H8, where M = Co (3) or Mn (4), have 3D frameworks with an sqc topology. A deep analysis of the magnetic measurements reveals different striking magnetic behaviors resulting from diverse secondary building unit and framework architectures. Compound 1 presents canted antiferromagnetic chains, compound 2 contains ferromagnetic linear trimeric clusters, and compound 3 exhibits ferromagnetic chains. For the three compounds, a 3D canted antiferromagnetic structure takes place at ∼8 K by means of weak magnetic interactions between the mentioned magnetic units. Such long-range magnetic order is precluded with the application of a high enough magnetic field. Compound 4 evidenced intrachain antiferromagnetic interactions.Fil: Bernini, Maria Celeste. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones En Tecnología Química; Argentina. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Romero de Paz, Julio. Universidad Complutense de Madrid; EspañaFil: Snejko, Natalia. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Sáez Puche, Regino. Universidad Complutense de Madrid; EspañaFil: Gutierrez Puebla, Enrique. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Monge, Maria Angeles . Instituto de Ciencia de Materiales de Madrid; EspañaAmerican Chemical Society2014-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5889Bernini, Maria Celeste; Romero de Paz, Julio; Snejko, Natalia; Sáez Puche, Regino; Gutierrez Puebla, Enrique; et al.; Unusual Magnetic Behaviors and Electronic Configurations Driven by Diverse Co(II) or Mn(II) MOF Architectures; American Chemical Society; Inorganic Chemistry; 53; 24; 12-2014; 12885-128950020-1669enginfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/ic501898xinfo:eu-repo/semantics/altIdentifier/doi/10.1021/ic501898xinfo:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-12T09:48:37Zoai:ri.conicet.gov.ar:11336/5889instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-12 09:48:37.599CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Unusual Magnetic Behaviors and Electronic Configurations Driven by Diverse Co(II) or Mn(II) MOF Architectures
title Unusual Magnetic Behaviors and Electronic Configurations Driven by Diverse Co(II) or Mn(II) MOF Architectures
spellingShingle Unusual Magnetic Behaviors and Electronic Configurations Driven by Diverse Co(II) or Mn(II) MOF Architectures
Bernini, Maria Celeste
Mofs
Magnetism
Topology
Hexafluoroisopropylidenebis(Benzoic) Acid
title_short Unusual Magnetic Behaviors and Electronic Configurations Driven by Diverse Co(II) or Mn(II) MOF Architectures
title_full Unusual Magnetic Behaviors and Electronic Configurations Driven by Diverse Co(II) or Mn(II) MOF Architectures
title_fullStr Unusual Magnetic Behaviors and Electronic Configurations Driven by Diverse Co(II) or Mn(II) MOF Architectures
title_full_unstemmed Unusual Magnetic Behaviors and Electronic Configurations Driven by Diverse Co(II) or Mn(II) MOF Architectures
title_sort Unusual Magnetic Behaviors and Electronic Configurations Driven by Diverse Co(II) or Mn(II) MOF Architectures
dc.creator.none.fl_str_mv Bernini, Maria Celeste
Romero de Paz, Julio
Snejko, Natalia
Sáez Puche, Regino
Gutierrez Puebla, Enrique
Monge, Maria Angeles
author Bernini, Maria Celeste
author_facet Bernini, Maria Celeste
Romero de Paz, Julio
Snejko, Natalia
Sáez Puche, Regino
Gutierrez Puebla, Enrique
Monge, Maria Angeles
author_role author
author2 Romero de Paz, Julio
Snejko, Natalia
Sáez Puche, Regino
Gutierrez Puebla, Enrique
Monge, Maria Angeles
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Mofs
Magnetism
Topology
Hexafluoroisopropylidenebis(Benzoic) Acid
topic Mofs
Magnetism
Topology
Hexafluoroisopropylidenebis(Benzoic) Acid
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Five novel metal organic frameworks were obtained by hydrosolvothermal reactions using the hexafluorisopropylidenebis(benzoic) acid (H2hfipbb) as linker and Co(II) or Mn(II) ions as connectors. [Co2(Hhfipbb)- (TEA)], compound 1 (TEA = triethanolamine trianion) with a threedimensional (3D) framework, and a tpu net; [Co1.5(hfipbb)2]·HN(CH2CH3)3 and [Co3(hfipbb)2]·2{HN(CH2CH3)3}, compounds 2 and 2-a, respectively, both with two-dimensional structure, sql topologies, and different layer packings. Compounds 3 and 4, having the general formula [M2(hfipbb)2]·C7H8, where M = Co (3) or Mn (4), have 3D frameworks with an sqc topology. A deep analysis of the magnetic measurements reveals different striking magnetic behaviors resulting from diverse secondary building unit and framework architectures. Compound 1 presents canted antiferromagnetic chains, compound 2 contains ferromagnetic linear trimeric clusters, and compound 3 exhibits ferromagnetic chains. For the three compounds, a 3D canted antiferromagnetic structure takes place at ∼8 K by means of weak magnetic interactions between the mentioned magnetic units. Such long-range magnetic order is precluded with the application of a high enough magnetic field. Compound 4 evidenced intrachain antiferromagnetic interactions.
Fil: Bernini, Maria Celeste. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones En Tecnología Química; Argentina. Instituto de Ciencia de Materiales de Madrid; España
Fil: Romero de Paz, Julio. Universidad Complutense de Madrid; España
Fil: Snejko, Natalia. Instituto de Ciencia de Materiales de Madrid; España
Fil: Sáez Puche, Regino. Universidad Complutense de Madrid; España
Fil: Gutierrez Puebla, Enrique. Instituto de Ciencia de Materiales de Madrid; España
Fil: Monge, Maria Angeles . Instituto de Ciencia de Materiales de Madrid; España
description Five novel metal organic frameworks were obtained by hydrosolvothermal reactions using the hexafluorisopropylidenebis(benzoic) acid (H2hfipbb) as linker and Co(II) or Mn(II) ions as connectors. [Co2(Hhfipbb)- (TEA)], compound 1 (TEA = triethanolamine trianion) with a threedimensional (3D) framework, and a tpu net; [Co1.5(hfipbb)2]·HN(CH2CH3)3 and [Co3(hfipbb)2]·2{HN(CH2CH3)3}, compounds 2 and 2-a, respectively, both with two-dimensional structure, sql topologies, and different layer packings. Compounds 3 and 4, having the general formula [M2(hfipbb)2]·C7H8, where M = Co (3) or Mn (4), have 3D frameworks with an sqc topology. A deep analysis of the magnetic measurements reveals different striking magnetic behaviors resulting from diverse secondary building unit and framework architectures. Compound 1 presents canted antiferromagnetic chains, compound 2 contains ferromagnetic linear trimeric clusters, and compound 3 exhibits ferromagnetic chains. For the three compounds, a 3D canted antiferromagnetic structure takes place at ∼8 K by means of weak magnetic interactions between the mentioned magnetic units. Such long-range magnetic order is precluded with the application of a high enough magnetic field. Compound 4 evidenced intrachain antiferromagnetic interactions.
publishDate 2014
dc.date.none.fl_str_mv 2014-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5889
Bernini, Maria Celeste; Romero de Paz, Julio; Snejko, Natalia; Sáez Puche, Regino; Gutierrez Puebla, Enrique; et al.; Unusual Magnetic Behaviors and Electronic Configurations Driven by Diverse Co(II) or Mn(II) MOF Architectures; American Chemical Society; Inorganic Chemistry; 53; 24; 12-2014; 12885-12895
0020-1669
url http://hdl.handle.net/11336/5889
identifier_str_mv Bernini, Maria Celeste; Romero de Paz, Julio; Snejko, Natalia; Sáez Puche, Regino; Gutierrez Puebla, Enrique; et al.; Unusual Magnetic Behaviors and Electronic Configurations Driven by Diverse Co(II) or Mn(II) MOF Architectures; American Chemical Society; Inorganic Chemistry; 53; 24; 12-2014; 12885-12895
0020-1669
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/ic501898x
info:eu-repo/semantics/altIdentifier/doi/10.1021/ic501898x
info:eu-repo/semantics/altIdentifier/doi/
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.223955

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