Synthesis and characterization of a novel tungstosilicic acid immobilized on zeolites catalyst for the photodegradation of methyl orange

Autores
Leal Marchena, Candelaria; Lerici, Laura Carolina; Renzini, Maria Soledad; Pizzio, Luis Rene; Pierella, Liliana Beatriz
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Materials based on tungstosilicic acid (TSA) immobilized on zeolites (NH4Y and NH4ZSM5) were prepared by wet impregnation of the zeolite matrix with TSA aqueous solutions. The concentration was varied in order to obtain TSA contents of 5%, 10%, 20%, and 30% w/w in the solid. Catalysts were further characterized by N2 adsorption–desorption isotherms, FT-IR, XRD, DRS-UV–vis and SEM techniques. The resulting materials were evaluated in the photodecomposition of azo dye methyl orange. The results revealed that the materials present suitable properties to be used as catalysts in the photocatalytic treatment of wastewater containing dyes, and the photodegradation follows a pseudo-first-order kinetics. Reaction parameters such as TSA content, catalysts mass, reuses and pH, were evaluated.
Fil: Leal Marchena, Candelaria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Lerici, Laura Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Renzini, Maria Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Pierella, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Materia
Photocatalysis
Zeolites
Tungstosilicic Acid
Azoic Dye
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31972
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/31972
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synthesis and characterization of a novel tungstosilicic acid immobilized on zeolites catalyst for the photodegradation of methyl orangeLeal Marchena, CandelariaLerici, Laura CarolinaRenzini, Maria SoledadPizzio, Luis RenePierella, Liliana BeatrizPhotocatalysisZeolitesTungstosilicic AcidAzoic Dyehttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Materials based on tungstosilicic acid (TSA) immobilized on zeolites (NH4Y and NH4ZSM5) were prepared by wet impregnation of the zeolite matrix with TSA aqueous solutions. The concentration was varied in order to obtain TSA contents of 5%, 10%, 20%, and 30% w/w in the solid. Catalysts were further characterized by N2 adsorption–desorption isotherms, FT-IR, XRD, DRS-UV–vis and SEM techniques. The resulting materials were evaluated in the photodecomposition of azo dye methyl orange. The results revealed that the materials present suitable properties to be used as catalysts in the photocatalytic treatment of wastewater containing dyes, and the photodegradation follows a pseudo-first-order kinetics. Reaction parameters such as TSA content, catalysts mass, reuses and pH, were evaluated.Fil: Leal Marchena, Candelaria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Lerici, Laura Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Renzini, Maria Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Pierella, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaElsevier Science2016-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31972Pierella, Liliana Beatriz; Pizzio, Luis Rene; Renzini, Maria Soledad; Lerici, Laura Carolina; Leal Marchena, Candelaria; Synthesis and characterization of a novel tungstosilicic acid immobilized on zeolites catalyst for the photodegradation of methyl orange; Elsevier Science; Applied Catalysis B: Environmental; 188; 7-2016; 23-300926-3373CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2016.01.064info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0926337316300716info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:45:59Zoai:ri.conicet.gov.ar:11336/31972instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:45:59.918CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and characterization of a novel tungstosilicic acid immobilized on zeolites catalyst for the photodegradation of methyl orange
title Synthesis and characterization of a novel tungstosilicic acid immobilized on zeolites catalyst for the photodegradation of methyl orange
spellingShingle Synthesis and characterization of a novel tungstosilicic acid immobilized on zeolites catalyst for the photodegradation of methyl orange
Leal Marchena, Candelaria
Photocatalysis
Zeolites
Tungstosilicic Acid
Azoic Dye
title_short Synthesis and characterization of a novel tungstosilicic acid immobilized on zeolites catalyst for the photodegradation of methyl orange
title_full Synthesis and characterization of a novel tungstosilicic acid immobilized on zeolites catalyst for the photodegradation of methyl orange
title_fullStr Synthesis and characterization of a novel tungstosilicic acid immobilized on zeolites catalyst for the photodegradation of methyl orange
title_full_unstemmed Synthesis and characterization of a novel tungstosilicic acid immobilized on zeolites catalyst for the photodegradation of methyl orange
title_sort Synthesis and characterization of a novel tungstosilicic acid immobilized on zeolites catalyst for the photodegradation of methyl orange
dc.creator.none.fl_str_mv Leal Marchena, Candelaria
Lerici, Laura Carolina
Renzini, Maria Soledad
Pizzio, Luis Rene
Pierella, Liliana Beatriz
author Leal Marchena, Candelaria
author_facet Leal Marchena, Candelaria
Lerici, Laura Carolina
Renzini, Maria Soledad
Pizzio, Luis Rene
Pierella, Liliana Beatriz
author_role author
author2 Lerici, Laura Carolina
Renzini, Maria Soledad
Pizzio, Luis Rene
Pierella, Liliana Beatriz
author2_role author
author
author
author
dc.subject.none.fl_str_mv Photocatalysis
Zeolites
Tungstosilicic Acid
Azoic Dye
topic Photocatalysis
Zeolites
Tungstosilicic Acid
Azoic Dye
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Materials based on tungstosilicic acid (TSA) immobilized on zeolites (NH4Y and NH4ZSM5) were prepared by wet impregnation of the zeolite matrix with TSA aqueous solutions. The concentration was varied in order to obtain TSA contents of 5%, 10%, 20%, and 30% w/w in the solid. Catalysts were further characterized by N2 adsorption–desorption isotherms, FT-IR, XRD, DRS-UV–vis and SEM techniques. The resulting materials were evaluated in the photodecomposition of azo dye methyl orange. The results revealed that the materials present suitable properties to be used as catalysts in the photocatalytic treatment of wastewater containing dyes, and the photodegradation follows a pseudo-first-order kinetics. Reaction parameters such as TSA content, catalysts mass, reuses and pH, were evaluated.
Fil: Leal Marchena, Candelaria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Lerici, Laura Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Renzini, Maria Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Pierella, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
description Materials based on tungstosilicic acid (TSA) immobilized on zeolites (NH4Y and NH4ZSM5) were prepared by wet impregnation of the zeolite matrix with TSA aqueous solutions. The concentration was varied in order to obtain TSA contents of 5%, 10%, 20%, and 30% w/w in the solid. Catalysts were further characterized by N2 adsorption–desorption isotherms, FT-IR, XRD, DRS-UV–vis and SEM techniques. The resulting materials were evaluated in the photodecomposition of azo dye methyl orange. The results revealed that the materials present suitable properties to be used as catalysts in the photocatalytic treatment of wastewater containing dyes, and the photodegradation follows a pseudo-first-order kinetics. Reaction parameters such as TSA content, catalysts mass, reuses and pH, were evaluated.
publishDate 2016
dc.date.none.fl_str_mv 2016-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31972
Pierella, Liliana Beatriz; Pizzio, Luis Rene; Renzini, Maria Soledad; Lerici, Laura Carolina; Leal Marchena, Candelaria; Synthesis and characterization of a novel tungstosilicic acid immobilized on zeolites catalyst for the photodegradation of methyl orange; Elsevier Science; Applied Catalysis B: Environmental; 188; 7-2016; 23-30
0926-3373
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31972
identifier_str_mv Pierella, Liliana Beatriz; Pizzio, Luis Rene; Renzini, Maria Soledad; Lerici, Laura Carolina; Leal Marchena, Candelaria; Synthesis and characterization of a novel tungstosilicic acid immobilized on zeolites catalyst for the photodegradation of methyl orange; Elsevier Science; Applied Catalysis B: Environmental; 188; 7-2016; 23-30
0926-3373
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2016.01.064
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0926337316300716
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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