TiO 2 Supported on HZSM-11 Zeolite as Efficient Catalyst for the Photodegradation of Chlorobenzoic Acids

Autores
Montañez, Juan Paulo; Gómez, Silvina del Valle; Santiago, Ana Noemi; Pierella, Liliana Beatriz
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The photocatalytic decomposition of 2-, 3- and 4-chlorobenzoic acids (2CB, 3CB and 4CB, respectively) with TiO2 loaded on HZSM-11 zeolite was investigated. The optimum decomposition rate of 2CB was obtained with TiO2/HZSM-11(30%) (TiO2 30 wt.%) catalyst at a concentration of 1 mg mL-1. 2CB and 3CB decompose at similar rates, but 4CB remains adsorbed on TiO2/HZSM-11(30%) without further degradation. This absorption is attributed to the relative positions of Cl and COOH groups on 4CB. However, this compound can be partially degraded and/or removed from aqueous solutions by TiO2/HZSM-11(50%) catalyst or HZSM-11 zeolite. TiO2/HZSM-11(30%) is stable; it retains its photocatalytic properties after nine cycles, can be easily removed and immediately reused. These are important advantages of TiO2/HZSM-11(30%) over unsupported TiO2, making it a good photocatalyst for the treatment of polluted water. On the other hand, HZSM-11 could be used to selectively adsorb 4CB, thus becoming an alternative method of environmental remediation.
Fil: Montañez, Juan Paulo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Gómez, Silvina del Valle. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Santiago, Ana Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Pierella, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Materia
Aromatic acids
Heterogeneous photocatalysis
Supported catalysts
TiO2
Zeolite
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/44004
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/44004
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling TiO 2 Supported on HZSM-11 Zeolite as Efficient Catalyst for the Photodegradation of Chlorobenzoic AcidsMontañez, Juan PauloGómez, Silvina del ValleSantiago, Ana NoemiPierella, Liliana BeatrizAromatic acidsHeterogeneous photocatalysisSupported catalystsTiO2Zeolitehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The photocatalytic decomposition of 2-, 3- and 4-chlorobenzoic acids (2CB, 3CB and 4CB, respectively) with TiO2 loaded on HZSM-11 zeolite was investigated. The optimum decomposition rate of 2CB was obtained with TiO2/HZSM-11(30%) (TiO2 30 wt.%) catalyst at a concentration of 1 mg mL-1. 2CB and 3CB decompose at similar rates, but 4CB remains adsorbed on TiO2/HZSM-11(30%) without further degradation. This absorption is attributed to the relative positions of Cl and COOH groups on 4CB. However, this compound can be partially degraded and/or removed from aqueous solutions by TiO2/HZSM-11(50%) catalyst or HZSM-11 zeolite. TiO2/HZSM-11(30%) is stable; it retains its photocatalytic properties after nine cycles, can be easily removed and immediately reused. These are important advantages of TiO2/HZSM-11(30%) over unsupported TiO2, making it a good photocatalyst for the treatment of polluted water. On the other hand, HZSM-11 could be used to selectively adsorb 4CB, thus becoming an alternative method of environmental remediation.Fil: Montañez, Juan Paulo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Gómez, Silvina del Valle. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaFil: Santiago, Ana Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Pierella, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; ArgentinaSociedade Brasileira de Química2015-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/44004Montañez, Juan Paulo; Gómez, Silvina del Valle; Santiago, Ana Noemi; Pierella, Liliana Beatriz; TiO 2 Supported on HZSM-11 Zeolite as Efficient Catalyst for the Photodegradation of Chlorobenzoic Acids; Sociedade Brasileira de Química; Journal of the Brazilian Chemical Society; 26; 6; 6-2015; 1191-12001678-47900103-5053CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.5935/0103-5053.20150083info:eu-repo/semantics/altIdentifier/url/https://www.crossref.org/iPage?doi=10.5935%2F0103-5053.20150083info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:09:31Zoai:ri.conicet.gov.ar:11336/44004instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:09:32.124CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv TiO 2 Supported on HZSM-11 Zeolite as Efficient Catalyst for the Photodegradation of Chlorobenzoic Acids
title TiO 2 Supported on HZSM-11 Zeolite as Efficient Catalyst for the Photodegradation of Chlorobenzoic Acids
spellingShingle TiO 2 Supported on HZSM-11 Zeolite as Efficient Catalyst for the Photodegradation of Chlorobenzoic Acids
Montañez, Juan Paulo
Aromatic acids
Heterogeneous photocatalysis
Supported catalysts
TiO2
Zeolite
title_short TiO 2 Supported on HZSM-11 Zeolite as Efficient Catalyst for the Photodegradation of Chlorobenzoic Acids
title_full TiO 2 Supported on HZSM-11 Zeolite as Efficient Catalyst for the Photodegradation of Chlorobenzoic Acids
title_fullStr TiO 2 Supported on HZSM-11 Zeolite as Efficient Catalyst for the Photodegradation of Chlorobenzoic Acids
title_full_unstemmed TiO 2 Supported on HZSM-11 Zeolite as Efficient Catalyst for the Photodegradation of Chlorobenzoic Acids
title_sort TiO 2 Supported on HZSM-11 Zeolite as Efficient Catalyst for the Photodegradation of Chlorobenzoic Acids
dc.creator.none.fl_str_mv Montañez, Juan Paulo
Gómez, Silvina del Valle
Santiago, Ana Noemi
Pierella, Liliana Beatriz
author Montañez, Juan Paulo
author_facet Montañez, Juan Paulo
Gómez, Silvina del Valle
Santiago, Ana Noemi
Pierella, Liliana Beatriz
author_role author
author2 Gómez, Silvina del Valle
Santiago, Ana Noemi
Pierella, Liliana Beatriz
author2_role author
author
author
dc.subject.none.fl_str_mv Aromatic acids
Heterogeneous photocatalysis
Supported catalysts
TiO2
Zeolite
topic Aromatic acids
Heterogeneous photocatalysis
Supported catalysts
TiO2
Zeolite
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The photocatalytic decomposition of 2-, 3- and 4-chlorobenzoic acids (2CB, 3CB and 4CB, respectively) with TiO2 loaded on HZSM-11 zeolite was investigated. The optimum decomposition rate of 2CB was obtained with TiO2/HZSM-11(30%) (TiO2 30 wt.%) catalyst at a concentration of 1 mg mL-1. 2CB and 3CB decompose at similar rates, but 4CB remains adsorbed on TiO2/HZSM-11(30%) without further degradation. This absorption is attributed to the relative positions of Cl and COOH groups on 4CB. However, this compound can be partially degraded and/or removed from aqueous solutions by TiO2/HZSM-11(50%) catalyst or HZSM-11 zeolite. TiO2/HZSM-11(30%) is stable; it retains its photocatalytic properties after nine cycles, can be easily removed and immediately reused. These are important advantages of TiO2/HZSM-11(30%) over unsupported TiO2, making it a good photocatalyst for the treatment of polluted water. On the other hand, HZSM-11 could be used to selectively adsorb 4CB, thus becoming an alternative method of environmental remediation.
Fil: Montañez, Juan Paulo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Gómez, Silvina del Valle. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
Fil: Santiago, Ana Noemi. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Pierella, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina
description The photocatalytic decomposition of 2-, 3- and 4-chlorobenzoic acids (2CB, 3CB and 4CB, respectively) with TiO2 loaded on HZSM-11 zeolite was investigated. The optimum decomposition rate of 2CB was obtained with TiO2/HZSM-11(30%) (TiO2 30 wt.%) catalyst at a concentration of 1 mg mL-1. 2CB and 3CB decompose at similar rates, but 4CB remains adsorbed on TiO2/HZSM-11(30%) without further degradation. This absorption is attributed to the relative positions of Cl and COOH groups on 4CB. However, this compound can be partially degraded and/or removed from aqueous solutions by TiO2/HZSM-11(50%) catalyst or HZSM-11 zeolite. TiO2/HZSM-11(30%) is stable; it retains its photocatalytic properties after nine cycles, can be easily removed and immediately reused. These are important advantages of TiO2/HZSM-11(30%) over unsupported TiO2, making it a good photocatalyst for the treatment of polluted water. On the other hand, HZSM-11 could be used to selectively adsorb 4CB, thus becoming an alternative method of environmental remediation.
publishDate 2015
dc.date.none.fl_str_mv 2015-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/44004
Montañez, Juan Paulo; Gómez, Silvina del Valle; Santiago, Ana Noemi; Pierella, Liliana Beatriz; TiO 2 Supported on HZSM-11 Zeolite as Efficient Catalyst for the Photodegradation of Chlorobenzoic Acids; Sociedade Brasileira de Química; Journal of the Brazilian Chemical Society; 26; 6; 6-2015; 1191-1200
1678-4790
0103-5053
CONICET Digital
CONICET
url http://hdl.handle.net/11336/44004
identifier_str_mv Montañez, Juan Paulo; Gómez, Silvina del Valle; Santiago, Ana Noemi; Pierella, Liliana Beatriz; TiO 2 Supported on HZSM-11 Zeolite as Efficient Catalyst for the Photodegradation of Chlorobenzoic Acids; Sociedade Brasileira de Química; Journal of the Brazilian Chemical Society; 26; 6; 6-2015; 1191-1200
1678-4790
0103-5053
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.5935/0103-5053.20150083
info:eu-repo/semantics/altIdentifier/url/https://www.crossref.org/iPage?doi=10.5935%2F0103-5053.20150083
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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