Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate

Autores
Perec, M.; Baggio, R.; Garland, M.T.
Año de publicación
1999
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The crystal structure of the title complex, [Ni(C3H4N2)6](C4H 4O5)·C2H5OH, is a tightly woven three-dimensional network composed of [Ni(Him)6]2+ cations (Him is imidazole) interlinked by the oxydiacetate anion through six different N-H⋯O bonds, in which all the N-H imidazole groups, as well as all the carboxylate O atoms, take part. This structure is the first to show an [Ni(Him)6]2+ group which does not display any crystallographic symmetry. © 1999 International Union of Crystallography.
Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Baggio, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fuente
Acta Crystallogr Sect C Cryst Struct Commun 1999;55(6):858-860
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/2.5/ar
Repositorio
Biblioteca Digital (UBA-FCEN)
Institución
Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
OAI Identificador
paperaa:paper_01082701_v55_n6_p858_Perec

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network_name_str Biblioteca Digital (UBA-FCEN)
spelling Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvatePerec, M.Baggio, R.Garland, M.T.The crystal structure of the title complex, [Ni(C3H4N2)6](C4H 4O5)·C2H5OH, is a tightly woven three-dimensional network composed of [Ni(Him)6]2+ cations (Him is imidazole) interlinked by the oxydiacetate anion through six different N-H⋯O bonds, in which all the N-H imidazole groups, as well as all the carboxylate O atoms, take part. This structure is the first to show an [Ni(Him)6]2+ group which does not display any crystallographic symmetry. © 1999 International Union of Crystallography.Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.Fil:Baggio, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.1999info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12110/paper_01082701_v55_n6_p858_PerecActa Crystallogr Sect C Cryst Struct Commun 1999;55(6):858-860reponame:Biblioteca Digital (UBA-FCEN)instname:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturalesinstacron:UBA-FCENenginfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/2.5/ar2025-10-16T09:30:01Zpaperaa:paper_01082701_v55_n6_p858_PerecInstitucionalhttps://digital.bl.fcen.uba.ar/Universidad públicaNo correspondehttps://digital.bl.fcen.uba.ar/cgi-bin/oaiserver.cgiana@bl.fcen.uba.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:18962025-10-16 09:30:02.746Biblioteca Digital (UBA-FCEN) - Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturalesfalse
dc.title.none.fl_str_mv Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
title Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
spellingShingle Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
Perec, M.
title_short Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
title_full Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
title_fullStr Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
title_full_unstemmed Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
title_sort Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
dc.creator.none.fl_str_mv Perec, M.
Baggio, R.
Garland, M.T.
author Perec, M.
author_facet Perec, M.
Baggio, R.
Garland, M.T.
author_role author
author2 Baggio, R.
Garland, M.T.
author2_role author
author
dc.description.none.fl_txt_mv The crystal structure of the title complex, [Ni(C3H4N2)6](C4H 4O5)·C2H5OH, is a tightly woven three-dimensional network composed of [Ni(Him)6]2+ cations (Him is imidazole) interlinked by the oxydiacetate anion through six different N-H⋯O bonds, in which all the N-H imidazole groups, as well as all the carboxylate O atoms, take part. This structure is the first to show an [Ni(Him)6]2+ group which does not display any crystallographic symmetry. © 1999 International Union of Crystallography.
Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Baggio, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
description The crystal structure of the title complex, [Ni(C3H4N2)6](C4H 4O5)·C2H5OH, is a tightly woven three-dimensional network composed of [Ni(Him)6]2+ cations (Him is imidazole) interlinked by the oxydiacetate anion through six different N-H⋯O bonds, in which all the N-H imidazole groups, as well as all the carboxylate O atoms, take part. This structure is the first to show an [Ni(Him)6]2+ group which does not display any crystallographic symmetry. © 1999 International Union of Crystallography.
publishDate 1999
dc.date.none.fl_str_mv 1999
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12110/paper_01082701_v55_n6_p858_Perec
url http://hdl.handle.net/20.500.12110/paper_01082701_v55_n6_p858_Perec
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/2.5/ar
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/2.5/ar
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv Acta Crystallogr Sect C Cryst Struct Commun 1999;55(6):858-860
reponame:Biblioteca Digital (UBA-FCEN)
instname:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
instacron:UBA-FCEN
reponame_str Biblioteca Digital (UBA-FCEN)
collection Biblioteca Digital (UBA-FCEN)
instname_str Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
instacron_str UBA-FCEN
institution UBA-FCEN
repository.name.fl_str_mv Biblioteca Digital (UBA-FCEN) - Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
repository.mail.fl_str_mv ana@bl.fcen.uba.ar
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