A pyrazine bis-adduct of a binuclear rhodium(II) carboxylate containing 3,4,5-triethoxybenzoate as the equatorial ligand

Autores
Castro, M.A.; Chaia, Z.D.; Piro, O.E.; Cukiernik, F.D.; Castellano, E.E.; Rusjan, M.
Año de publicación
2002
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The title compound, tetrakis(μ-3,4,5-triethoxybenzoato κ 2 O:O′)bis[(pyrazine-κN)rhodium(II)](Rh-Rh). [Rh 2 (C 13 -H 17 O 5 ) 4 (C 4 H 4 N 2 ) 2 ], crystallizes on an inversion centre in the triclinic space group P1̄. The equatorial carboxylate ligands bridge the two Rh 11 atoms, giving a binuclear lantern-like structure. The pyrazine molecules occupy the two axial coordination sites. The phenyl rings are titled by ca 10° with respect to the attached carboxylate groups. The pyrazine planes have a torsion angle of ca 19° around the Rh-N bond with respect to the plane of the nearer carboxylate group and are not coplanar with the Rh-Rh bond.
Fil:Castro, M.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Chaia, Z.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Cukiernik, F.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Rusjan, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fuente
Acta Crystallogr Sect C Cryst Struct Commun 2002;58(7):m393-m395
Materia
Carboxylic acids
Chemical bonds
Conformations
Crystal structure
Crystallization
Molecular structure
Binuclear rhodium carboxylate
Equatorial ligand
Pyrazine
Triethoxybenzoate
Rhodium compounds
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/2.5/ar
Repositorio
Biblioteca Digital (UBA-FCEN)
Institución
Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
OAI Identificador
paperaa:paper_01082701_v58_n7_pm393_Castro
Acceder
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oai_identifier_str paperaa:paper_01082701_v58_n7_pm393_Castro
network_acronym_str BDUBAFCEN
repository_id_str 1896
network_name_str Biblioteca Digital (UBA-FCEN)
spelling A pyrazine bis-adduct of a binuclear rhodium(II) carboxylate containing 3,4,5-triethoxybenzoate as the equatorial ligandCastro, M.A.Chaia, Z.D.Piro, O.E.Cukiernik, F.D.Castellano, E.E.Rusjan, M.Carboxylic acidsChemical bondsConformationsCrystal structureCrystallizationMolecular structureBinuclear rhodium carboxylateEquatorial ligandPyrazineTriethoxybenzoateRhodium compoundsThe title compound, tetrakis(μ-3,4,5-triethoxybenzoato κ 2 O:O′)bis[(pyrazine-κN)rhodium(II)](Rh-Rh). [Rh 2 (C 13 -H 17 O 5 ) 4 (C 4 H 4 N 2 ) 2 ], crystallizes on an inversion centre in the triclinic space group P1̄. The equatorial carboxylate ligands bridge the two Rh 11 atoms, giving a binuclear lantern-like structure. The pyrazine molecules occupy the two axial coordination sites. The phenyl rings are titled by ca 10° with respect to the attached carboxylate groups. The pyrazine planes have a torsion angle of ca 19° around the Rh-N bond with respect to the plane of the nearer carboxylate group and are not coplanar with the Rh-Rh bond.Fil:Castro, M.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.Fil:Chaia, Z.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.Fil:Cukiernik, F.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.Fil:Rusjan, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.2002info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12110/paper_01082701_v58_n7_pm393_CastroActa Crystallogr Sect C Cryst Struct Commun 2002;58(7):m393-m395reponame:Biblioteca Digital (UBA-FCEN)instname:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturalesinstacron:UBA-FCENenginfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/2.5/ar2025-10-23T11:18:25Zpaperaa:paper_01082701_v58_n7_pm393_CastroInstitucionalhttps://digital.bl.fcen.uba.ar/Universidad públicaNo correspondehttps://digital.bl.fcen.uba.ar/cgi-bin/oaiserver.cgiana@bl.fcen.uba.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:18962025-10-23 11:18:26.855Biblioteca Digital (UBA-FCEN) - Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturalesfalse
dc.title.none.fl_str_mv A pyrazine bis-adduct of a binuclear rhodium(II) carboxylate containing 3,4,5-triethoxybenzoate as the equatorial ligand
title A pyrazine bis-adduct of a binuclear rhodium(II) carboxylate containing 3,4,5-triethoxybenzoate as the equatorial ligand
spellingShingle A pyrazine bis-adduct of a binuclear rhodium(II) carboxylate containing 3,4,5-triethoxybenzoate as the equatorial ligand
Castro, M.A.
Carboxylic acids
Chemical bonds
Conformations
Crystal structure
Crystallization
Molecular structure
Binuclear rhodium carboxylate
Equatorial ligand
Pyrazine
Triethoxybenzoate
Rhodium compounds
title_short A pyrazine bis-adduct of a binuclear rhodium(II) carboxylate containing 3,4,5-triethoxybenzoate as the equatorial ligand
title_full A pyrazine bis-adduct of a binuclear rhodium(II) carboxylate containing 3,4,5-triethoxybenzoate as the equatorial ligand
title_fullStr A pyrazine bis-adduct of a binuclear rhodium(II) carboxylate containing 3,4,5-triethoxybenzoate as the equatorial ligand
title_full_unstemmed A pyrazine bis-adduct of a binuclear rhodium(II) carboxylate containing 3,4,5-triethoxybenzoate as the equatorial ligand
title_sort A pyrazine bis-adduct of a binuclear rhodium(II) carboxylate containing 3,4,5-triethoxybenzoate as the equatorial ligand
dc.creator.none.fl_str_mv Castro, M.A.
Chaia, Z.D.
Piro, O.E.
Cukiernik, F.D.
Castellano, E.E.
Rusjan, M.
author Castro, M.A.
author_facet Castro, M.A.
Chaia, Z.D.
Piro, O.E.
Cukiernik, F.D.
Castellano, E.E.
Rusjan, M.
author_role author
author2 Chaia, Z.D.
Piro, O.E.
Cukiernik, F.D.
Castellano, E.E.
Rusjan, M.
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Carboxylic acids
Chemical bonds
Conformations
Crystal structure
Crystallization
Molecular structure
Binuclear rhodium carboxylate
Equatorial ligand
Pyrazine
Triethoxybenzoate
Rhodium compounds
topic Carboxylic acids
Chemical bonds
Conformations
Crystal structure
Crystallization
Molecular structure
Binuclear rhodium carboxylate
Equatorial ligand
Pyrazine
Triethoxybenzoate
Rhodium compounds
dc.description.none.fl_txt_mv The title compound, tetrakis(μ-3,4,5-triethoxybenzoato κ 2 O:O′)bis[(pyrazine-κN)rhodium(II)](Rh-Rh). [Rh 2 (C 13 -H 17 O 5 ) 4 (C 4 H 4 N 2 ) 2 ], crystallizes on an inversion centre in the triclinic space group P1̄. The equatorial carboxylate ligands bridge the two Rh 11 atoms, giving a binuclear lantern-like structure. The pyrazine molecules occupy the two axial coordination sites. The phenyl rings are titled by ca 10° with respect to the attached carboxylate groups. The pyrazine planes have a torsion angle of ca 19° around the Rh-N bond with respect to the plane of the nearer carboxylate group and are not coplanar with the Rh-Rh bond.
Fil:Castro, M.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Chaia, Z.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Cukiernik, F.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Rusjan, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
description The title compound, tetrakis(μ-3,4,5-triethoxybenzoato κ 2 O:O′)bis[(pyrazine-κN)rhodium(II)](Rh-Rh). [Rh 2 (C 13 -H 17 O 5 ) 4 (C 4 H 4 N 2 ) 2 ], crystallizes on an inversion centre in the triclinic space group P1̄. The equatorial carboxylate ligands bridge the two Rh 11 atoms, giving a binuclear lantern-like structure. The pyrazine molecules occupy the two axial coordination sites. The phenyl rings are titled by ca 10° with respect to the attached carboxylate groups. The pyrazine planes have a torsion angle of ca 19° around the Rh-N bond with respect to the plane of the nearer carboxylate group and are not coplanar with the Rh-Rh bond.
publishDate 2002
dc.date.none.fl_str_mv 2002
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12110/paper_01082701_v58_n7_pm393_Castro
url http://hdl.handle.net/20.500.12110/paper_01082701_v58_n7_pm393_Castro
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/2.5/ar
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/2.5/ar
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv Acta Crystallogr Sect C Cryst Struct Commun 2002;58(7):m393-m395
reponame:Biblioteca Digital (UBA-FCEN)
instname:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
instacron:UBA-FCEN
reponame_str Biblioteca Digital (UBA-FCEN)
collection Biblioteca Digital (UBA-FCEN)
instname_str Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
instacron_str UBA-FCEN
institution UBA-FCEN
repository.name.fl_str_mv Biblioteca Digital (UBA-FCEN) - Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
repository.mail.fl_str_mv ana@bl.fcen.uba.ar
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score 12.982451

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