Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate

Autores
Baggio, R.; Perec, M.; Garland, M.T.
Año de publicación
1996
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The title complex, aqua(2,2′-bipyridy-N,N′(3-thiapentanedioate-O,S,O′)zinc(II) tetrahydrate, [Zn(C4H4-O4S)(C10H8N 2)(H2O)].4H2O, is mononuclear with a coordination sphere consisting of one S, two N and three O atoms. The Zn atom is linked to a tridentate thiodiacetate ligand, a bidentate 2,2′-bipyridine ligand and an aqua ligand resulting in a slightly distorted octahedral coordination geometry. The molecular units are linked together in the crystal by an extensive hydrogen-bonding network and by intermolecular S⋯S interactions.
Fil:Baggio, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fuente
Acta Crystallogr Sect C Cryst Struct Commun 1996;52(10):2457-2460
Materia
Crystal atomic structure
Crystal defects
Crystallography
Hydrogen bonds
Molecular structure
Zinc compounds
Aqua ligands
Octahedral coordination geometry
Tridentate thiodiacetate ligand
Organometallics
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/2.5/ar
Repositorio
Biblioteca Digital (UBA-FCEN)
Institución
Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
OAI Identificador
paperaa:paper_01082701_v52_n10_p2457_Baggio
Acceder
id BDUBAFCEN_012fa019679ec3a7988ae3ac93936252
oai_identifier_str paperaa:paper_01082701_v52_n10_p2457_Baggio
network_acronym_str BDUBAFCEN
repository_id_str 1896
network_name_str Biblioteca Digital (UBA-FCEN)
spelling Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrateBaggio, R.Perec, M.Garland, M.T.Crystal atomic structureCrystal defectsCrystallographyHydrogen bondsMolecular structureZinc compoundsAqua ligandsOctahedral coordination geometryTridentate thiodiacetate ligandOrganometallicsThe title complex, aqua(2,2′-bipyridy-N,N′(3-thiapentanedioate-O,S,O′)zinc(II) tetrahydrate, [Zn(C4H4-O4S)(C10H8N 2)(H2O)].4H2O, is mononuclear with a coordination sphere consisting of one S, two N and three O atoms. The Zn atom is linked to a tridentate thiodiacetate ligand, a bidentate 2,2′-bipyridine ligand and an aqua ligand resulting in a slightly distorted octahedral coordination geometry. The molecular units are linked together in the crystal by an extensive hydrogen-bonding network and by intermolecular S⋯S interactions.Fil:Baggio, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.1996info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12110/paper_01082701_v52_n10_p2457_BaggioActa Crystallogr Sect C Cryst Struct Commun 1996;52(10):2457-2460reponame:Biblioteca Digital (UBA-FCEN)instname:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturalesinstacron:UBA-FCENenginfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/2.5/ar2025-11-06T09:39:54Zpaperaa:paper_01082701_v52_n10_p2457_BaggioInstitucionalhttps://digital.bl.fcen.uba.ar/Universidad públicaNo correspondehttps://digital.bl.fcen.uba.ar/cgi-bin/oaiserver.cgiana@bl.fcen.uba.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:18962025-11-06 09:39:56.242Biblioteca Digital (UBA-FCEN) - Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturalesfalse
dc.title.none.fl_str_mv Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate
title Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate
spellingShingle Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate
Baggio, R.
Crystal atomic structure
Crystal defects
Crystallography
Hydrogen bonds
Molecular structure
Zinc compounds
Aqua ligands
Octahedral coordination geometry
Tridentate thiodiacetate ligand
Organometallics
title_short Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate
title_full Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate
title_fullStr Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate
title_full_unstemmed Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate
title_sort Aqua(2,2′-bipyridyl-N,N′)(thiodiacetato-0,0′,S)zinc(II) tetrahydrate
dc.creator.none.fl_str_mv Baggio, R.
Perec, M.
Garland, M.T.
author Baggio, R.
author_facet Baggio, R.
Perec, M.
Garland, M.T.
author_role author
author2 Perec, M.
Garland, M.T.
author2_role author
author
dc.subject.none.fl_str_mv Crystal atomic structure
Crystal defects
Crystallography
Hydrogen bonds
Molecular structure
Zinc compounds
Aqua ligands
Octahedral coordination geometry
Tridentate thiodiacetate ligand
Organometallics
topic Crystal atomic structure
Crystal defects
Crystallography
Hydrogen bonds
Molecular structure
Zinc compounds
Aqua ligands
Octahedral coordination geometry
Tridentate thiodiacetate ligand
Organometallics
dc.description.none.fl_txt_mv The title complex, aqua(2,2′-bipyridy-N,N′(3-thiapentanedioate-O,S,O′)zinc(II) tetrahydrate, [Zn(C4H4-O4S)(C10H8N 2)(H2O)].4H2O, is mononuclear with a coordination sphere consisting of one S, two N and three O atoms. The Zn atom is linked to a tridentate thiodiacetate ligand, a bidentate 2,2′-bipyridine ligand and an aqua ligand resulting in a slightly distorted octahedral coordination geometry. The molecular units are linked together in the crystal by an extensive hydrogen-bonding network and by intermolecular S⋯S interactions.
Fil:Baggio, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
description The title complex, aqua(2,2′-bipyridy-N,N′(3-thiapentanedioate-O,S,O′)zinc(II) tetrahydrate, [Zn(C4H4-O4S)(C10H8N 2)(H2O)].4H2O, is mononuclear with a coordination sphere consisting of one S, two N and three O atoms. The Zn atom is linked to a tridentate thiodiacetate ligand, a bidentate 2,2′-bipyridine ligand and an aqua ligand resulting in a slightly distorted octahedral coordination geometry. The molecular units are linked together in the crystal by an extensive hydrogen-bonding network and by intermolecular S⋯S interactions.
publishDate 1996
dc.date.none.fl_str_mv 1996
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12110/paper_01082701_v52_n10_p2457_Baggio
url http://hdl.handle.net/20.500.12110/paper_01082701_v52_n10_p2457_Baggio
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/2.5/ar
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/2.5/ar
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv Acta Crystallogr Sect C Cryst Struct Commun 1996;52(10):2457-2460
reponame:Biblioteca Digital (UBA-FCEN)
instname:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
instacron:UBA-FCEN
reponame_str Biblioteca Digital (UBA-FCEN)
collection Biblioteca Digital (UBA-FCEN)
instname_str Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
instacron_str UBA-FCEN
institution UBA-FCEN
repository.name.fl_str_mv Biblioteca Digital (UBA-FCEN) - Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
repository.mail.fl_str_mv ana@bl.fcen.uba.ar
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score 13.084122

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