Synthesis and structural study of 2-(haloalkyl)-3-methylchromones

Autores
Alcívar León, Christian David; Ramos Guerrero, Luis; Bonilla Valladares, Pablo; Echeverría, Gustavo Alberto; Piro, Oscar Enrique; Ulic, Sonia Elizabeth; Jios, Jorge Luis; Langer, Peter
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The novel 2-(difluoromethyl)-3-methylchromone, 2-(dichloromethyl)-3-methylchromone, and 3-methyl-2-(perfluoroethyl)chromone were synthesized by a one-pot method and characterized through MS spectrometry, cyclic voltammetry, and vibrational (IR, Raman), UV–Vis, fluorescence, and NMR (1H, 13C, and 19F) spectroscopy. The crystal structure of 2-(difluoromethyl)-3-methylchromone and 2-(dichloromethyl)-3-methylchromone determined by X-ray diffraction methods were used to calculate their intermolecular interactions and crystal lattice energies together with the Hirshfeld surface analysis.
Instituto de Física La Plata
Centro de Química Inorgánica
Planta Piloto Multipropósito - Laboratorio de Servicios a la Industria y al Sistema Científico
Materia
Física
Química
Haloalkylchromones
Spectroscopic properties
Single crystal X-ray difraction
Quantum chemical calculations
Hirshfeld surface analysis
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/145893
Acceder
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network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Synthesis and structural study of 2-(haloalkyl)-3-methylchromonesAlcívar León, Christian DavidRamos Guerrero, LuisBonilla Valladares, PabloEcheverría, Gustavo AlbertoPiro, Oscar EnriqueUlic, Sonia ElizabethJios, Jorge LuisLanger, PeterFísicaQuímicaHaloalkylchromonesSpectroscopic propertiesSingle crystal X-ray difractionQuantum chemical calculationsHirshfeld surface analysisThe novel 2-(difluoromethyl)-3-methylchromone, 2-(dichloromethyl)-3-methylchromone, and 3-methyl-2-(perfluoroethyl)chromone were synthesized by a one-pot method and characterized through MS spectrometry, cyclic voltammetry, and vibrational (IR, Raman), UV–Vis, fluorescence, and NMR (1H, 13C, and 19F) spectroscopy. The crystal structure of 2-(difluoromethyl)-3-methylchromone and 2-(dichloromethyl)-3-methylchromone determined by X-ray diffraction methods were used to calculate their intermolecular interactions and crystal lattice energies together with the Hirshfeld surface analysis.Instituto de Física La PlataCentro de Química InorgánicaPlanta Piloto Multipropósito - Laboratorio de Servicios a la Industria y al Sistema Científico2019-10-28info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf1929-1940http://sedici.unlp.edu.ar/handle/10915/145893enginfo:eu-repo/semantics/altIdentifier/issn/0026-9247info:eu-repo/semantics/altIdentifier/issn/1434-4475info:eu-repo/semantics/altIdentifier/issn/0343-7329info:eu-repo/semantics/altIdentifier/doi/10.1007/s00706-019-02512-5info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-22T17:13:15Zoai:sedici.unlp.edu.ar:10915/145893Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-22 17:13:16.213SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Synthesis and structural study of 2-(haloalkyl)-3-methylchromones
title Synthesis and structural study of 2-(haloalkyl)-3-methylchromones
spellingShingle Synthesis and structural study of 2-(haloalkyl)-3-methylchromones
Alcívar León, Christian David
Física
Química
Haloalkylchromones
Spectroscopic properties
Single crystal X-ray difraction
Quantum chemical calculations
Hirshfeld surface analysis
title_short Synthesis and structural study of 2-(haloalkyl)-3-methylchromones
title_full Synthesis and structural study of 2-(haloalkyl)-3-methylchromones
title_fullStr Synthesis and structural study of 2-(haloalkyl)-3-methylchromones
title_full_unstemmed Synthesis and structural study of 2-(haloalkyl)-3-methylchromones
title_sort Synthesis and structural study of 2-(haloalkyl)-3-methylchromones
dc.creator.none.fl_str_mv Alcívar León, Christian David
Ramos Guerrero, Luis
Bonilla Valladares, Pablo
Echeverría, Gustavo Alberto
Piro, Oscar Enrique
Ulic, Sonia Elizabeth
Jios, Jorge Luis
Langer, Peter
author Alcívar León, Christian David
author_facet Alcívar León, Christian David
Ramos Guerrero, Luis
Bonilla Valladares, Pablo
Echeverría, Gustavo Alberto
Piro, Oscar Enrique
Ulic, Sonia Elizabeth
Jios, Jorge Luis
Langer, Peter
author_role author
author2 Ramos Guerrero, Luis
Bonilla Valladares, Pablo
Echeverría, Gustavo Alberto
Piro, Oscar Enrique
Ulic, Sonia Elizabeth
Jios, Jorge Luis
Langer, Peter
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Física
Química
Haloalkylchromones
Spectroscopic properties
Single crystal X-ray difraction
Quantum chemical calculations
Hirshfeld surface analysis
topic Física
Química
Haloalkylchromones
Spectroscopic properties
Single crystal X-ray difraction
Quantum chemical calculations
Hirshfeld surface analysis
dc.description.none.fl_txt_mv The novel 2-(difluoromethyl)-3-methylchromone, 2-(dichloromethyl)-3-methylchromone, and 3-methyl-2-(perfluoroethyl)chromone were synthesized by a one-pot method and characterized through MS spectrometry, cyclic voltammetry, and vibrational (IR, Raman), UV–Vis, fluorescence, and NMR (1H, 13C, and 19F) spectroscopy. The crystal structure of 2-(difluoromethyl)-3-methylchromone and 2-(dichloromethyl)-3-methylchromone determined by X-ray diffraction methods were used to calculate their intermolecular interactions and crystal lattice energies together with the Hirshfeld surface analysis.
Instituto de Física La Plata
Centro de Química Inorgánica
Planta Piloto Multipropósito - Laboratorio de Servicios a la Industria y al Sistema Científico
description The novel 2-(difluoromethyl)-3-methylchromone, 2-(dichloromethyl)-3-methylchromone, and 3-methyl-2-(perfluoroethyl)chromone were synthesized by a one-pot method and characterized through MS spectrometry, cyclic voltammetry, and vibrational (IR, Raman), UV–Vis, fluorescence, and NMR (1H, 13C, and 19F) spectroscopy. The crystal structure of 2-(difluoromethyl)-3-methylchromone and 2-(dichloromethyl)-3-methylchromone determined by X-ray diffraction methods were used to calculate their intermolecular interactions and crystal lattice energies together with the Hirshfeld surface analysis.
publishDate 2019
dc.date.none.fl_str_mv 2019-10-28
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/145893
url http://sedici.unlp.edu.ar/handle/10915/145893
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0026-9247
info:eu-repo/semantics/altIdentifier/issn/1434-4475
info:eu-repo/semantics/altIdentifier/issn/0343-7329
info:eu-repo/semantics/altIdentifier/doi/10.1007/s00706-019-02512-5
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
1929-1940
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 12.982451

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