Synthesis and structural study of 2-(haloalkyl)-3-methylchromones
- Autores
- Alcívar León, Christian David; Ramos Guerrero, Luis; Bonilla Valladares, Pablo; Echeverría, Gustavo Alberto; Piro, Oscar Enrique; Ulic, Sonia Elizabeth; Jios, Jorge Luis; Langer, Peter
- Año de publicación
- 2019
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The novel 2-(difluoromethyl)-3-methylchromone, 2-(dichloromethyl)-3-methylchromone, and 3-methyl-2-(perfluoroethyl)chromone were synthesized by a one-pot method and characterized through MS spectrometry, cyclic voltammetry, and vibrational (IR, Raman), UV–Vis, fluorescence, and NMR (1H, 13C, and 19F) spectroscopy. The crystal structure of 2-(difluoromethyl)-3-methylchromone and 2-(dichloromethyl)-3-methylchromone determined by X-ray diffraction methods were used to calculate their intermolecular interactions and crystal lattice energies together with the Hirshfeld surface analysis.
Instituto de Física La Plata
Centro de Química Inorgánica
Planta Piloto Multipropósito - Laboratorio de Servicios a la Industria y al Sistema Científico - Materia
-
Física
Química
Haloalkylchromones
Spectroscopic properties
Single crystal X-ray difraction
Quantum chemical calculations
Hirshfeld surface analysis - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by/4.0/
- Repositorio
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/145893
Ver los metadatos del registro completo
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Synthesis and structural study of 2-(haloalkyl)-3-methylchromonesAlcívar León, Christian DavidRamos Guerrero, LuisBonilla Valladares, PabloEcheverría, Gustavo AlbertoPiro, Oscar EnriqueUlic, Sonia ElizabethJios, Jorge LuisLanger, PeterFísicaQuímicaHaloalkylchromonesSpectroscopic propertiesSingle crystal X-ray difractionQuantum chemical calculationsHirshfeld surface analysisThe novel 2-(difluoromethyl)-3-methylchromone, 2-(dichloromethyl)-3-methylchromone, and 3-methyl-2-(perfluoroethyl)chromone were synthesized by a one-pot method and characterized through MS spectrometry, cyclic voltammetry, and vibrational (IR, Raman), UV–Vis, fluorescence, and NMR (1H, 13C, and 19F) spectroscopy. The crystal structure of 2-(difluoromethyl)-3-methylchromone and 2-(dichloromethyl)-3-methylchromone determined by X-ray diffraction methods were used to calculate their intermolecular interactions and crystal lattice energies together with the Hirshfeld surface analysis.Instituto de Física La PlataCentro de Química InorgánicaPlanta Piloto Multipropósito - Laboratorio de Servicios a la Industria y al Sistema Científico2019-10-28info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf1929-1940http://sedici.unlp.edu.ar/handle/10915/145893enginfo:eu-repo/semantics/altIdentifier/issn/0026-9247info:eu-repo/semantics/altIdentifier/issn/1434-4475info:eu-repo/semantics/altIdentifier/issn/0343-7329info:eu-repo/semantics/altIdentifier/doi/10.1007/s00706-019-02512-5info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:32:17Zoai:sedici.unlp.edu.ar:10915/145893Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:32:18.218SEDICI (UNLP) - Universidad Nacional de La Platafalse |
dc.title.none.fl_str_mv |
Synthesis and structural study of 2-(haloalkyl)-3-methylchromones |
title |
Synthesis and structural study of 2-(haloalkyl)-3-methylchromones |
spellingShingle |
Synthesis and structural study of 2-(haloalkyl)-3-methylchromones Alcívar León, Christian David Física Química Haloalkylchromones Spectroscopic properties Single crystal X-ray difraction Quantum chemical calculations Hirshfeld surface analysis |
title_short |
Synthesis and structural study of 2-(haloalkyl)-3-methylchromones |
title_full |
Synthesis and structural study of 2-(haloalkyl)-3-methylchromones |
title_fullStr |
Synthesis and structural study of 2-(haloalkyl)-3-methylchromones |
title_full_unstemmed |
Synthesis and structural study of 2-(haloalkyl)-3-methylchromones |
title_sort |
Synthesis and structural study of 2-(haloalkyl)-3-methylchromones |
dc.creator.none.fl_str_mv |
Alcívar León, Christian David Ramos Guerrero, Luis Bonilla Valladares, Pablo Echeverría, Gustavo Alberto Piro, Oscar Enrique Ulic, Sonia Elizabeth Jios, Jorge Luis Langer, Peter |
author |
Alcívar León, Christian David |
author_facet |
Alcívar León, Christian David Ramos Guerrero, Luis Bonilla Valladares, Pablo Echeverría, Gustavo Alberto Piro, Oscar Enrique Ulic, Sonia Elizabeth Jios, Jorge Luis Langer, Peter |
author_role |
author |
author2 |
Ramos Guerrero, Luis Bonilla Valladares, Pablo Echeverría, Gustavo Alberto Piro, Oscar Enrique Ulic, Sonia Elizabeth Jios, Jorge Luis Langer, Peter |
author2_role |
author author author author author author author |
dc.subject.none.fl_str_mv |
Física Química Haloalkylchromones Spectroscopic properties Single crystal X-ray difraction Quantum chemical calculations Hirshfeld surface analysis |
topic |
Física Química Haloalkylchromones Spectroscopic properties Single crystal X-ray difraction Quantum chemical calculations Hirshfeld surface analysis |
dc.description.none.fl_txt_mv |
The novel 2-(difluoromethyl)-3-methylchromone, 2-(dichloromethyl)-3-methylchromone, and 3-methyl-2-(perfluoroethyl)chromone were synthesized by a one-pot method and characterized through MS spectrometry, cyclic voltammetry, and vibrational (IR, Raman), UV–Vis, fluorescence, and NMR (1H, 13C, and 19F) spectroscopy. The crystal structure of 2-(difluoromethyl)-3-methylchromone and 2-(dichloromethyl)-3-methylchromone determined by X-ray diffraction methods were used to calculate their intermolecular interactions and crystal lattice energies together with the Hirshfeld surface analysis. Instituto de Física La Plata Centro de Química Inorgánica Planta Piloto Multipropósito - Laboratorio de Servicios a la Industria y al Sistema Científico |
description |
The novel 2-(difluoromethyl)-3-methylchromone, 2-(dichloromethyl)-3-methylchromone, and 3-methyl-2-(perfluoroethyl)chromone were synthesized by a one-pot method and characterized through MS spectrometry, cyclic voltammetry, and vibrational (IR, Raman), UV–Vis, fluorescence, and NMR (1H, 13C, and 19F) spectroscopy. The crystal structure of 2-(difluoromethyl)-3-methylchromone and 2-(dichloromethyl)-3-methylchromone determined by X-ray diffraction methods were used to calculate their intermolecular interactions and crystal lattice energies together with the Hirshfeld surface analysis. |
publishDate |
2019 |
dc.date.none.fl_str_mv |
2019-10-28 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/145893 |
url |
http://sedici.unlp.edu.ar/handle/10915/145893 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/issn/0026-9247 info:eu-repo/semantics/altIdentifier/issn/1434-4475 info:eu-repo/semantics/altIdentifier/issn/0343-7329 info:eu-repo/semantics/altIdentifier/doi/10.1007/s00706-019-02512-5 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
dc.format.none.fl_str_mv |
application/pdf 1929-1940 |
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reponame:SEDICI (UNLP) instname:Universidad Nacional de La Plata instacron:UNLP |
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Universidad Nacional de La Plata |
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UNLP |
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SEDICI (UNLP) - Universidad Nacional de La Plata |
repository.mail.fl_str_mv |
alira@sedici.unlp.edu.ar |
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