Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>)

Autores
Arvia, Alejandro Jorge; Aymonino, Pedro José
Año de publicación
1963
Idioma
español castellano
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The infrared spectrum of gaseous chloryl fluoride has been investigated in the region between 2.5 and 25 μ at pressures from ca. 1 mm Hg to ca. 1 atm at room temperature. The strong bands located at 1265, 1104, 627 and 542 cm-1 have been assigned to four of the six fundamental vibrations expected for a pyramidal tetratomic molecule pertaining to the C8 point group. The other two bands could not be detected but they were tcnt,atively located at 405 and 349 cm-1. A correlation of the chloryl fluoride spectrum with spectra of related molecules and ions has been useful to the assignment of the bands.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Materia
Ciencias Exactas
Química
Chloryl fluoride
Infrared spectrum
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/118208

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network_name_str SEDICI (UNLP)
spelling Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>)Arvia, Alejandro JorgeAymonino, Pedro JoséCiencias ExactasQuímicaChloryl fluorideInfrared spectrumThe infrared spectrum of gaseous chloryl fluoride has been investigated in the region between 2.5 and 25 μ at pressures from ca. 1 mm Hg to ca. 1 atm at room temperature. The strong bands located at 1265, 1104, 627 and 542 cm<sup>-1</sup> have been assigned to four of the six fundamental vibrations expected for a pyramidal tetratomic molecule pertaining to the C<sub>8</sub> point group. The other two bands could not be detected but they were tcnt,atively located at 405 and 349 cm<sup>-1</sup>. A correlation of the chloryl fluoride spectrum with spectra of related molecules and ions has been useful to the assignment of the bands.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas1963info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf1449-1456http://sedici.unlp.edu.ar/handle/10915/118208spainfo:eu-repo/semantics/altIdentifier/issn/1386-1425info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:27:45Zoai:sedici.unlp.edu.ar:10915/118208Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:27:46.039SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>)
title Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>)
spellingShingle Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>)
Arvia, Alejandro Jorge
Ciencias Exactas
Química
Chloryl fluoride
Infrared spectrum
title_short Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>)
title_full Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>)
title_fullStr Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>)
title_full_unstemmed Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>)
title_sort Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>)
dc.creator.none.fl_str_mv Arvia, Alejandro Jorge
Aymonino, Pedro José
author Arvia, Alejandro Jorge
author_facet Arvia, Alejandro Jorge
Aymonino, Pedro José
author_role author
author2 Aymonino, Pedro José
author2_role author
dc.subject.none.fl_str_mv Ciencias Exactas
Química
Chloryl fluoride
Infrared spectrum
topic Ciencias Exactas
Química
Chloryl fluoride
Infrared spectrum
dc.description.none.fl_txt_mv The infrared spectrum of gaseous chloryl fluoride has been investigated in the region between 2.5 and 25 μ at pressures from ca. 1 mm Hg to ca. 1 atm at room temperature. The strong bands located at 1265, 1104, 627 and 542 cm<sup>-1</sup> have been assigned to four of the six fundamental vibrations expected for a pyramidal tetratomic molecule pertaining to the C<sub>8</sub> point group. The other two bands could not be detected but they were tcnt,atively located at 405 and 349 cm<sup>-1</sup>. A correlation of the chloryl fluoride spectrum with spectra of related molecules and ions has been useful to the assignment of the bands.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
description The infrared spectrum of gaseous chloryl fluoride has been investigated in the region between 2.5 and 25 μ at pressures from ca. 1 mm Hg to ca. 1 atm at room temperature. The strong bands located at 1265, 1104, 627 and 542 cm<sup>-1</sup> have been assigned to four of the six fundamental vibrations expected for a pyramidal tetratomic molecule pertaining to the C<sub>8</sub> point group. The other two bands could not be detected but they were tcnt,atively located at 405 and 349 cm<sup>-1</sup>. A correlation of the chloryl fluoride spectrum with spectra of related molecules and ions has been useful to the assignment of the bands.
publishDate 1963
dc.date.none.fl_str_mv 1963
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/118208
url http://sedici.unlp.edu.ar/handle/10915/118208
dc.language.none.fl_str_mv spa
language spa
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/1386-1425
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
1449-1456
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instname:Universidad Nacional de La Plata
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instname_str Universidad Nacional de La Plata
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repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
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