Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>)
- Autores
- Arvia, Alejandro Jorge; Aymonino, Pedro José
- Año de publicación
- 1963
- Idioma
- español castellano
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The infrared spectrum of gaseous chloryl fluoride has been investigated in the region between 2.5 and 25 μ at pressures from ca. 1 mm Hg to ca. 1 atm at room temperature. The strong bands located at 1265, 1104, 627 and 542 cm-1 have been assigned to four of the six fundamental vibrations expected for a pyramidal tetratomic molecule pertaining to the C8 point group. The other two bands could not be detected but they were tcnt,atively located at 405 and 349 cm-1. A correlation of the chloryl fluoride spectrum with spectra of related molecules and ions has been useful to the assignment of the bands.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas - Materia
-
Ciencias Exactas
Química
Chloryl fluoride
Infrared spectrum - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by-nc-sa/4.0/
- Repositorio
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/118208
Ver los metadatos del registro completo
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Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>)Arvia, Alejandro JorgeAymonino, Pedro JoséCiencias ExactasQuímicaChloryl fluorideInfrared spectrumThe infrared spectrum of gaseous chloryl fluoride has been investigated in the region between 2.5 and 25 μ at pressures from ca. 1 mm Hg to ca. 1 atm at room temperature. The strong bands located at 1265, 1104, 627 and 542 cm<sup>-1</sup> have been assigned to four of the six fundamental vibrations expected for a pyramidal tetratomic molecule pertaining to the C<sub>8</sub> point group. The other two bands could not be detected but they were tcnt,atively located at 405 and 349 cm<sup>-1</sup>. A correlation of the chloryl fluoride spectrum with spectra of related molecules and ions has been useful to the assignment of the bands.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas1963info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf1449-1456http://sedici.unlp.edu.ar/handle/10915/118208spainfo:eu-repo/semantics/altIdentifier/issn/1386-1425info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:27:45Zoai:sedici.unlp.edu.ar:10915/118208Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:27:46.039SEDICI (UNLP) - Universidad Nacional de La Platafalse |
dc.title.none.fl_str_mv |
Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>) |
title |
Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>) |
spellingShingle |
Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>) Arvia, Alejandro Jorge Ciencias Exactas Química Chloryl fluoride Infrared spectrum |
title_short |
Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>) |
title_full |
Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>) |
title_fullStr |
Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>) |
title_full_unstemmed |
Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>) |
title_sort |
Infra-red absorption spectrum of gaseous chloryl fluoride (FC1O<sub>2</sub>) |
dc.creator.none.fl_str_mv |
Arvia, Alejandro Jorge Aymonino, Pedro José |
author |
Arvia, Alejandro Jorge |
author_facet |
Arvia, Alejandro Jorge Aymonino, Pedro José |
author_role |
author |
author2 |
Aymonino, Pedro José |
author2_role |
author |
dc.subject.none.fl_str_mv |
Ciencias Exactas Química Chloryl fluoride Infrared spectrum |
topic |
Ciencias Exactas Química Chloryl fluoride Infrared spectrum |
dc.description.none.fl_txt_mv |
The infrared spectrum of gaseous chloryl fluoride has been investigated in the region between 2.5 and 25 μ at pressures from ca. 1 mm Hg to ca. 1 atm at room temperature. The strong bands located at 1265, 1104, 627 and 542 cm<sup>-1</sup> have been assigned to four of the six fundamental vibrations expected for a pyramidal tetratomic molecule pertaining to the C<sub>8</sub> point group. The other two bands could not be detected but they were tcnt,atively located at 405 and 349 cm<sup>-1</sup>. A correlation of the chloryl fluoride spectrum with spectra of related molecules and ions has been useful to the assignment of the bands. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas |
description |
The infrared spectrum of gaseous chloryl fluoride has been investigated in the region between 2.5 and 25 μ at pressures from ca. 1 mm Hg to ca. 1 atm at room temperature. The strong bands located at 1265, 1104, 627 and 542 cm<sup>-1</sup> have been assigned to four of the six fundamental vibrations expected for a pyramidal tetratomic molecule pertaining to the C<sub>8</sub> point group. The other two bands could not be detected but they were tcnt,atively located at 405 and 349 cm<sup>-1</sup>. A correlation of the chloryl fluoride spectrum with spectra of related molecules and ions has been useful to the assignment of the bands. |
publishDate |
1963 |
dc.date.none.fl_str_mv |
1963 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/118208 |
url |
http://sedici.unlp.edu.ar/handle/10915/118208 |
dc.language.none.fl_str_mv |
spa |
language |
spa |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/issn/1386-1425 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by-nc-sa/4.0/ Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) |
dc.format.none.fl_str_mv |
application/pdf 1449-1456 |
dc.source.none.fl_str_mv |
reponame:SEDICI (UNLP) instname:Universidad Nacional de La Plata instacron:UNLP |
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Universidad Nacional de La Plata |
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SEDICI (UNLP) - Universidad Nacional de La Plata |
repository.mail.fl_str_mv |
alira@sedici.unlp.edu.ar |
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1844616156116156416 |
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13.070432 |