The dynamic behavior of butanethiol and dodecanethiol adsorbates on Au(111) terraces

Autores
Terán Arce, Fernando; Vela, María Elena; Salvarezza, Roberto Carlos; Arvia, Alejandro Jorge
Año de publicación
1998
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The dynamics of butanethiol and dodecanethiol monolayers adsorbed on Au(111) studied by ex situ and in situ sequential scanning tunneling microscopy (STM) shows, at room temperature and in the range of seconds, √3×√3 R30°⇔c(4×2) transitions. High-resolution STM imaging also shows that these transitions can be explained by a displacement of adsorbed molecules from hollow to bridge sites and vice versa. Transitions from the p(n×1) superlattice to the √3×√3 R30° lattice were also imaged in real time. These processes appear to be coupled with fluctuations of the hole size of the Au(111) terrace.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Facultad de Ciencias Exactas
Materia
Ciencias Exactas
Química
Butanoles
Dodecanol
Oro
monolayers
scanning tunneling microscopy
Cinética química
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/84128
Acceder
id SEDICI_d4778f0fedb7c9fa56affe043662047e
oai_identifier_str oai:sedici.unlp.edu.ar:10915/84128
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling The dynamic behavior of butanethiol and dodecanethiol adsorbates on Au(111) terracesTerán Arce, FernandoVela, María ElenaSalvarezza, Roberto CarlosArvia, Alejandro JorgeCiencias ExactasQuímicaButanolesDodecanolOromonolayersscanning tunneling microscopyCinética químicaThe dynamics of butanethiol and dodecanethiol monolayers adsorbed on Au(111) studied by <i>ex situ</i> and <i>in situ</i> sequential scanning tunneling microscopy (STM) shows, at room temperature and in the range of seconds, √3×√3 <i>R30°⇔c</i>(4×2) transitions. High-resolution STM imaging also shows that these transitions can be explained by a displacement of adsorbed molecules from hollow to bridge sites and vice versa. Transitions from the <i>p</i>(<i>n</i>×1) superlattice to the √3×√3 <i>R30°</i> lattice were also imaged in real time. These processes appear to be coupled with fluctuations of the hole size of the Au(111) terrace.Instituto de Investigaciones Fisicoquímicas Teóricas y AplicadasFacultad de Ciencias Exactas1998-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf5703-5706http://sedici.unlp.edu.ar/handle/10915/84128enginfo:eu-repo/semantics/altIdentifier/issn/0021-9606info:eu-repo/semantics/altIdentifier/doi/10.1063/1.477190info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:16:19Zoai:sedici.unlp.edu.ar:10915/84128Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:16:20.266SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv The dynamic behavior of butanethiol and dodecanethiol adsorbates on Au(111) terraces
title The dynamic behavior of butanethiol and dodecanethiol adsorbates on Au(111) terraces
spellingShingle The dynamic behavior of butanethiol and dodecanethiol adsorbates on Au(111) terraces
Terán Arce, Fernando
Ciencias Exactas
Química
Butanoles
Dodecanol
Oro
monolayers
scanning tunneling microscopy
Cinética química
title_short The dynamic behavior of butanethiol and dodecanethiol adsorbates on Au(111) terraces
title_full The dynamic behavior of butanethiol and dodecanethiol adsorbates on Au(111) terraces
title_fullStr The dynamic behavior of butanethiol and dodecanethiol adsorbates on Au(111) terraces
title_full_unstemmed The dynamic behavior of butanethiol and dodecanethiol adsorbates on Au(111) terraces
title_sort The dynamic behavior of butanethiol and dodecanethiol adsorbates on Au(111) terraces
dc.creator.none.fl_str_mv Terán Arce, Fernando
Vela, María Elena
Salvarezza, Roberto Carlos
Arvia, Alejandro Jorge
author Terán Arce, Fernando
author_facet Terán Arce, Fernando
Vela, María Elena
Salvarezza, Roberto Carlos
Arvia, Alejandro Jorge
author_role author
author2 Vela, María Elena
Salvarezza, Roberto Carlos
Arvia, Alejandro Jorge
author2_role author
author
author
dc.subject.none.fl_str_mv Ciencias Exactas
Química
Butanoles
Dodecanol
Oro
monolayers
scanning tunneling microscopy
Cinética química
topic Ciencias Exactas
Química
Butanoles
Dodecanol
Oro
monolayers
scanning tunneling microscopy
Cinética química
dc.description.none.fl_txt_mv The dynamics of butanethiol and dodecanethiol monolayers adsorbed on Au(111) studied by <i>ex situ</i> and <i>in situ</i> sequential scanning tunneling microscopy (STM) shows, at room temperature and in the range of seconds, √3×√3 <i>R30°⇔c</i>(4×2) transitions. High-resolution STM imaging also shows that these transitions can be explained by a displacement of adsorbed molecules from hollow to bridge sites and vice versa. Transitions from the <i>p</i>(<i>n</i>×1) superlattice to the √3×√3 <i>R30°</i> lattice were also imaged in real time. These processes appear to be coupled with fluctuations of the hole size of the Au(111) terrace.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Facultad de Ciencias Exactas
description The dynamics of butanethiol and dodecanethiol monolayers adsorbed on Au(111) studied by <i>ex situ</i> and <i>in situ</i> sequential scanning tunneling microscopy (STM) shows, at room temperature and in the range of seconds, √3×√3 <i>R30°⇔c</i>(4×2) transitions. High-resolution STM imaging also shows that these transitions can be explained by a displacement of adsorbed molecules from hollow to bridge sites and vice versa. Transitions from the <i>p</i>(<i>n</i>×1) superlattice to the √3×√3 <i>R30°</i> lattice were also imaged in real time. These processes appear to be coupled with fluctuations of the hole size of the Au(111) terrace.
publishDate 1998
dc.date.none.fl_str_mv 1998-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/84128
url http://sedici.unlp.edu.ar/handle/10915/84128
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0021-9606
info:eu-repo/semantics/altIdentifier/doi/10.1063/1.477190
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
5703-5706
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.070432

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