Changes in real surface area, crystallographic orientation and morphology of platinum electrodes caused by periodic potential treatments : Phenomenological approach

Autores
Visintin, Arnaldo; Canullo, José Carlos; Triaca, Walter Enrique; Arvia, Alejandro Jorge
Año de publicación
1988
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The changes in surface structure of polyfaceted single crystal platinum spheres subjected to repetitive square-wave potential treatments in acid solution have been studied . The dependence of the prevailing type of change on symmetry, potential limits and frequency of the periodic potential has been determined. Results are discussed on the basis of different reactions occurring within definite potential windows and distinct rate controlling processes depending on the operating conditions. Accordingly, the surface restructuring involves a predominant change in either the real surface area, the crystallographic orientation or the entire surface morphology.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Facultad de Ciencias Exactas
Materia
Ciencias Exactas
Química
surface area
Cristalografía
Platino (Metal)
Electrodos
Hallazgos Morfológicos y Microscópicos
Metales
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/80301
Acceder
id SEDICI_ca0de557bfe21fe82aea6f508b6fb2f3
oai_identifier_str oai:sedici.unlp.edu.ar:10915/80301
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Changes in real surface area, crystallographic orientation and morphology of platinum electrodes caused by periodic potential treatments : Phenomenological approachVisintin, ArnaldoCanullo, José CarlosTriaca, Walter EnriqueArvia, Alejandro JorgeCiencias ExactasQuímicasurface areaCristalografíaPlatino (Metal)ElectrodosHallazgos Morfológicos y MicroscópicosMetalesThe changes in surface structure of polyfaceted single crystal platinum spheres subjected to repetitive square-wave potential treatments in acid solution have been studied . The dependence of the prevailing type of change on symmetry, potential limits and frequency of the periodic potential has been determined. Results are discussed on the basis of different reactions occurring within definite potential windows and distinct rate controlling processes depending on the operating conditions. Accordingly, the surface restructuring involves a predominant change in either the real surface area, the crystallographic orientation or the entire surface morphology.Instituto de Investigaciones Fisicoquímicas Teóricas y AplicadasFacultad de Ciencias Exactas1988-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf67-89http://sedici.unlp.edu.ar/handle/10915/80301enginfo:eu-repo/semantics/altIdentifier/issn/0022-0728info:eu-repo/semantics/altIdentifier/doi/10.1016/0022-0728(88)80270-5info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-29T15:19:52Zoai:sedici.unlp.edu.ar:10915/80301Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-29 15:19:52.295SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Changes in real surface area, crystallographic orientation and morphology of platinum electrodes caused by periodic potential treatments : Phenomenological approach
title Changes in real surface area, crystallographic orientation and morphology of platinum electrodes caused by periodic potential treatments : Phenomenological approach
spellingShingle Changes in real surface area, crystallographic orientation and morphology of platinum electrodes caused by periodic potential treatments : Phenomenological approach
Visintin, Arnaldo
Ciencias Exactas
Química
surface area
Cristalografía
Platino (Metal)
Electrodos
Hallazgos Morfológicos y Microscópicos
Metales
title_short Changes in real surface area, crystallographic orientation and morphology of platinum electrodes caused by periodic potential treatments : Phenomenological approach
title_full Changes in real surface area, crystallographic orientation and morphology of platinum electrodes caused by periodic potential treatments : Phenomenological approach
title_fullStr Changes in real surface area, crystallographic orientation and morphology of platinum electrodes caused by periodic potential treatments : Phenomenological approach
title_full_unstemmed Changes in real surface area, crystallographic orientation and morphology of platinum electrodes caused by periodic potential treatments : Phenomenological approach
title_sort Changes in real surface area, crystallographic orientation and morphology of platinum electrodes caused by periodic potential treatments : Phenomenological approach
dc.creator.none.fl_str_mv Visintin, Arnaldo
Canullo, José Carlos
Triaca, Walter Enrique
Arvia, Alejandro Jorge
author Visintin, Arnaldo
author_facet Visintin, Arnaldo
Canullo, José Carlos
Triaca, Walter Enrique
Arvia, Alejandro Jorge
author_role author
author2 Canullo, José Carlos
Triaca, Walter Enrique
Arvia, Alejandro Jorge
author2_role author
author
author
dc.subject.none.fl_str_mv Ciencias Exactas
Química
surface area
Cristalografía
Platino (Metal)
Electrodos
Hallazgos Morfológicos y Microscópicos
Metales
topic Ciencias Exactas
Química
surface area
Cristalografía
Platino (Metal)
Electrodos
Hallazgos Morfológicos y Microscópicos
Metales
dc.description.none.fl_txt_mv The changes in surface structure of polyfaceted single crystal platinum spheres subjected to repetitive square-wave potential treatments in acid solution have been studied . The dependence of the prevailing type of change on symmetry, potential limits and frequency of the periodic potential has been determined. Results are discussed on the basis of different reactions occurring within definite potential windows and distinct rate controlling processes depending on the operating conditions. Accordingly, the surface restructuring involves a predominant change in either the real surface area, the crystallographic orientation or the entire surface morphology.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Facultad de Ciencias Exactas
description The changes in surface structure of polyfaceted single crystal platinum spheres subjected to repetitive square-wave potential treatments in acid solution have been studied . The dependence of the prevailing type of change on symmetry, potential limits and frequency of the periodic potential has been determined. Results are discussed on the basis of different reactions occurring within definite potential windows and distinct rate controlling processes depending on the operating conditions. Accordingly, the surface restructuring involves a predominant change in either the real surface area, the crystallographic orientation or the entire surface morphology.
publishDate 1988
dc.date.none.fl_str_mv 1988-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/80301
url http://sedici.unlp.edu.ar/handle/10915/80301
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0022-0728
info:eu-repo/semantics/altIdentifier/doi/10.1016/0022-0728(88)80270-5
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
67-89
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
_version_ 1847428151967219712
score 13.10058

Publicaciones similares