Influence of capping on the atomistic arrangement in palladium nanoparticles at room temperature

Autores
Corthey, Gastón; Olmos Asar, Jimena A.; Casillas, Gilberto; Mariscal, Marcelo M.; Mejía Rosales, Sergio; Azcárate, Julio César; Larios, Eduardo; José Yacamán, Miguel; Salvarezza, Roberto Carlos; Fonticelli, Mariano Hernán
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The role that protecting molecules have on the way that palladium atoms arrange themselves in nanoparticles prepared at room temperature was studied by the analysis of aberration-corrected scanning transmission electron microscopy images and atomistic Langevin dynamics simulations. It was found that the arrangement of Pd atoms is less ordered in thiolate-protected nanoparticles than in amine-protected ones. The experimental and theoretical data showed that the disorder in ∼3 nm thiolate-protected particles is promoted by the strong S–Pd bond in the sulfide layer that surrounds the nanoparticles.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Materia
Química
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/124341
Acceder
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oai_identifier_str oai:sedici.unlp.edu.ar:10915/124341
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Influence of capping on the atomistic arrangement in palladium nanoparticles at room temperatureCorthey, GastónOlmos Asar, Jimena A.Casillas, GilbertoMariscal, Marcelo M.Mejía Rosales, SergioAzcárate, Julio CésarLarios, EduardoJosé Yacamán, MiguelSalvarezza, Roberto CarlosFonticelli, Mariano HernánQuímicaThe role that protecting molecules have on the way that palladium atoms arrange themselves in nanoparticles prepared at room temperature was studied by the analysis of aberration-corrected scanning transmission electron microscopy images and atomistic Langevin dynamics simulations. It was found that the arrangement of Pd atoms is less ordered in thiolate-protected nanoparticles than in amine-protected ones. The experimental and theoretical data showed that the disorder in ∼3 nm thiolate-protected particles is promoted by the strong S–Pd bond in the sulfide layer that surrounds the nanoparticles.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas2014-10-13info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf24641-24647http://sedici.unlp.edu.ar/handle/10915/124341enginfo:eu-repo/semantics/altIdentifier/issn/1932-7447info:eu-repo/semantics/altIdentifier/issn/1932-7455info:eu-repo/semantics/altIdentifier/doi/10.1021/jp5083505info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-22T17:10:29Zoai:sedici.unlp.edu.ar:10915/124341Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-22 17:10:29.349SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Influence of capping on the atomistic arrangement in palladium nanoparticles at room temperature
title Influence of capping on the atomistic arrangement in palladium nanoparticles at room temperature
spellingShingle Influence of capping on the atomistic arrangement in palladium nanoparticles at room temperature
Corthey, Gastón
Química
title_short Influence of capping on the atomistic arrangement in palladium nanoparticles at room temperature
title_full Influence of capping on the atomistic arrangement in palladium nanoparticles at room temperature
title_fullStr Influence of capping on the atomistic arrangement in palladium nanoparticles at room temperature
title_full_unstemmed Influence of capping on the atomistic arrangement in palladium nanoparticles at room temperature
title_sort Influence of capping on the atomistic arrangement in palladium nanoparticles at room temperature
dc.creator.none.fl_str_mv Corthey, Gastón
Olmos Asar, Jimena A.
Casillas, Gilberto
Mariscal, Marcelo M.
Mejía Rosales, Sergio
Azcárate, Julio César
Larios, Eduardo
José Yacamán, Miguel
Salvarezza, Roberto Carlos
Fonticelli, Mariano Hernán
author Corthey, Gastón
author_facet Corthey, Gastón
Olmos Asar, Jimena A.
Casillas, Gilberto
Mariscal, Marcelo M.
Mejía Rosales, Sergio
Azcárate, Julio César
Larios, Eduardo
José Yacamán, Miguel
Salvarezza, Roberto Carlos
Fonticelli, Mariano Hernán
author_role author
author2 Olmos Asar, Jimena A.
Casillas, Gilberto
Mariscal, Marcelo M.
Mejía Rosales, Sergio
Azcárate, Julio César
Larios, Eduardo
José Yacamán, Miguel
Salvarezza, Roberto Carlos
Fonticelli, Mariano Hernán
author2_role author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Química
topic Química
dc.description.none.fl_txt_mv The role that protecting molecules have on the way that palladium atoms arrange themselves in nanoparticles prepared at room temperature was studied by the analysis of aberration-corrected scanning transmission electron microscopy images and atomistic Langevin dynamics simulations. It was found that the arrangement of Pd atoms is less ordered in thiolate-protected nanoparticles than in amine-protected ones. The experimental and theoretical data showed that the disorder in ∼3 nm thiolate-protected particles is promoted by the strong S–Pd bond in the sulfide layer that surrounds the nanoparticles.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
description The role that protecting molecules have on the way that palladium atoms arrange themselves in nanoparticles prepared at room temperature was studied by the analysis of aberration-corrected scanning transmission electron microscopy images and atomistic Langevin dynamics simulations. It was found that the arrangement of Pd atoms is less ordered in thiolate-protected nanoparticles than in amine-protected ones. The experimental and theoretical data showed that the disorder in ∼3 nm thiolate-protected particles is promoted by the strong S–Pd bond in the sulfide layer that surrounds the nanoparticles.
publishDate 2014
dc.date.none.fl_str_mv 2014-10-13
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/124341
url http://sedici.unlp.edu.ar/handle/10915/124341
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/1932-7447
info:eu-repo/semantics/altIdentifier/issn/1932-7455
info:eu-repo/semantics/altIdentifier/doi/10.1021/jp5083505
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
24641-24647
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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