Influence of capping on the atomistic arrangement in palladium nanoparticles at room temperature
- Autores
- Corthey, Gastón; Olmos Asar, Jimena A.; Casillas, Gilberto; Mariscal, Marcelo M.; Mejía Rosales, Sergio; Azcárate, Julio César; Larios, Eduardo; José Yacamán, Miguel; Salvarezza, Roberto Carlos; Fonticelli, Mariano Hernán
- Año de publicación
- 2014
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The role that protecting molecules have on the way that palladium atoms arrange themselves in nanoparticles prepared at room temperature was studied by the analysis of aberration-corrected scanning transmission electron microscopy images and atomistic Langevin dynamics simulations. It was found that the arrangement of Pd atoms is less ordered in thiolate-protected nanoparticles than in amine-protected ones. The experimental and theoretical data showed that the disorder in ∼3 nm thiolate-protected particles is promoted by the strong S–Pd bond in the sulfide layer that surrounds the nanoparticles.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas - Materia
- Química
- Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by/4.0/
- Repositorio
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/124341
Ver los metadatos del registro completo
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Influence of capping on the atomistic arrangement in palladium nanoparticles at room temperatureCorthey, GastónOlmos Asar, Jimena A.Casillas, GilbertoMariscal, Marcelo M.Mejía Rosales, SergioAzcárate, Julio CésarLarios, EduardoJosé Yacamán, MiguelSalvarezza, Roberto CarlosFonticelli, Mariano HernánQuímicaThe role that protecting molecules have on the way that palladium atoms arrange themselves in nanoparticles prepared at room temperature was studied by the analysis of aberration-corrected scanning transmission electron microscopy images and atomistic Langevin dynamics simulations. It was found that the arrangement of Pd atoms is less ordered in thiolate-protected nanoparticles than in amine-protected ones. The experimental and theoretical data showed that the disorder in ∼3 nm thiolate-protected particles is promoted by the strong S–Pd bond in the sulfide layer that surrounds the nanoparticles.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas2014-10-13info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf24641-24647http://sedici.unlp.edu.ar/handle/10915/124341enginfo:eu-repo/semantics/altIdentifier/issn/1932-7447info:eu-repo/semantics/altIdentifier/issn/1932-7455info:eu-repo/semantics/altIdentifier/doi/10.1021/jp5083505info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:29:33Zoai:sedici.unlp.edu.ar:10915/124341Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:29:33.791SEDICI (UNLP) - Universidad Nacional de La Platafalse |
dc.title.none.fl_str_mv |
Influence of capping on the atomistic arrangement in palladium nanoparticles at room temperature |
title |
Influence of capping on the atomistic arrangement in palladium nanoparticles at room temperature |
spellingShingle |
Influence of capping on the atomistic arrangement in palladium nanoparticles at room temperature Corthey, Gastón Química |
title_short |
Influence of capping on the atomistic arrangement in palladium nanoparticles at room temperature |
title_full |
Influence of capping on the atomistic arrangement in palladium nanoparticles at room temperature |
title_fullStr |
Influence of capping on the atomistic arrangement in palladium nanoparticles at room temperature |
title_full_unstemmed |
Influence of capping on the atomistic arrangement in palladium nanoparticles at room temperature |
title_sort |
Influence of capping on the atomistic arrangement in palladium nanoparticles at room temperature |
dc.creator.none.fl_str_mv |
Corthey, Gastón Olmos Asar, Jimena A. Casillas, Gilberto Mariscal, Marcelo M. Mejía Rosales, Sergio Azcárate, Julio César Larios, Eduardo José Yacamán, Miguel Salvarezza, Roberto Carlos Fonticelli, Mariano Hernán |
author |
Corthey, Gastón |
author_facet |
Corthey, Gastón Olmos Asar, Jimena A. Casillas, Gilberto Mariscal, Marcelo M. Mejía Rosales, Sergio Azcárate, Julio César Larios, Eduardo José Yacamán, Miguel Salvarezza, Roberto Carlos Fonticelli, Mariano Hernán |
author_role |
author |
author2 |
Olmos Asar, Jimena A. Casillas, Gilberto Mariscal, Marcelo M. Mejía Rosales, Sergio Azcárate, Julio César Larios, Eduardo José Yacamán, Miguel Salvarezza, Roberto Carlos Fonticelli, Mariano Hernán |
author2_role |
author author author author author author author author author |
dc.subject.none.fl_str_mv |
Química |
topic |
Química |
dc.description.none.fl_txt_mv |
The role that protecting molecules have on the way that palladium atoms arrange themselves in nanoparticles prepared at room temperature was studied by the analysis of aberration-corrected scanning transmission electron microscopy images and atomistic Langevin dynamics simulations. It was found that the arrangement of Pd atoms is less ordered in thiolate-protected nanoparticles than in amine-protected ones. The experimental and theoretical data showed that the disorder in ∼3 nm thiolate-protected particles is promoted by the strong S–Pd bond in the sulfide layer that surrounds the nanoparticles. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas |
description |
The role that protecting molecules have on the way that palladium atoms arrange themselves in nanoparticles prepared at room temperature was studied by the analysis of aberration-corrected scanning transmission electron microscopy images and atomistic Langevin dynamics simulations. It was found that the arrangement of Pd atoms is less ordered in thiolate-protected nanoparticles than in amine-protected ones. The experimental and theoretical data showed that the disorder in ∼3 nm thiolate-protected particles is promoted by the strong S–Pd bond in the sulfide layer that surrounds the nanoparticles. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-10-13 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/124341 |
url |
http://sedici.unlp.edu.ar/handle/10915/124341 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/issn/1932-7447 info:eu-repo/semantics/altIdentifier/issn/1932-7455 info:eu-repo/semantics/altIdentifier/doi/10.1021/jp5083505 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
dc.format.none.fl_str_mv |
application/pdf 24641-24647 |
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reponame:SEDICI (UNLP) instname:Universidad Nacional de La Plata instacron:UNLP |
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SEDICI (UNLP) - Universidad Nacional de La Plata |
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13.070432 |