Voltammetric characterization of [ReO]3+ containing complexes
- Autores
- Cerda, María Fernanda; Kremer, Carlos; Castro Luna, Ana María; Méndez, Eduardo
- Año de publicación
- 2007
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- In the present work, the voltammetric profiles of Au-pc in 1 mM solutions of K[ReVOCl2(L)] (L = dianions of H2hida or H2eida; hida, n-(2,6-dimethylphenyl carbamoylmethyl)imino diacetic acid, and eida, 2,6-diethyl ida) complexes were evaluated. The obtained electrochemical response was the result of the contributions coming from the [ReO]3+ core (Epa at ca. 0.2 V vs. Ag/AgNO3) and the carboxylic group of the ligand. There where also observed redox contributions ascribed to the presence of perrhenate coming from the decomposition of the complex with the lost of ligands, in agreement with the low stability of the studied complexes. copyright The Electrochemical Society.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Facultad de Ciencias Exactas - Materia
-
Ciencias Exactas
solutions
complexes
rhenium - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by-nc-sa/4.0/
- Repositorio
.jpg)
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/83370
Ver los metadatos del registro completo
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Voltammetric characterization of [ReO]3+ containing complexesCerda, María FernandaKremer, CarlosCastro Luna, Ana MaríaMéndez, EduardoCiencias ExactassolutionscomplexesrheniumIn the present work, the voltammetric profiles of Au-pc in 1 mM solutions of K[Re<SUP>V</SUP>OCl<SUB>2</SUB>(L)] (L = dianions of H<SUB>2</SUB>hida or H<SUB>2</SUB>eida; hida, n-(2,6-dimethylphenyl carbamoylmethyl)imino diacetic acid, and eida, 2,6-diethyl ida) complexes were evaluated. The obtained electrochemical response was the result of the contributions coming from the [ReO]<SUP>3+</SUP> <i>core</i> (E<SUB>pa</SUB> at ca. 0.2 V vs. Ag/AgNO<SUB>3</SUB>) and the carboxylic group of the ligand. There where also observed redox contributions ascribed to the presence of perrhenate coming from the decomposition of the complex with the lost of ligands, in agreement with the low stability of the studied complexes. copyright The Electrochemical Society.Instituto de Investigaciones Fisicoquímicas Teóricas y AplicadasFacultad de Ciencias Exactas2007info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf7-15http://sedici.unlp.edu.ar/handle/10915/83370enginfo:eu-repo/semantics/altIdentifier/issn/1938-5862info:eu-repo/semantics/altIdentifier/doi/10.1149/1.2721509info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-22T16:56:32Zoai:sedici.unlp.edu.ar:10915/83370Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-22 16:56:32.474SEDICI (UNLP) - Universidad Nacional de La Platafalse |
| dc.title.none.fl_str_mv |
Voltammetric characterization of [ReO]3+ containing complexes |
| title |
Voltammetric characterization of [ReO]3+ containing complexes |
| spellingShingle |
Voltammetric characterization of [ReO]3+ containing complexes Cerda, María Fernanda Ciencias Exactas solutions complexes rhenium |
| title_short |
Voltammetric characterization of [ReO]3+ containing complexes |
| title_full |
Voltammetric characterization of [ReO]3+ containing complexes |
| title_fullStr |
Voltammetric characterization of [ReO]3+ containing complexes |
| title_full_unstemmed |
Voltammetric characterization of [ReO]3+ containing complexes |
| title_sort |
Voltammetric characterization of [ReO]3+ containing complexes |
| dc.creator.none.fl_str_mv |
Cerda, María Fernanda Kremer, Carlos Castro Luna, Ana María Méndez, Eduardo |
| author |
Cerda, María Fernanda |
| author_facet |
Cerda, María Fernanda Kremer, Carlos Castro Luna, Ana María Méndez, Eduardo |
| author_role |
author |
| author2 |
Kremer, Carlos Castro Luna, Ana María Méndez, Eduardo |
| author2_role |
author author author |
| dc.subject.none.fl_str_mv |
Ciencias Exactas solutions complexes rhenium |
| topic |
Ciencias Exactas solutions complexes rhenium |
| dc.description.none.fl_txt_mv |
In the present work, the voltammetric profiles of Au-pc in 1 mM solutions of K[Re<SUP>V</SUP>OCl<SUB>2</SUB>(L)] (L = dianions of H<SUB>2</SUB>hida or H<SUB>2</SUB>eida; hida, n-(2,6-dimethylphenyl carbamoylmethyl)imino diacetic acid, and eida, 2,6-diethyl ida) complexes were evaluated. The obtained electrochemical response was the result of the contributions coming from the [ReO]<SUP>3+</SUP> <i>core</i> (E<SUB>pa</SUB> at ca. 0.2 V vs. Ag/AgNO<SUB>3</SUB>) and the carboxylic group of the ligand. There where also observed redox contributions ascribed to the presence of perrhenate coming from the decomposition of the complex with the lost of ligands, in agreement with the low stability of the studied complexes. copyright The Electrochemical Society. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas Facultad de Ciencias Exactas |
| description |
In the present work, the voltammetric profiles of Au-pc in 1 mM solutions of K[Re<SUP>V</SUP>OCl<SUB>2</SUB>(L)] (L = dianions of H<SUB>2</SUB>hida or H<SUB>2</SUB>eida; hida, n-(2,6-dimethylphenyl carbamoylmethyl)imino diacetic acid, and eida, 2,6-diethyl ida) complexes were evaluated. The obtained electrochemical response was the result of the contributions coming from the [ReO]<SUP>3+</SUP> <i>core</i> (E<SUB>pa</SUB> at ca. 0.2 V vs. Ag/AgNO<SUB>3</SUB>) and the carboxylic group of the ligand. There where also observed redox contributions ascribed to the presence of perrhenate coming from the decomposition of the complex with the lost of ligands, in agreement with the low stability of the studied complexes. copyright The Electrochemical Society. |
| publishDate |
2007 |
| dc.date.none.fl_str_mv |
2007 |
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info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
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article |
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publishedVersion |
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http://sedici.unlp.edu.ar/handle/10915/83370 |
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eng |
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eng |
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