DEMS and in-situ FTIR investigations of C<sub>3</sub> primary alcohols on platinum electrodes in acid solutions : Part II. Allyl alcohol

Autores
Pastor, E.; Wasmus, S.; Iwasita, T.; Arévalo, M. C.; González, S.; Arvia, Alejandro Jorge
Año de publicación
1993
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
On-line mass spectroscopy (DEMS) and in-situ Fourier transform IR spectroscope (FTIRS) have been employed to study the electro-oxidation and the electroreduction products of allyl alcohol on Pt electrodes in acids. The electroreduction products were propanol and a mixture of propylene, propane and ethane. The main oxidation products were CO2 and acrolein. Results are interpreted and possible mechanisms are suggested with the participation of adsorbates having different chain lengths and structures.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Materia
Ciencias Exactas
Química
Mass spectroscopy
Fourier transform IR spectroscope
Allyl alcohol
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/3.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/119264
Acceder
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oai_identifier_str oai:sedici.unlp.edu.ar:10915/119264
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling DEMS and in-situ FTIR investigations of C<sub>3</sub> primary alcohols on platinum electrodes in acid solutions : Part II. Allyl alcoholPastor, E.Wasmus, S.Iwasita, T.Arévalo, M. C.González, S.Arvia, Alejandro JorgeCiencias ExactasQuímicaMass spectroscopyFourier transform IR spectroscopeAllyl alcoholOn-line mass spectroscopy (DEMS) and in-situ Fourier transform IR spectroscope (FTIRS) have been employed to study the electro-oxidation and the electroreduction products of allyl alcohol on Pt electrodes in acids. The electroreduction products were propanol and a mixture of propylene, propane and ethane. The main oxidation products were CO<sub>2</sub> and acrolein. Results are interpreted and possible mechanisms are suggested with the participation of adsorbates having different chain lengths and structures.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas1993info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf81-100http://sedici.unlp.edu.ar/handle/10915/119264enginfo:eu-repo/semantics/altIdentifier/issn/0022-0728info:eu-repo/semantics/altIdentifier/doi/10.1016/0022-0728(93)80288-Sinfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/3.0/Creative Commons Attribution 3.0 Unported (CC BY 3.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-10-15T11:20:00Zoai:sedici.unlp.edu.ar:10915/119264Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-10-15 11:20:00.282SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv DEMS and in-situ FTIR investigations of C<sub>3</sub> primary alcohols on platinum electrodes in acid solutions : Part II. Allyl alcohol
title DEMS and in-situ FTIR investigations of C<sub>3</sub> primary alcohols on platinum electrodes in acid solutions : Part II. Allyl alcohol
spellingShingle DEMS and in-situ FTIR investigations of C<sub>3</sub> primary alcohols on platinum electrodes in acid solutions : Part II. Allyl alcohol
Pastor, E.
Ciencias Exactas
Química
Mass spectroscopy
Fourier transform IR spectroscope
Allyl alcohol
title_short DEMS and in-situ FTIR investigations of C<sub>3</sub> primary alcohols on platinum electrodes in acid solutions : Part II. Allyl alcohol
title_full DEMS and in-situ FTIR investigations of C<sub>3</sub> primary alcohols on platinum electrodes in acid solutions : Part II. Allyl alcohol
title_fullStr DEMS and in-situ FTIR investigations of C<sub>3</sub> primary alcohols on platinum electrodes in acid solutions : Part II. Allyl alcohol
title_full_unstemmed DEMS and in-situ FTIR investigations of C<sub>3</sub> primary alcohols on platinum electrodes in acid solutions : Part II. Allyl alcohol
title_sort DEMS and in-situ FTIR investigations of C<sub>3</sub> primary alcohols on platinum electrodes in acid solutions : Part II. Allyl alcohol
dc.creator.none.fl_str_mv Pastor, E.
Wasmus, S.
Iwasita, T.
Arévalo, M. C.
González, S.
Arvia, Alejandro Jorge
author Pastor, E.
author_facet Pastor, E.
Wasmus, S.
Iwasita, T.
Arévalo, M. C.
González, S.
Arvia, Alejandro Jorge
author_role author
author2 Wasmus, S.
Iwasita, T.
Arévalo, M. C.
González, S.
Arvia, Alejandro Jorge
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Ciencias Exactas
Química
Mass spectroscopy
Fourier transform IR spectroscope
Allyl alcohol
topic Ciencias Exactas
Química
Mass spectroscopy
Fourier transform IR spectroscope
Allyl alcohol
dc.description.none.fl_txt_mv On-line mass spectroscopy (DEMS) and in-situ Fourier transform IR spectroscope (FTIRS) have been employed to study the electro-oxidation and the electroreduction products of allyl alcohol on Pt electrodes in acids. The electroreduction products were propanol and a mixture of propylene, propane and ethane. The main oxidation products were CO<sub>2</sub> and acrolein. Results are interpreted and possible mechanisms are suggested with the participation of adsorbates having different chain lengths and structures.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
description On-line mass spectroscopy (DEMS) and in-situ Fourier transform IR spectroscope (FTIRS) have been employed to study the electro-oxidation and the electroreduction products of allyl alcohol on Pt electrodes in acids. The electroreduction products were propanol and a mixture of propylene, propane and ethane. The main oxidation products were CO<sub>2</sub> and acrolein. Results are interpreted and possible mechanisms are suggested with the participation of adsorbates having different chain lengths and structures.
publishDate 1993
dc.date.none.fl_str_mv 1993
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/119264
url http://sedici.unlp.edu.ar/handle/10915/119264
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0022-0728
info:eu-repo/semantics/altIdentifier/doi/10.1016/0022-0728(93)80288-S
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/3.0/
Creative Commons Attribution 3.0 Unported (CC BY 3.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/3.0/
Creative Commons Attribution 3.0 Unported (CC BY 3.0)
dc.format.none.fl_str_mv application/pdf
81-100
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.22299

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