The Molecular Structure of 4-Methyl Benzenesulfonyl Chloride
- Autores
- Rigotti, Guillermo; Rivero, Blas Eduardo; Filgueira, Roberto Raúl
- Año de publicación
- 1986
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The molecular structure of C7H7SO2CI was determined by X-ray diffraction and refined to R = 0.060 and Rw = 0.053 from 1170 unique reflections. The unit cell is triclinic, P1, with Z = 2, a = 8.528(5), b = 8.214(3), c = 6.306(2) A; a = 95.47(3), ß = 104.41(3), y = 93.08(4)°; V = 424.6(3) ų; u = 6.30 cm⁻¹; δcale = 1.49 Mg. m⁻³; F(000) = 196. The dihedral angle between the benzene ring and the CI-S-C(l) plane [84.3(1)°] is similar to those observed for benzenesulfonyl chlorides where molecular packing results from normal van der Waals interactions [1, 2], The compound has normal bond lengths and angles. Distortion of the benzene ring is in agreement with the predicted σ- and π-effects of substituent groups [3], No significantly short intermolecular distances were found.
Publicado on line en 2014.
Facultad de Ciencias Exactas - Materia
-
Química
4-Methyl Benzenesulfonyl chloride
Molecular structure - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by-nc-nd/3.0/
- Repositorio
.jpg)
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/120223
Ver los metadatos del registro completo
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The Molecular Structure of 4-Methyl Benzenesulfonyl ChlorideRigotti, GuillermoRivero, Blas EduardoFilgueira, Roberto RaúlQuímica4-Methyl Benzenesulfonyl chlorideMolecular structureThe molecular structure of C7H7SO2CI was determined by X-ray diffraction and refined to R = 0.060 and Rw = 0.053 from 1170 unique reflections. The unit cell is triclinic, P1, with Z = 2, a = 8.528(5), b = 8.214(3), c = 6.306(2) A; a = 95.47(3), ß = 104.41(3), y = 93.08(4)°; V = 424.6(3) ų; u = 6.30 cm⁻¹; δcale = 1.49 Mg. m⁻³; F(000) = 196. The dihedral angle between the benzene ring and the CI-S-C(l) plane [84.3(1)°] is similar to those observed for benzenesulfonyl chlorides where molecular packing results from normal van der Waals interactions [1, 2], The compound has normal bond lengths and angles. Distortion of the benzene ring is in agreement with the predicted σ- and π-effects of substituent groups [3], No significantly short intermolecular distances were found.Publicado on line en 2014.Facultad de Ciencias Exactas1986info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf1107-1111http://sedici.unlp.edu.ar/handle/10915/120223enginfo:eu-repo/semantics/altIdentifier/issn/1865-7117info:eu-repo/semantics/altIdentifier/doi/10.1515/znb-1986-0908info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/3.0/Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-10T12:31:05Zoai:sedici.unlp.edu.ar:10915/120223Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-10 12:31:05.337SEDICI (UNLP) - Universidad Nacional de La Platafalse |
| dc.title.none.fl_str_mv |
The Molecular Structure of 4-Methyl Benzenesulfonyl Chloride |
| title |
The Molecular Structure of 4-Methyl Benzenesulfonyl Chloride |
| spellingShingle |
The Molecular Structure of 4-Methyl Benzenesulfonyl Chloride Rigotti, Guillermo Química 4-Methyl Benzenesulfonyl chloride Molecular structure |
| title_short |
The Molecular Structure of 4-Methyl Benzenesulfonyl Chloride |
| title_full |
The Molecular Structure of 4-Methyl Benzenesulfonyl Chloride |
| title_fullStr |
The Molecular Structure of 4-Methyl Benzenesulfonyl Chloride |
| title_full_unstemmed |
The Molecular Structure of 4-Methyl Benzenesulfonyl Chloride |
| title_sort |
The Molecular Structure of 4-Methyl Benzenesulfonyl Chloride |
| dc.creator.none.fl_str_mv |
Rigotti, Guillermo Rivero, Blas Eduardo Filgueira, Roberto Raúl |
| author |
Rigotti, Guillermo |
| author_facet |
Rigotti, Guillermo Rivero, Blas Eduardo Filgueira, Roberto Raúl |
| author_role |
author |
| author2 |
Rivero, Blas Eduardo Filgueira, Roberto Raúl |
| author2_role |
author author |
| dc.subject.none.fl_str_mv |
Química 4-Methyl Benzenesulfonyl chloride Molecular structure |
| topic |
Química 4-Methyl Benzenesulfonyl chloride Molecular structure |
| dc.description.none.fl_txt_mv |
The molecular structure of C7H7SO2CI was determined by X-ray diffraction and refined to R = 0.060 and Rw = 0.053 from 1170 unique reflections. The unit cell is triclinic, P1, with Z = 2, a = 8.528(5), b = 8.214(3), c = 6.306(2) A; a = 95.47(3), ß = 104.41(3), y = 93.08(4)°; V = 424.6(3) ų; u = 6.30 cm⁻¹; δcale = 1.49 Mg. m⁻³; F(000) = 196. The dihedral angle between the benzene ring and the CI-S-C(l) plane [84.3(1)°] is similar to those observed for benzenesulfonyl chlorides where molecular packing results from normal van der Waals interactions [1, 2], The compound has normal bond lengths and angles. Distortion of the benzene ring is in agreement with the predicted σ- and π-effects of substituent groups [3], No significantly short intermolecular distances were found. Publicado on line en 2014. Facultad de Ciencias Exactas |
| description |
The molecular structure of C7H7SO2CI was determined by X-ray diffraction and refined to R = 0.060 and Rw = 0.053 from 1170 unique reflections. The unit cell is triclinic, P1, with Z = 2, a = 8.528(5), b = 8.214(3), c = 6.306(2) A; a = 95.47(3), ß = 104.41(3), y = 93.08(4)°; V = 424.6(3) ų; u = 6.30 cm⁻¹; δcale = 1.49 Mg. m⁻³; F(000) = 196. The dihedral angle between the benzene ring and the CI-S-C(l) plane [84.3(1)°] is similar to those observed for benzenesulfonyl chlorides where molecular packing results from normal van der Waals interactions [1, 2], The compound has normal bond lengths and angles. Distortion of the benzene ring is in agreement with the predicted σ- and π-effects of substituent groups [3], No significantly short intermolecular distances were found. |
| publishDate |
1986 |
| dc.date.none.fl_str_mv |
1986 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
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article |
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publishedVersion |
| dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/120223 |
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http://sedici.unlp.edu.ar/handle/10915/120223 |
| dc.language.none.fl_str_mv |
eng |
| language |
eng |
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info:eu-repo/semantics/altIdentifier/issn/1865-7117 info:eu-repo/semantics/altIdentifier/doi/10.1515/znb-1986-0908 |
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info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by-nc-nd/3.0/ Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0) |
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openAccess |
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http://creativecommons.org/licenses/by-nc-nd/3.0/ Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0) |
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application/pdf 1107-1111 |
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