Removal of phenol from aqueous solutions by adsorption onto Mn-Ce-K solids
- Autores
- D'Alessandro, Oriana; Thomas, Horacio Jorge; Sambeth, Jorge Enrique
- Año de publicación
- 2014
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Mn-Ce solids were used for the adsorption of phenol from aqueous solution at 25 and 50 C. The samples were prepared with a Mn-Ce molar ratio Between 0 and 100 % by the alkaline co-precipitation method (KOH). Structural studies showed the formation of cryptomelane, Mn2O3, Mn5O8, Mn3O4 and CeO2. The formation of different phases is a function of the Ce concentration. The adsorption isotherms of phenol were determined and modelled with Langmuir and Freundlich equations. Sample 7/3 had a high adsorption capacity. Thermodynamic parameters, in flat and vertical position of phenol, were calculated. These parameters indicated that the adsorption of phenol onto Mn-Ce was spontaneous and exothermic. The DRIFTS study detected of both phenol and phenolate species adsorbed on the surface and the aromatic ring of phenol is parallel to the surface. The interaction between Mn and Ce enhanced the reducibility of the oxides and activated oxygen, which is favorable for the adsorption process.
Centro de Investigación y Desarrollo en Ciencias Aplicadas - Materia
-
Química
Phenol adsorption
Alkaline precipitation
Mn–Ce–K
Thermodynamic parameters - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by/4.0/
- Repositorio
- Institución
- Universidad Nacional de La Plata
- OAI Identificador
- oai:sedici.unlp.edu.ar:10915/122503
Ver los metadatos del registro completo
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Removal of phenol from aqueous solutions by adsorption onto Mn-Ce-K solidsD'Alessandro, OrianaThomas, Horacio JorgeSambeth, Jorge EnriqueQuímicaPhenol adsorptionAlkaline precipitationMn–Ce–KThermodynamic parametersMn-Ce solids were used for the adsorption of phenol from aqueous solution at 25 and 50 C. The samples were prepared with a Mn-Ce molar ratio Between 0 and 100 % by the alkaline co-precipitation method (KOH). Structural studies showed the formation of cryptomelane, Mn2O3, Mn5O8, Mn3O4 and CeO2. The formation of different phases is a function of the Ce concentration. The adsorption isotherms of phenol were determined and modelled with Langmuir and Freundlich equations. Sample 7/3 had a high adsorption capacity. Thermodynamic parameters, in flat and vertical position of phenol, were calculated. These parameters indicated that the adsorption of phenol onto Mn-Ce was spontaneous and exothermic. The DRIFTS study detected of both phenol and phenolate species adsorbed on the surface and the aromatic ring of phenol is parallel to the surface. The interaction between Mn and Ce enhanced the reducibility of the oxides and activated oxygen, which is favorable for the adsorption process.Centro de Investigación y Desarrollo en Ciencias Aplicadas2014info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://sedici.unlp.edu.ar/handle/10915/122503enginfo:eu-repo/semantics/altIdentifier/issn/1878-5190info:eu-repo/semantics/altIdentifier/issn/1878-5204info:eu-repo/semantics/altIdentifier/doi/10.1007/s11144-014-0747-6info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-03T11:01:03Zoai:sedici.unlp.edu.ar:10915/122503Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-03 11:01:04.019SEDICI (UNLP) - Universidad Nacional de La Platafalse |
dc.title.none.fl_str_mv |
Removal of phenol from aqueous solutions by adsorption onto Mn-Ce-K solids |
title |
Removal of phenol from aqueous solutions by adsorption onto Mn-Ce-K solids |
spellingShingle |
Removal of phenol from aqueous solutions by adsorption onto Mn-Ce-K solids D'Alessandro, Oriana Química Phenol adsorption Alkaline precipitation Mn–Ce–K Thermodynamic parameters |
title_short |
Removal of phenol from aqueous solutions by adsorption onto Mn-Ce-K solids |
title_full |
Removal of phenol from aqueous solutions by adsorption onto Mn-Ce-K solids |
title_fullStr |
Removal of phenol from aqueous solutions by adsorption onto Mn-Ce-K solids |
title_full_unstemmed |
Removal of phenol from aqueous solutions by adsorption onto Mn-Ce-K solids |
title_sort |
Removal of phenol from aqueous solutions by adsorption onto Mn-Ce-K solids |
dc.creator.none.fl_str_mv |
D'Alessandro, Oriana Thomas, Horacio Jorge Sambeth, Jorge Enrique |
author |
D'Alessandro, Oriana |
author_facet |
D'Alessandro, Oriana Thomas, Horacio Jorge Sambeth, Jorge Enrique |
author_role |
author |
author2 |
Thomas, Horacio Jorge Sambeth, Jorge Enrique |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Química Phenol adsorption Alkaline precipitation Mn–Ce–K Thermodynamic parameters |
topic |
Química Phenol adsorption Alkaline precipitation Mn–Ce–K Thermodynamic parameters |
dc.description.none.fl_txt_mv |
Mn-Ce solids were used for the adsorption of phenol from aqueous solution at 25 and 50 C. The samples were prepared with a Mn-Ce molar ratio Between 0 and 100 % by the alkaline co-precipitation method (KOH). Structural studies showed the formation of cryptomelane, Mn2O3, Mn5O8, Mn3O4 and CeO2. The formation of different phases is a function of the Ce concentration. The adsorption isotherms of phenol were determined and modelled with Langmuir and Freundlich equations. Sample 7/3 had a high adsorption capacity. Thermodynamic parameters, in flat and vertical position of phenol, were calculated. These parameters indicated that the adsorption of phenol onto Mn-Ce was spontaneous and exothermic. The DRIFTS study detected of both phenol and phenolate species adsorbed on the surface and the aromatic ring of phenol is parallel to the surface. The interaction between Mn and Ce enhanced the reducibility of the oxides and activated oxygen, which is favorable for the adsorption process. Centro de Investigación y Desarrollo en Ciencias Aplicadas |
description |
Mn-Ce solids were used for the adsorption of phenol from aqueous solution at 25 and 50 C. The samples were prepared with a Mn-Ce molar ratio Between 0 and 100 % by the alkaline co-precipitation method (KOH). Structural studies showed the formation of cryptomelane, Mn2O3, Mn5O8, Mn3O4 and CeO2. The formation of different phases is a function of the Ce concentration. The adsorption isotherms of phenol were determined and modelled with Langmuir and Freundlich equations. Sample 7/3 had a high adsorption capacity. Thermodynamic parameters, in flat and vertical position of phenol, were calculated. These parameters indicated that the adsorption of phenol onto Mn-Ce was spontaneous and exothermic. The DRIFTS study detected of both phenol and phenolate species adsorbed on the surface and the aromatic ring of phenol is parallel to the surface. The interaction between Mn and Ce enhanced the reducibility of the oxides and activated oxygen, which is favorable for the adsorption process. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Articulo http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://sedici.unlp.edu.ar/handle/10915/122503 |
url |
http://sedici.unlp.edu.ar/handle/10915/122503 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/issn/1878-5190 info:eu-repo/semantics/altIdentifier/issn/1878-5204 info:eu-repo/semantics/altIdentifier/doi/10.1007/s11144-014-0747-6 |
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info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
eu_rights_str_mv |
openAccess |
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http://creativecommons.org/licenses/by/4.0/ Creative Commons Attribution 4.0 International (CC BY 4.0) |
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application/pdf |
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SEDICI (UNLP) - Universidad Nacional de La Plata |
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